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5. Complete the following reactions with major monosubstitution product(s). Be sure to account for regioselectivity and...
8. Complete the following reactions with major product(s). Be sure to account for regioselectivity and stereoisomers. Write NR if no reaction is expected. (20 pt) AcOH, A - Br Br KH, DMF Me OH, A x CH3O, CH3OH Br
7. Complete the following reactions. Be sure to account for regioselectivity and stereoisomers. Write NR if no reaction is expected. (10 pt) Δ Δ +
Evening SN2 vs. E2 Homework Predict the major product(s) expected for each of the following reactions. Remember to indica stereochemistry, when appropriate. If no reaction is expected, write NR. a. CH3CN opothe Na t-BuO t-BuOH Rrot b. C. H3C d. H3C Br e. OH EtOH Pro NaN3 OH acetone poic NaOH Stos nlphe h. OTS EtOH pokc
Give the major organic product(s) of the following reactions or
sequences of reactions. Show the stereochemistry and/or isotope
position clearly where it is relevant. If you think that the
reaction would not occur, write as "NR" or "No Reaction."
A) ON CI 'N AlCl3 B) Br-N hu, CC14 ? Br2, FeBrz
Give the major organic product(s) of the following reactions or
sequences of reactions. Show the stereochemistry and/or isotope
position clearly where it is relevant. If you think that the
reaction would not occur, write as "NR" or "No Reaction."
A) 1) NaOH ОН ? 2) CH3CH Br B) 1) NH3, excess 2) SOC12, Pyridine, heat CI
VI. Reactions (21 pts) Provide the major product in the following reaction. It as the product Show your work for each stepll Pay attentio Stereochemistry! Product in the following reaction. If no reaction occurs, write" NR stepll pay attention to Regiochemistry and TSCI ElyN 1. CHy-Br (xs) 2 A0,0,H,O, A H-CI E-G NaBH,CN a. NaNs, EtOH b. H20, он 1. SOCI, pyridine 2. NaN, DMF 3. LIAIH, EL 0
VI. Reactions (21 pts) Provide the major product in the following reaction. If no reaction occurs, write "NR as the product. Show your work for each step!! Pay attention to Regiochemistry and Stereochemistry! TSCI EtyN 1. CHg-Br (xs) 2. Ag20, H20, A H-CI Et20 Sold lo no? NaBH CN a. NaNg, EtOH b. H20,4 OH 1. SOCI, pyridine 2. NaN, DMF 3. LIAIH, Et20
5. Draw the complete mechanism for the following reaction. Be sure to account for all possible major products, including stereoisomers. Br HSCH3 H2O
organic
III. Predict the major product(s) or fill in the reagent(s) for the following reactions. If there is no reaction write NR. (6 points each, 36 points total) Show the correct stereochemistry when needed!! 16 HO H,Cro (excess) -CHO 17 1)0, (2 equiv.) 2) Mezs (2 equiv.) 18 Ph Ph он om Ph Ph 19 1) mCPBA 2) EtONa, EtOH 20 1) LIAIH (excess) 2) H20*, ,0+ 21 1) NaNH, 2) CH,Br 3) HBr (2 equiv.)
5. (7 pts) Predict the major product(s) for the following reactions. Remember to indicate stereochemistry, when appropriate. If no reaction is expected, write NR. C12 hv а. NBS hv b HBr ROOR с.