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each of the reactions, show the reafents that would best accomplish
the given synthesis, according...
? (CH3)2CHCH2CECH (CH3)-CHCHCCH (d) Br ? + enantiomer ? -C=C-H CEC (f) Hint: this is a...
? (CH3)2CHCH2CECH (CH3)-CHCHCCH (d) Br ? + enantiomer ? -C=C-H CEC (f) Hint: this is a multistep synthesis. Propose a series of reactions that would achieve the following transformation. Make sure to number the steps. Br ?
Propose a synthesis of the following derivative of diethyl malonate using reagents from the choices provided...
Propose a synthesis of the following derivative of diethyl malonate using reagents from the choices provided below. (From the choices provided, list the reagent(s) in order that will accomplish this transformation. No more than 4 steps are required. List your answer as a single letter (single-step transformation) or a series of letters (multi-step transformation) with no commas separating them.) Reagents available a. Eto Na g. CH2=CHCH=CHCH,Br b. CH3 CH2Br c. CH3 CH, CH, CH(CH3)Br d. (CH3)2 CHCH, CH,Br e. CH3...
Synthesis version: 7. Provide reagents for the following two transformations. If more than one step is...
Synthesis version: 7. Provide reagents for the following two transformations. If more than one step is required, number individual steps. Use your answers to 6a and 6b to help you with this! Br CH,CH3 + E H CIWC- H, OH HzC CH3 CEC CH,CHz . HC Br H C-CICH "CH + E HO CH2CH3
CHM230 Class Worksheet Alkene and Alkyne reactions Give the major product of each of the following...
CHM230 Class Worksheet Alkene and Alkyne reactions Give the major product of each of the following reactions: CH,CH,C=CH + 1 equivalent HCI H2 + Lindlar catalyst CH3CHCH2C=CCHCH3 + CICH + H+ + CH3CH2OH CH3CH2C=CH + 2 equivalents HCI CH,CH2C=C-CH3 + 2 equivalents HBr + H+ + H2O + excess HBr CH,CH.C=C-CH3 + excess Hy/Lindlar 2 + excess H/PUC CH3C=C-CH3 + H2O / H / Hg2+ ox.. + HBr + NaNH2 + CH CH Br Given the following alkyne, provide the...
Which of these anions would be the most nucleophilic towards methyl iodide in an ethanol solution?...
Which of these anions would be the most nucleophilic towards methyl iodide in an ethanol solution? LI. CH,CH2-C- Which reagent would be best for carrying out this transformation он (B) HO",heat (C) HIO, N-H Cro,cr (PCC) @ C+--Ο- Which reaction sequence would accomplish this t- What is che best rearest or set of reagents to accomplish ICH CH (B) H2, Pd NBS HBr, peroxides (A) KMnO/KOH (B) MCPBA 5 Which series of reactions would best accomplish this 1eWhas is the...
Consider the following reaction: OH HC H.SO CH, + ОН Δ Show the complete mechanism for...
Consider the following reaction: OH HC H.SO CH, + ОН Δ Show the complete mechanism for the following transformations. Make sure to show all arrows depicting the movement of electrons. The above reaction (using acid and heat) causes a number of unwanted side products to form (a big mess). Propose a better synthesis for the product using the same starting materials. Show the reagents and intermediate steps to complete the synthesis: OH H3C- ??? + CH3 OH X steps Propose...
Which reagents would best accomplish the following transformation? ОН N 1. Potassium Phthalimide 2. CH3NH2 3....
Which reagents would best accomplish the following transformation? ОН N 1. Potassium Phthalimide 2. CH3NH2 3. N2H4 O 1. CH3NH2 2. LiAlH4 3. H30+ O 1. SOCl2, pyridine 2. CH3NH2 O 1. p-TsOH, HOCH CHOH 2. CH3NH2 3. H30+ ? 3:13 PM 7/30/2020 Which reaction sequence would accomplish this transformation? oth HO H O 1. CH3MgBr 2. H30+ 3. CH3OH 1. H30+, CH3OH 2. NaBH4 3. H30+ O 1. p-TOH, HOCH CH2OH 2. NaBH: 3. H30+ O 1. pTSOH, HOCH,CH,OH...
Which starting material would best accomplish this transformation? 1. SOCI2 2. CH3NH2 3. LiAlH4 4. H30*...
Which starting material would best accomplish this transformation? 1. SOCI2 2. CH3NH2 3. LiAlH4 4. H30* Н OH Br Which is the best starting material for the following reaction? CH3CH2NH2 ? pyridine HN o о NH2 С- CI OH Which are the best reagents for the following transformation? OCH3 core O 1. (CH3)2CHMgBr 2. H30+ 1. NaOH, heat 2. (CH3)2CHCH=PPh3 O 1. LiAlH4 2. TosCl, pyridine 3. (CH3)2CHCH Br O 1. DIBAL 2. (CH3)2CHCH=PPh3 What is the major product in...
Complete the following reactions. Be sure to evaluate each reaction in terms of substrate, nucleophile, leaving...
Complete the following reactions. Be sure to evaluate each
reaction in terms of substrate, nucleophile, leaving group, and
solvent in order to best judge the nature of the reaction and the
products formed.
Complete the following reactions. Be sure to evaluate each reaction in terms of substrate, nucleophile, leaving group and solvent in order to best judge the nature of the reaction and the product(s) formed. (5 pts) CH2O СН,ОН H₃C & CH₂ H₂O. Ethanol CH3 CH,Br OH CHCN Which...
