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Which of the following is/are paramagnetic 1) [Co(en) I(low spin n) [Fe(NH) (high spin m) [Cu(H.O.S(square...
Which of the following ions CANNOT form both a high spin and low spin octahedral complex ion? Select one or more: +2 a. Co +3 b. Cr +3 c. Mn +3 d. Fe
1. For each of the following complexes, give the electron configurations of the d-type M Os, for tetrahedral complexes. Also ie ) (e) for octahedral complexes and (e( ch complex in units of the Bohr , Fe(CN) 3, CoCl , Ni(CO)4, Ti(H2O) +, magnet n f.в Co ( NH3) 3+, Co(FLO)r", Fe(CN) V Fa". Cu(H2O) г., CuCl? , V(CO), Cr(CO) each octahedral complex is high-spi the ligand field theory notes). ust use your judgment as to whether n or low-spin...
a. Predict the structure of [Cr(OH2)6]2+ - I wrote that the complex will undergo Jahn-Teller distortion, making the octahedral complex become tetragonal (don't know if that's correct) b. Account for the variation in the lattice enthalpy of Mn (2780 kJ/mol), Fe (2926 kJ/mol), Co (2976 kJ/mol), Ni (3060 kJ/mol), and Zn (2985 kJ/mol) flouride given that the metal center in all of the flourides is surrounded by an octahedral array of F-ions. c. Explain the effect on the d-orbital energies...
Problem #10: Which of the following sequences converge? (i) an (-1)n+1 n n2 - 7 (-1)" n2 n? - (iii) an = cos(NT) (iv) an= sin(nn) (ii) an= -9 (A) (i) only (B) (ii) only (C) (i) and (iv) only (D) (i) and (iii) only (E) (ii) and (iii) only (F) (ii) and (iv) only (G) all of them (H) none of them
just part f please
1. For the following complexes: i) give the formal oxidation state of the metal ii) the d count for the metal ions (e.g. Fe → d) iii) sketch the compound iv) give its point group v) provide a qualitative o-only d-orbital splitting diagram indicating the correct symbols for the point group (i.e. a1g) vi) Indicate if you would predict a Jahn-Teller distortion (no need to distort to splitting diagram) vii) Calculate the spin-only value of off,...
just part d please
1. For the following complexes: i) give the formal oxidation state of the metal ii) the d count for the metal ions (e.g. Fe → d). iii) sketch the compound iv) give its point group v) provide a qualitative o-only d-orbital splitting diagram indicating the correct symbols for the point group (i.e. a10) vi) Indicate if you would predict a Jahn-Teller distortion (no need to distort to splitting diagram) vii) Calculate the spin-only value of Weft,...
i
can't solve this question of coordination chemistry, could someone
hlep me please
Exercise 1: 1. What kind(s) of interaction between the ligand and the metal ion is(are) considered in the crystal field approach? 2. Give and justify the degeneracy lifting for a tetrahedral complex. Would it be the same for an octahedral complex? 3. Let us consider hexaaquacopper(II) ion. Justify the elongation of two opposite Cu-O bonds (along z for example) compared to the other four Cu-O bonds using...
Refer to the following program sample to answer the parts (a-i) below. Keep in mind that low and high are both indices of array A. /1 Assume that A is a sorted array containing N integers // Assume that x is a variable of type int int low= 0; // Line 1 int high- N; // Line 2 while (low- high) I/ Line 3 m- (lowthigh)/2; // Line 4 (This is integer division) if (A [m]<) I/Line 5 then low-...
due ASAP please help!!
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Cell potentials for the following species were measured using the Standard Hydrogen Electrode (SHE) at 25°C: Reaction Fe3+ (aq) + + Fe2+ (aq) Ecell E° = + 0.771 V Cu2+ (aq) + 2e + Cu(s) E° = + 0.340 V 2H+(aq) + 2e + H2(g) E° = 0.000 V Which species is the strongest reductant? O Fe3+ (aq) O Fe2+ (aq) O Cu2+ (aq) O Cu(s) O H2(g) O H+(aq) Cell potentials...
Explain the answer please.
) 1 on electronegativity differences, which of the following is most likely to be ionie? BaF2 b) Bra c) PH d) NO e CL 6. How many electrons can be contained in all of the orbitals with n-4? c) 10 d) 18 32 Which of the following molecules has no dipole moment? mause it is a Hencar wno 7. NH c) H20 d) all e) none 8. How many electrons can be described by the quantum...