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4. Predict the Product: NaBHA MeOH 1. LAH 요 2. H30* Ph3P li Php NaOEt EtOH...
4. Draw the products of the following sequences of reactions. 1) NaOET, HOE 1) NaOEt Eto OEt 2) H3O+ 2) Br | 1) LDA, -78°C 2) 0 H30+ heat H 3) NaOH, heat 1) LDA (1.1 equiv), -78°C, THE 2) CH3Br 1) CH3CH2MgBr 2) H30* H2, Pd-C LU H2SO4 NaOH, H2O 1) LDA, -78°C 2) HOE 3) H30+ 1) O3 2) CH2SCH3
1) Reactions. Provide the major product for each reaction sequence, account for stereochemistry 1) PCC, CHCI 2) Bry, acetic acid 3) KOBU, A 4) NaOEI, ETOH, P CO- 5) H30 workup 6) THF, H.COPPA HC CH2 O e .cat. Pd(OAc) cat. PPh. DMF, EIN 2) LDA, THF. -78 °C 3) Chichen H3O* workup 4) NaBH, EtOH, then H3O+ workup 5) cat. TSOH, benzaldehyde (c) L AL SUO TESTE TO 1) cat. H2SO4. A лон 2) O3, CH, Cl, then (CH),...
2) CHs LDA 1) LDA 3 2) Ci OH, H20 -OH, H2O CHO 1 LDA 2) CH3CH2Br Он, H2O 1) NaOEt 8 2) NaOEt OEt 10 Cl NaH 2 (excess) 12 HO Bra(excess) 13 HO LDA 14L THF, -78 C NaOEt, EtOH NaOEt, EtOH 16 NaOEt, EtOH 17 Br но 18 OOEt 1)NaOEt, EtOH 2) H3O 19 OEt 20 l HO o CHO + H20
Need Help. Will Rate If Complete.
1) NaoEt, EtOH Br 2) O 3) H30+ / A. 1) NaoEt, EtOH (s) ar 2) Y Br 3) Hz0+ / A 1) NaOme/MeOH ~ Br OMe 3) Hz0+/A. 1) NaOEt, EtOH 2) V Br 3) NaOEt, EtOH COOEt 5) H30+/A Robinson Annulation NaoEt, EtOH/A come lui OMe 28- The following molecules can be formed by either: Michael Reaction; Enamine Acylation; Acetoacetic Ester Synthesis; Michael Addition; Malonic Ester Synthesis; Robinson Annulation; Aldol Condensation; Claisen...
Predict the products of the reaction
ter 1) Li (2 equiv) / hexane 2) CuCN Br 3) I. 4) H30+ / H20 1) Br2 / H20 2) NaH 3) H2SO4 (dil), EtOH 4) PCC, DCM J.
Predict the major organic product of the following reaction and complete its mechanism below. 1) NaOEt/EtOH 2) CH3CH2CH2Br 3) dilute NaOH/heat 4) H30* 5) heat Complete the curved-arrow mechanism for the scheme below by adding any missing atoms, bonds, charges, nonbonding electrons, and curved arrows. :O O: :Br. CH3CH2OH Do not show curved arrows for this step. Added acid Dilute HH NaOH and heat hydrolyzes the ester. O: Na Br - H20, Na* O: 100-150 °C O:
1. Predict the major product for the reactions shown below; pick any 5: HO xs CHal Ag20 NaOEt EtOH, Δ -H2O HO но он 0 он H2SO4 H20, A heat 1) PhMgBr 1) NaOH, Br2 2) 5% HCI 2)H3O+, Δ OEt 1) PPh3 3) KOtBu 2) O 1) NaOH on. Br 2) O o
1. Predict the major product for the reactions shown below; pick any 5: HO xs CHal Ag20 NaOEt EtOH, Δ -H2O HO но он 0 он...
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the reagent list handout Step 1 Step 2 Step 3 OH Alkyl Halides (X = CI, Br or 1) and Acyl chlorides: Assume Allig 15 present, if needed CIP CU CH3X X CI E A B EE Ketones. Aldehydes and Epoxides: Assume "then H20" is included if a protonation step is needed F A A K 0 MN Р Grignard, Wittig and Organocuprate Reagents: Assume...
Propose an efficient synthesis for the transformation below,
using two sequential reductive aminations. Enter
the appropriate number or letter from the reagent list handout.
Propose an efficient synthesis for the transformation below, using two sequential reductive aminations. Enter the appropriate number or letter from the reagent list handout. Step 1 + NaBH3CN, H+, Step 2 - NaBH3CN, H+ Reagent List (Updated 4/30/2020) Enter # or letter in the appropriate boxes. Note: Exam responses are case insensitive Alkyl Halides (X = Cl,...
Ph cyclopropene HF CH h) OH 1. POCICH.Ch 2. Pri 3 NH4Cl ag) 1.) 1. Li/THE 2.CO 3.NH.CH HNO k.) NH 1. HNO (aq) 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCU. n) -OH XS H.CO acetone он 0.) OH XS Bobbit's SiO, CH.CH -OH 1. Ch. AICI 2 NaOH, 30 C 4,000 psi 3. HCI 9.) SCH 2Na, ETOH, NH, r.) 1. LIETO 2. oxirane 3. H,00 1.2 PY-MOBI OMe 2. NHCl(aq) t.) 1. Cl/ Feer...