Question 2: Determine in the following examples if the base is strong enough to deprotonate the...
Question 2: Determine in the following examples if the base is strong enough to deprotonate the terminal alkyne. сH, нс. t-BuOK + Cн Question 3: A terminal alkyne is prepared by treating the dihalide with excess (xs) sodium amide, followed by water. Predict the major product and draw a mechanism for its formation: Br 1) xs NaNHNH 2) Hо Br Identify reagents that you could use to achieve the following transformations: CH3 Нас Н,с CH3 CH3 HyC Н.с CHs CH3...
? (CH3)2CHCH2CECH (CH3)-CHCHCCH (d) Br ? + enantiomer ? -C=C-H CEC (f) Hint: this is a multistep synthesis. Propose a series of reactions that would achieve the following transformation. Make sure to number the steps. Br ?
Propose a synthesis of the following derivative of diethyl malonate using reagents from the choices provided below. (From the choices provided, list the reagent(s) in order that will accomplish this transformation. No more than 4 steps are required. List your answer as a single letter (single-step transformation) or a series of letters (multi-step transformation) with no commas separating them.) Reagents available a. Eto Na g. CH2=CHCH=CHCH,Br b. CH3 CH2Br c. CH3 CH, CH, CH(CH3)Br d. (CH3)2 CHCH, CH,Br e. CH3...
Synthesis version: 7. Provide reagents for the following two transformations. If more than one step is required, number individual steps. Use your answers to 6a and 6b to help you with this! Br CH,CH3 + E H CIWC- H, OH HzC CH3 CEC CH,CHz . HC Br H C-CICH "CH + E HO CH2CH3
CHM230 Class Worksheet Alkene and Alkyne reactions Give the major product of each of the following reactions: CH,CH,C=CH + 1 equivalent HCI H2 + Lindlar catalyst CH3CHCH2C=CCHCH3 + CICH + H+ + CH3CH2OH CH3CH2C=CH + 2 equivalents HCI CH,CH2C=C-CH3 + 2 equivalents HBr + H+ + H2O + excess HBr CH,CH.C=C-CH3 + excess Hy/Lindlar 2 + excess H/PUC CH3C=C-CH3 + H2O / H / Hg2+ ox.. + HBr + NaNH2 + CH CH Br Given the following alkyne, provide the...
Which of these anions would be the most nucleophilic towards methyl iodide in an ethanol solution? LI. CH,CH2-C- Which reagent would be best for carrying out this transformation он (B) HO",heat (C) HIO, N-H Cro,cr (PCC) @ C+--Ο- Which reaction sequence would accomplish this t- What is che best rearest or set of reagents to accomplish ICH CH (B) H2, Pd NBS HBr, peroxides (A) KMnO/KOH (B) MCPBA 5 Which series of reactions would best accomplish this 1eWhas is the...
Consider the following reaction: OH HC H.SO CH, + ОН Δ Show the complete mechanism for the following transformations. Make sure to show all arrows depicting the movement of electrons. The above reaction (using acid and heat) causes a number of unwanted side products to form (a big mess). Propose a better synthesis for the product using the same starting materials. Show the reagents and intermediate steps to complete the synthesis: OH H3C- ??? + CH3 OH X steps Propose...
Which reagents would best accomplish the following transformation? ОН N 1. Potassium Phthalimide 2. CH3NH2 3. N2H4 O 1. CH3NH2 2. LiAlH4 3. H30+ O 1. SOCl2, pyridine 2. CH3NH2 O 1. p-TsOH, HOCH CHOH 2. CH3NH2 3. H30+ ? 3:13 PM 7/30/2020 Which reaction sequence would accomplish this transformation? oth HO H O 1. CH3MgBr 2. H30+ 3. CH3OH 1. H30+, CH3OH 2. NaBH4 3. H30+ O 1. p-TOH, HOCH CH2OH 2. NaBH: 3. H30+ O 1. pTSOH, HOCH,CH,OH...
Which starting material would best accomplish this transformation? 1. SOCI2 2. CH3NH2 3. LiAlH4 4. H30* Н OH Br Which is the best starting material for the following reaction? CH3CH2NH2 ? pyridine HN o о NH2 С- CI OH Which are the best reagents for the following transformation? OCH3 core O 1. (CH3)2CHMgBr 2. H30+ 1. NaOH, heat 2. (CH3)2CHCH=PPh3 O 1. LiAlH4 2. TosCl, pyridine 3. (CH3)2CHCH Br O 1. DIBAL 2. (CH3)2CHCH=PPh3 What is the major product in...
Complete the following reactions. Be sure to evaluate each
reaction in terms of substrate, nucleophile, leaving group, and
solvent in order to best judge the nature of the reaction and the
products formed.
Complete the following reactions. Be sure to evaluate each reaction in terms of substrate, nucleophile, leaving group and solvent in order to best judge the nature of the reaction and the product(s) formed. (5 pts) CH2O СН,ОН H₃C & CH₂ H₂O. Ethanol CH3 CH,Br OH CHCN Which...
Question 2: Determine in the following examples if the base is strong enough to deprotonate the terminal alkyne. сH, нс. t-BuOK + Cн Question 3: A terminal alkyne is prepared by treating the dihalide with excess (xs) sodium amide, followed by water. Predict the major product and draw a mechanism for its formation: Br 1) xs NaNHNH 2) Hо Br Identify reagents that you could use to achieve the following transformations: CH3 Нас Н,с CH3 CH3 HyC Н.с CHs CH3...
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