Please find attached file foe answer.
1) KMNO4 is strong oxiding agent , react with P-Isopropyl toulene gives terephthalic acid
2) This is Clemensens reduction Example
Clemensen reduction is of ketones (or aldehydes) to alkanes using zinc amalgam and concentrated hydrochloric acid to give Hydrocarbon
3) This is example of Benzyne Intermediate
Meta product is more Favorable
draw major product/s of each of these reactions
KMnO4 (Excess) 7. CI Zn (Hg)/HCI 8. NaNH2 9. CI НО. HNO3 / H2SO4 10.
1. Draw the product(s) of the following reactions HeCrO4 1. CH,COCVAICI 2. Zn (Hg)HCI 3. NBS (light) 1. KMnO4/H2SO4 og er CH3 NaNH2 NH3(0) 2. Show how you would synthesize the following compounds from toluene. OH O он Br
01. What is the final product of the reaction shown below? CH3C(=O)CI Zn(Hg) AlCl3 HCI Ethylbenzene A) B) © D 1-Phenylethanol 2-Phenylethanol Chlorobenzene
Which reaction sequence would accomplish this transformation? CN O H2SO4/HNO3 Zn(Hg)/HCL NaNO2/HCI CuCN H2SO4/HNO3 Zn(Hg)/HCI NaNO2/HCI HBF4 O H2SO4/HNO3 Br2 NaNO/HCI CuCN Br2/FeBr3 H2SO4/HNO3 KE NaNO2/HCI
Draw the major product(s) of the following reactions. 1) HNO3 H2S0 2) Zn, HCi Br 1) AICl3, CI 2) Zn(Hg), HCl, heat 1) CH3CI, AICI3 2) KMnO4, NaOH, heat 3) H3o 1)CH3C, AIC 2) Excess NBS
833 17-10 The Friedel-Crafts Alkylation 1.2NaOH 100 °C 2. H,09 o Zn(Hg) dilute HCI NBS hy NO, Zn HCI C 17-10 The Friedel-Crafts Alkylation U 8. Predict the major product or products for the following reactions. Assume reagents are present in excess amounts unless otherwise indicated. Clearly depict any stereochemistry. "No Reaction is a possible answer. (4 points) each et :O 1 SO, H2SO4 CH2 CH3 сH,CH,CI AICI, NO2 Br FeBrz OH AICI 1 cq Bry FeBr
Provide the missing structures. Indicate stereochemistry where it
is known.
ore NH3, H30. Zn(Hg), HCI excess ethanol, H (CH3)2CHCH2CH-P(C@Hs)a (CH3)2CHCH2CH CH(CH2)4CH3
For Questions 9-13, choose the correct reagents for the following functional group conversion. 9. A. PCC B. H2CrO C. NaBH.4 D. KMnO4 10. 2 HO CN A. HCN/H2SO4 B. KCN C. HCN/KCN D. NH:/NaOH 2 он A. 1) 4-bromobutanal /2) Mg'/ether /3) H B. NaOH MgBr D. LDA 12. CI Zn(Hg) HCI B. 2) Raney Ni, H2 1)H2N.NL 12. CI Zn(Hg) HCI ) 15 B. 2) Raney Ni, H2 1)H2N C. 2) NaOH/H20, heat NaCI D. 13. 2 Zn(Hg) HCI...
Complete the following reactions:
e) CCH2CH3 Zn(Hg) HCL, heat CH3 (1) KMnO4, OH , heat (2) H30 CH3 g) conc. H2SO4 o-CH heat
9. What is the major product of the following reaction? HCI(9) ? (excess) (a) (b) (c) (d) e) H CI CI H CI H H CI H H CICI HCI HH CHE