Homework Answers
The
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please help with the reactions
-Br + H30* Н (1) H3 C mg -Br H₃C mg...
predict the following reactions for each. 200°C CH2 CH5 1. CH 3 Mg Br 2. H30+
predict the following reactions for each.
200°C CH2 CH5 1. CH 3 Mg Br 2. H30+
Он н H-C-C-CH3 + H20+ reactant H OH 1. + H30+ - reaction of: CH, (1)...
Он н H-C-C-CH3 + H20+ reactant H OH 1. + H30+ - reaction of: CH, (1) BH, - THE (2) H2O, NaOH H product is: OH H,SO calor reactant: 4 OH NaBH, CH CHON H
11. Indicate the order of stability CH н сн. Br CH сH, На н н. Br H H н н" Br н H н н н' Br н A В C D 12. Which of...
11. Indicate the order of stability CH н сн. Br CH сH, На н н. Br H H н н" Br н H н н н' Br н A В C D 12. Which of the following structures does NOT have tetrahedral geometry around any of its central central atoms. Use resonance to help explain A. В. с. D. = NH2 13. Is it theoretically possible to separate the pair of compounds below by distillation? Explain briefly CH CHs Br...
Predict the products of the following reactions. a. b. c. (1) excess CH Mg! CI (2) H30* (1) DIBAL-H (-78 °C) (2) H...
Predict the products of the following reactions.
a.
b.
c.
(1) excess CH Mg! CI (2) H30* (1) DIBAL-H (-78 °C) (2) H30 OCH (1) DIBAL-H (-78 °C) (2) H2O
Fill in the blanks to complete the reaction. (3pts each) Br Н-С—с—н Mg CH3CHCH2CH3 1 Ether...
Fill in the blanks to complete the reaction. (3pts each) Br Н-С—с—н Mg CH3CHCH2CH3 1 Ether Br (CH),CО H 2 C CH-CH,ОH CH3CH20 + 3 E1OH CI 1. ВНз 2. NaOH, H02 ОН HO 5 (CH3CH2)2CuLi 6 OH Bi Br КОН 7 Нас NaCN DMSO
complete the following reactions. A) i) 1. MgBr O 1. LICH2CH3 2. H20 2. H30+ j)...
complete the following
reactions. A) i) 1. MgBr O 1. LICH2CH3 2. H20 2. H30+ j) b) 1. MgBr
OCH3 1.
PLS PLS PLSSS help me with these.
a) i) 1. MgBr O 1. LICH2CH3 2. H20 2. H30+ j) b) 1. MgBr OCH3 1. CH3Li 2. H20 2. H30* c) k) OH 1. CH3 MgBr 2. H20 OH 1. CH3Li 2. H20 d) 1) MgBr 1. CH20 2. H307 1. (CH3)3CMgBr 2. H20 H 3 1. MgBr 2. H30*...
please help Which of the following reactions is not correct as written? Br 1) NaOCH, major product сH, он Br 2) CH...
please help
Which of the following reactions is not correct as written? Br 1) NaOCH, major product сH, он Br 2) CH,CO Na major product сH,Cо Н Br 3) CH,CH,SNa major product DMF A 1) and 2) are incorrect 2) and 3) are incorrect C 3) is incorrect D 2) is incorrect E All are correct
Which of the following reactions is not correct as written? Br 1) NaOCH, major product сH, он Br 2) CH,CO Na major product сH,Cо...
3) Which of the following compounds is chiral? A) H Н-С-н н B) H HO C-OH Н C) CH3 HO-C-H Cl D) Br Н-С-ОН н E) C B...
3) Which of the following compounds is chiral? A) H Н-С-н н B) H HO C-OH Н C) CH3 HO-C-H Cl D) Br Н-С-ОН н E) C Br- C-C Br 4) In the L- isomer of a Fischer projection of a monosaccharide, the -OH group furthest from the carbonyl is written A) on the left of the top chiral carbon B) on the right of the top chiral carbon C) on the left of the middle chiral carbon D) on...
complete the following reactions. a) i) 1. MgBr O 1. LICH2CH3 2. H20 2. H30+ j)...
complete the following reactions.
a) i) 1. MgBr O 1. LICH2CH3 2. H20 2. H30+ j) b) 1. MgBr OCH3 1. CH3Li 2. H20 2. H30* c) k) OH 1. CH3 MgBr 2. H20 OH 1. CH3Li 2. H20 d) 1) MgBr 1. CH20 2. H307 1. (CH3)3CMgBr 2. H20 H 3 1. MgBr 2. H30* 1. Mg Br 2. CO2 3. H20 OCH3 n) f) 1. CH3CH2MgBr 2. H20 1. Li CI 2. CH3CH2OH OH o) g) Br 1....
