Question

8. Find the reactant(s) of the that would make the following products from benzene: ou NH2 ON

Answer 1

The synthesisi scheme is given below-

in 1st case, Friedel craft alkylation, followed by oxidation and the reaction with SOCl2 gives benzoyl chloride. in final step benzoyl chloride react with acetic acid delivered the final product.

for the second reaction, the reaction sequences are depicted in the given scheme.

COOH CH3 + AICI: KMnO4 SOCI2 gri . ܚ OH CI acetic benzoic anhydride CH31 + AICI: HNO3 + H2SO4 NO2 KMnO4 CI COOH NH2 NH3 SOCI2 ON 4-nitrobenzamide NO2 NO2