14-15) Predict the product. Show each step. 16-17) Predict the product. If no reaction, write NR....
Predict the product(s) for the following reactions. If no significant reaction occurs, then write "NR." If you write "NR" make sure to provide an explanation. 1) (CH2=CH) CALI 2) H20 pyridine CH,C1, H.07
16. GO ? Nr.1) NaOH, heat (bo - 2) H₃ ot 3) Soch 41 CH₂ Mg Br (excess) 5) 20 a) in b) HO d) inat Hop -OH
Predict the product(s) and reagent(s) or if there is no reaction write NR. OH K2Cr207 (excess) H2SO4, H20 "ОН 1. PhLi, Et20 2. HCI, HO 3. SOCl2, Et3N 4. NaOAC 1. Mg (1 eq), Et20 < Br 2. (1 eq) CHO 3. HCI, H2O MsCI LDA ОН pyridine 1. Nah 2. Br
Predict the product(s) and reagent(s) or if there is no reaction write NR. 041 for 1. NaBH4, MeOH, 0°C 2. PBr3, THE 3. LiAlD4, THE 4. HCI, H20 1. SOCl2, NEt3, THE CHO 2. 2 eq Li, hexane 3. HCI, H2O OTE hint: multiple steps 1. LIAIH4, THE 2. HCI, H2O 3. PBr3, THE CN OH 1. PCC, DCM 2. Mg, Et O 3. HCI, H2O 1. MSCI, pyr 2. KO'Bu, BuOH
Predict the product(s) for the following reaction. 1. excess LiAIH 2.H20 Edit Predict the product for the following reaction. 0 Br Mg/ether 1. H 1 H 2. H20 12 Edit Predict the major product for the following reaction. -OH 1. TsClipyridine 2. CH CH ONa 12 Edit Predict the product for the following reaction. NaH OH Br heat ? Edit
15. Predict the product of the following Sn2 reaction (CH3)3С—СН,CH,Br + excess 16
16. Give the reagents for the following reaction. Write the product for each step. CH, CH2CH2CECH CH3CH2CH2CHCH2Br :CH, HCH. BY Br
HELP!!! Provide the products of the following transformation. If there is no reaction then write NR. Provide the products of the following transformation. If there is no reaction then write NR. 1. Br Na CN CH3 -CH-CHз DMF H K SCH3 CH3 -CH2CH3 DMF Br OH CH3 -CH2CH3 Draw the product of the following transformation. Show a reaction mechani sm to account for the overall transformation. 2. + sodium metal
17. Give the reagents for the following reaction. Write the product for each step. HCECH CH, CH2CH2CH CH, CH.CHOH 18. Give the reagents for the following reaction. Write the mechanism for each step. Br Br HCECH CH.CH -CH2CH3 1 Br Br
HELP PLEASE ANSWER ALL III. Predict the major product(s) or fill in the reagent(s) for the following reactices. If there is to reaction write NR. (6 points each, 16 points total) Show the correct stresshemistry when needed!! 16 H.CO (excess) CHO HO 17 10 (equiv.) 2) Mes (2 equis.) 18 OH o" 19 1) mCPBA 2) EXON, EICH 20 1) LIAIR (excess) io 2) H 0,1,0 21 1) SNI, 2) CH, Br 3) HBr (2 equiv.) 22.Draw DETAILED arrow.pushing mechanisms...