H3 C H2Br Br2, H30* HC X CH3 HzC CH3 H3C CH3 Aldehydes and ketones can...
H3 C H2Br Br2, H30* HC X CH3 HzC CH3 H3C CH3 Aldehydes and ketones can be halogenated at their a-position by reaction with Cl, Br, or 12, under acidic conditions. Using Br2 under acidic conditions, an intermediate enol is formed which adds bromine at the a-position. The reaction stops after the addition of one bromine because the electron-withdrawing halogen decreases the basicity of the carbonyl oxygen, making the protonation less favorable. Not started curved arrows to show the movement...
predict the following reactions for each.
200°C CH2 CH5 1. CH 3 Mg Br 2. H30+
Он н H-C-C-CH3 + H20+ reactant H OH 1. + H30+ - reaction of: CH, (1) BH, - THE (2) H2O, NaOH H product is: OH H,SO calor reactant: 4 OH NaBH, CH CHON H
11. Indicate the order of stability CH н сн. Br CH сH, На н н. Br H H н н" Br н H н н н' Br н A В C D 12. Which of the following structures does NOT have tetrahedral geometry around any of its central central atoms. Use resonance to help explain A. В. с. D. = NH2 13. Is it theoretically possible to separate the pair of compounds below by distillation? Explain briefly CH CHs Br...
Predict the products of the following reactions.
a.
b.
c.
(1) excess CH Mg! CI (2) H30* (1) DIBAL-H (-78 °C) (2) H30 OCH (1) DIBAL-H (-78 °C) (2) H2O
Fill in the blanks to complete the reaction. (3pts each) Br Н-С—с—н Mg CH3CHCH2CH3 1 Ether Br (CH),CО H 2 C CH-CH,ОH CH3CH20 + 3 E1OH CI 1. ВНз 2. NaOH, H02 ОН HO 5 (CH3CH2)2CuLi 6 OH Bi Br КОН 7 Нас NaCN DMSO
complete the following
reactions. A) i) 1. MgBr O 1. LICH2CH3 2. H20 2. H30+ j) b) 1. MgBr
OCH3 1.
PLS PLS PLSSS help me with these.
a) i) 1. MgBr O 1. LICH2CH3 2. H20 2. H30+ j) b) 1. MgBr OCH3 1. CH3Li 2. H20 2. H30* c) k) OH 1. CH3 MgBr 2. H20 OH 1. CH3Li 2. H20 d) 1) MgBr 1. CH20 2. H307 1. (CH3)3CMgBr 2. H20 H 3 1. MgBr 2. H30*...
please help
Which of the following reactions is not correct as written? Br 1) NaOCH, major product сH, он Br 2) CH,CO Na major product сH,Cо Н Br 3) CH,CH,SNa major product DMF A 1) and 2) are incorrect 2) and 3) are incorrect C 3) is incorrect D 2) is incorrect E All are correct
Which of the following reactions is not correct as written? Br 1) NaOCH, major product сH, он Br 2) CH,CO Na major product сH,Cо...
3) Which of the following compounds is chiral? A) H Н-С-н н B) H HO C-OH Н C) CH3 HO-C-H Cl D) Br Н-С-ОН н E) C Br- C-C Br 4) In the L- isomer of a Fischer projection of a monosaccharide, the -OH group furthest from the carbonyl is written A) on the left of the top chiral carbon B) on the right of the top chiral carbon C) on the left of the middle chiral carbon D) on...
complete the following reactions.
a) i) 1. MgBr O 1. LICH2CH3 2. H20 2. H30+ j) b) 1. MgBr OCH3 1. CH3Li 2. H20 2. H30* c) k) OH 1. CH3 MgBr 2. H20 OH 1. CH3Li 2. H20 d) 1) MgBr 1. CH20 2. H307 1. (CH3)3CMgBr 2. H20 H 3 1. MgBr 2. H30* 1. Mg Br 2. CO2 3. H20 OCH3 n) f) 1. CH3CH2MgBr 2. H20 1. Li CI 2. CH3CH2OH OH o) g) Br 1....
H3 C H2Br Br2, H30* HC X CH3 HzC CH3 H3C CH3 Aldehydes and ketones can be halogenated at their a-position by reaction with Cl, Br, or 12, under acidic conditions. Using Br2 under acidic conditions, an intermediate enol is formed which adds bromine at the a-position. The reaction stops after the addition of one bromine because the electron-withdrawing halogen decreases the basicity of the carbonyl oxygen, making the protonation less favorable. Not started curved arrows to show the movement...
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