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is this correct? 16. Draw the product below: н Br 7:S: O 1 HẠNG NHA 2....
2014 Reaction Quiz 2 (4 pages) Name: 1. Draw an expected product. 2. Assign R or S to anv stereocenter created in the product you show. A Product Starting Material Reagents or Reaction OsO, Н.с Br Br н.с Br -Br H -OH (NOT the same product as previous above) (water) н,с H, H20 Н,с H, H20 FAssign R or S! MCPBA IDENTICAL
16. [10 points] (a) Draw the major product(s) expected for the reactions shown below. Indicate stereochemistry in the product when appropriate. (b) Classify each reaction as SN2, Sn 1, E2 or E1 or a combination of these if applicable. Br (a) + Xe K (CH3)3COH CI (b) K acetone (c) xi C2H5OH, A Br # Na Өс,н, + (d) OC2H5 C2H5OH (e) CH31 xo + K (CH3)3COH
Draw the correct organic product for the following oxidation reaction: Na,Cr,O,/acetone н,so,
Is my naming correct?
CH3З CH3 Br .CH2CH3 (b) (a) НО CH2Br Н H Н (S)-1-bromo-2-propanal 3-bromopentane Br CH3 (d) (c) HIIl" H OH H OH CI CH3 (2S,3S)-2-bromo-3-chlorobutane (2S,3R)-2,3-butanediol / meso compound
1. Predict the product(s) (or no reaction) and reagent(s).
j. ETOH Br heat k. Br NaOH DMSO NaCN Br DMF m. РСС Н n. О H2SO4, H20 Н
Question 17 Predict the major product(s) for the reaction shown below. (choose all correct answers) Br2 ?? Br Br Br Br Br Br Br பி Question 18 Which of the reaction steps, shown below, would be part of the mechanism for the acid-catalyzed hydration of trans-but-2-ene? (choose all correct answers) OH но н-о-s-он + H нн H-O-S-OH Он + о H H онн нн :Он он H H нн O нн H-O-S-OH он + OH o=S-O
Draw a detailed mechanism for the following transformation 1. Br. Br HBr HO 2. What are the major product (s) formed in the following substitution reaction? Draw as Fisher projections CH;CH2ОH CH-CHз Нас— вr CH2CH2CH3 Draw the mechanism for the following reaction. 3. HO Br Draw the major organic product(s) produced in the following reaction as Fischer projection. 4. CHз ОСHЗ Н NaN3 Н. -CH3 Н- Br DMSO CH3 Draw the mechanism for the following reaction to demonstrate how the...
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Which of the following reactions is not correct as written? Br 1) NaOCH, major product сH, он Br 2) CH,CO Na major product сH,Cо Н Br 3) CH,CH,SNa major product DMF A 1) and 2) are incorrect 2) and 3) are incorrect C 3) is incorrect D 2) is incorrect E All are correct
Which of the following reactions is not correct as written? Br 1) NaOCH, major product сH, он Br 2) CH,CO Na major product сH,Cо...
s) Predict the principal organic product(s) in each of the following reactions. Draw the correct stereoisom wherever applicable (Structures with incomplete/wrong stereochemistry will not be accepted!!). CH₃ Clz Br2 Н,0 CCIA 1) BH3. THE 2) H2Oz/NaOH 1) O₃ 2) (CH3)2S МСРВА MCPECIES CH2Cl2 OsO4 NMO 1) МСРВА 2) H2O/H30* Hoy for Hos 1) Brz/H20 2) NaOH 1) Hg(OAC)2, H2O/THF 2) NaBHA = 1) O₃ 2) H20 340 H2SO4 HgSO4 2 Brz CCIA 2 HCI 26. pts) Listed below is information...
7. Draw the structure of the missing major organic product(s) for each of the following reactions. There is no “No Reaction in any of the answers. Show correct stereochemistry when needed! NO ON Na S204 (excess) NaOH, H20, heat Sebacoyl chloride PhCH OH OH (excess) 0 H2SO4, heat Aryl Bromide 1) Mg, THF 2) CH2=0 3) H20, H307 PhCH,CH,OH1 H2SO4 (catalytie) T heat H2Cro (excess)