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ㅏ NH2 oblo obno AICI: 1) H2CrO2, H2SO4 H20 1 ОН 2) SOCI2, pyridine 3) CH2CH2SH,...
give the major product
CH2CH2CI AICI 0 0 NH2. ॥ ॥ SOCI2 PhH ОН
5. Match the reagents to the corresponding reaction. I Cl NH2 OH II NH2 G. H20 A. SOCI2, pyridine B. Ethanol, pyridine H. xs CH3CH2NH2 I. 1) LIAI(OR)sH 2) H2O C. 1) xs LAH 2) H20 J. (CH3CH2)2CuLi D. 1) xs CH3CH2MgBr 2) H2O K. xs NH3 E. 1) NaOH 2) H30 L. 1) NaOH 2) CH3CH2CH2COCI F. 1) DIBAH 2) H20 M.Butanol, H
Predict the product for the following reaction. он 1. SOCI2/pyridine 2. LiA[[OC(CH3)3]Н ОН Осн. || ОН SOCIII Оооооо
provide the major product in the following reaction
NH2 NaBH3CN a. NaNg, EtOH b. H20, A ОН 1. SOCI2, pyridine 2. NaN3, DMF 3. LIAIH4, Et20
4) Predict the product (A) of the following reaction. 1. KMnO4/NaOH/H20 2. H30* SOCI2 pyridine (CH3)2CHCH2OH pyridine A
5. Match the reagents to the corresponding reaction. OH NH2 II NH2 G. H2O A. SOCI2, pyridine H. xs CH3CH2N H2 B. Ethanol, pyridine I. 1) LIAI(OR)sH 2) H20 C. 1) xs LAH 2) H20 J. (CH2CH2)2CuLi D. 1) xs CH3CH2M9 Br 2) H2O K. xs NH3 E. 1) NAOH 2) H,O F. 1) DIBAH 2) H2O L. 1) NaOH 2) CH3CH2CH2COCI M. Butanol, H
Explain
the mechanism of the reactions by showing the curved arrows.
H OH H2SO4 SOCI2 pyridine POC pyridine H Br
OH r. Он reagent(s) Br OEt S. reagent(s) Br Он K2Cr2O7 (excess) H2SO4, H20 Он но 1. PhLi, Et O 2. HCI, H2O 3. SOCI2, EtN 4. NaOAc u. н 1. Mg (1 eq), Et2O V. Br 2. (1 eq) -сно 3. HCI, Н,О W. 1. NaBH,, MeOН, 0° С 2. PBra THF 3. LIAID4, THF 4. HCI, H20
1. Predict the product(s) for each of the following reactions: H2SO4 NH2 a. 0 1. H2N-NH2, H2S04, -H20 H 2. KOH/H2O b. MeOH, TsOH он H2O C. H2SO4, -H20 HO d. H2O, H30+ e. H20,H30+ 2. Predict the product and draw the full pushing arrow mechanism for the following reaction NH2 H20,H30+ a. b. 3. Devise an efficient synthesis for the following transformation. HO Br Br
Question 6 Identify the reagents necessary for the following transformation: OH -oo O 1) SOCI2, H2SO4, H20 2) Na2Cr2O7 1) Na2Cr207, H2SO4, H20 2) SOCI O 1) Na2Cr2O7, H20 2) SOCI2 1) Na2Cr2O7, SOCI2, H20 2) H2SO4