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An electrochemical cell is constructed in which a Cut(1.00 M)Cu(s) half-cell is connected to an H30+(aq)H2(1...
a.) A voltaic cell is constructed in which the cathode is a standard hydrogen electrode and the anode is a hydrogen electrode (P(H2) = 1 atm) immersed in a solution of unknown [H+]. If the cell potential is 0.204 V, what is the pH of the unknown solution at 298 K? b.) An electrochemical cell is constructed in which a Cr3+(1.00 M)|Cr(s) half-cell is connected to an H3O+(aq)|H2(1 atm) half-cell with unknown H3O+ concentration. The measured cell voltage is 0.366...
An electrochemical cell consists of a Pt|H+(aq,1.00 M)|H2(g) cathode connected to a Pt|H+(aq)|H2(g) anode in which the H+ concentration is that of a buffer consisting of a weak acid, HA(0.136 M), mixed with its conjugate base, A-(0.142 M). The measured cell voltage is E°cell = 0.196 V at 25 °C, with PH2 = 1.00 atm at both electrodes. Calculate the pH in the buffer solution and the Ka of the weak acid. pH = _______ Ka = _______
An electrochemical cell consists of a Pt|H+(aq,1.00 M)|H2(g) cathode connected to a Pt|H+(aq)|H2(g) anode in which the H+ concentration is that of a buffer consisting of a weak acid, HA(0.160 M), mixed with its conjugate base, A-(0.120 M). The measured cell voltage is E°cell = 0.228 V at 25 °C, with PH2 = 1.00 atm at both electrodes. Calculate the pH in the buffer solution and the Ka of the weak acid. pH = Ka =
8) An electrochemical cell consists of a Pt|H+(aq,1.00 M)|H2(g) cathode connected to a Pt|H+(aq)|H2(g) anode in which the H+concentration is that of a buffer consisting of a weak acid, HA(0.115 M), mixed with its conjugate base, A-(0.192 M). The measured cell voltage is E°cell = 0.168 V at 25 °C, with PH2 = 1.00 atm at both electrodes. Calculate the pH in the buffer solution and the Ka of the weak acid. pH = Ka =
A voltaic electrochemical cell is constructed in which the anode is a Pb2+Pb half cell and the cathode is a Cu2+, Cu+ half cell. The half-cell compartments are connected by a salt bridge. Write the anode reaction. ___+______---->_____ +______ Write the cathode reaction. ______+________---->______ +_____ Write the net cell reaction. _______+_______------>______ +_______ In the external circuit, electrons migrate_____(from or to) the Pb2+Pb electrode ______ (from or to) the Cu2+, Cu+ electrode. In the salt bridge, anions migrate______ (from or to)...
3. Consider the following electrochemical cell. Standard reduction potentials are given on the next page. Tl(s) | Tl+(aq, 0.50 mol L−1) || H+(aq, x mol L−1) | H2(g, 1 atm) | Pt(s) The concentration of H+ is unknown and the pressure of H2 is kept constant at 1 atm. The cell voltage is initially measured as 0.139 V, with the Pt | H2 | H+ half-cell acting as the cathode. (a) (6 marks) Write out the oxidation and reduction half...
A standard galvanic cell is constructed in which a Cu2+ Cut half cell acts as the cathode. Which of the following statements are correct? Hint: Refer to a table of standard reduction potentials. (Choose all that apply.) The anode compartment could be Hg? Hg. As the cell runs, anions will migrate from the Cu²+ Cu" compartment to the other compartment Cut is oxidized at the cathode. In the external circuit, electrons flow from the Cu2+Cut compartment to the other compartment...
An electrochemical cell consists of one half-cell that contains Ag(s) and Ag+(aq), and one half-cell that contains Cu(s) and Cu2+(aq). What species are produced at the electrodes under standard conditions? E° = +0.80 V Agt(aq) + e- → Ag(s) Cu2+(aq) + 2 e- → Cu(s) E° = +0.34 V O Ag(s) is formed at the cathode, and Cu(s) is formed at the anode. Ag(s) is formed at the cathode, and Cu2+ (aq) is formed at the anode. Cu(S) is formed...
Consider the following electrochemical cell: Pt | Cu2+ (aq) | Cu+ (aq) || Fe2+ (aq) | Fe3+ (aq)| Pt The cell is constructed by preparing one half-cell with a solution containing 8.33 * 10-3 M FeCl3 and 1.67*10-2 M FeCl2, and preparing the other half-cell with a solution containing 8.33*10-3 M CuCl2 and 0.025 M CuCl. Calculate the cell potential once the half-cells are connected to each other. E°(Cu2+/Cu+) = 0.16 V; E°(Fe2+/Fe3+) = 0.77 V
*A copper, Cu(s), electrode is immersed in a solution that is
1.00 M in ammonia, NH3, and 1.00 M in tetraamminecopper(II),
[Cu(NH3)4]2+. If a standard hydrogen electrode is used as the
cathode, the cell potential, Ecell, is found to be 0.070 V at 298
K.
A copper, Cu(s), electrode is immersed in a solution that is 1.00 M in ammonia, NH3, and 1.00 M in tetraamminecopper(II), [NH. If a standard hydrogen electrode is used as the cathode, the cell potential,...