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7. Is it possible to tell if the following reaction took place via an E, or an Ez reaction? Explain why? Н. CH3 H H Base 61111111 + Him... CH3 Br H
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10. Which solvent (acetone or t-butyl alcohol) would be better to carry out the following reaction? Why? Draw the complete mechanism of this reaction using generic base B. O 0 11. Name the following compounds F Ph NH ... H NH2 Bn
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1. Draw the Sn1, SN2, Es, and Ez reaction mechanisms of (just do all four reactions for each): A. (R)-2-bromo-1-phenylpropane reacting with sodium hydroxide B.(2S,3R)-3-bromo-2-methoxy-3-methylpentane with NaF 2. If the two above reactions (from question 1) were carried out in DMSO at room temperature, which reaction mechanism would be favored and why? 3. Draw the most stable chair conformation of 1-t-butylcyclohexane
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4. If (R)-2-bromo-3-methylbutane were to react with water, describe reaction conditions of how the achiral compound 2-methylbutan-2-ol would form. Draw the mechanism. 5.Put the following three compounds in order of increasing basicity. OH OH OH 6.What type of reaction happened if 3-chlorohexane reacted with water to form hexan-3-ol given the following chart and why? Draw the mechanism. Angle of light rotation as reaction proceeds 130 105 80...
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4. If (R)-2-bromo-3-methylbutane were to react with water, describe reaction conditions of how the achiral compound 2-methylbutan-2-ol would form. Draw the mechanism. 6.What type of reaction happened if 3-chlorohexane reacted with water to form hexan-3-ol given the following chart and why? Draw the mechanism. Angle of light rotation as reaction proceeds 130 105 80 55 30 5 -20 -45 -70 -95 -120 . 0 1 2 3 4...
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5. Draw the Newman Projection for butane in the gauche position. 6. Out of the following compounds, rank in terms of increasing heat of combustion?
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11. Name the following compounds Ph ZI... H NH2 Bn
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6.What type of reaction happened if 3-chlorohexane reacted with water to form hexan-3-ol given the following chart and why? Draw the mechanism. Angle of light rotation as reaction proceeds 130 105 80 55 30 5 -20 -45 -70 -95 - 120 9 4 6 7 8 1 3 5 0 2
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Give the major substitution product of the following reaction. Br CH3CO2H ? heat OH SCH O NH2 O o There is no reaction under these conditions or the correct product is not listed here. Give the major substitution product of the following reaction. Br CH3OH ? heat There is no reaction under these conditions or the correct product is not listed here. OH...
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THE FOLLOWING REACTION SCHEME APPLIES TO QUESTIONS 21 AND 22 Jon + intos xor (2) Har Xothon QUESTION 21 [2] In the products of reaction (1), the halogen is on the less hindered carbon labelled (b) in the ether, and the oxygen remains on the more hindered carbon labelled (a). The reason for this is: 11 The reaction proceeds via an 2 mechanism, oxygen in the ether gets protonated first,...