I am having so much difficulty with this lab report. Can someone help me with the calculations?
Determining the wavelength of H-spectrum lines in the Balmer series:
λBalmer(Å) Table:
n | λBalmer(Å) |
3 | 6563.052 |
4 | 4861.52 |
5 | 4340.643 |
6 | 4101.908 |
Determining the Rydberg's constant:
Calculation table:
i\θ | (θiSC)1 | (θiSC)2 | (θiSC)3 | <θiSC> | θi=<θiSC>-θ0 | Sin θi | λ(nm) | λ(Å) | Nearest λBalmer(Å) |
n assigned |
1/n2 | 1/λ(cm) |
δ | 144 | 144.05 | 144.05 | 144.0333 | 14.03333 | 0.24248635 | 410.7154 | 4107.154 | 4101.908 | 6 | 0.027778 | 2434.776 |
ɣ | 144.8833333 | 144.8833333 | 144.9166667 | 144.8944 | 14.89444 | 0.25703909 | 435.3643 | 4353.643 | 4340.643 | 5 | 0.04 | 2296.927 |
β | 146.6666667 | 144.75 | 144.7166667 | 145.3778 | 15.37778 | 0.26518217 | 449.1568 | 4491.568 | 4340.643 | 5 | 0.04 | 2226.394 |
α | 152.9166667 | 153 | 153 | 152.9722 | 22.97222 | 0.39028481 | 661.0515 | 6610.515 | 6563.052 | 3 | 0.111111 | 1512.741 |
Plotting 1/λ(cm) vs 1/n2:
Slope= - 10807 cm-1
Rydberg's constant, R= - Slope=10807 cm-1
Taking n(assigned)=4 for β:
i\θ | (θiSC)1 | (θiSC)2 | (θiSC)3 | <θiSC> | θi=<θiSC>-θ0 | Sin θi | λ(nm) | λ(Å) | Nearest λBalmer(Å) |
n assigned |
1/n2 | 1/λ(cm) |
δ | 144 | 144.05 | 144.05 | 144.0333 | 14.03333 | 0.24248635 | 410.7154 | 4107.154 | 4101.908 | 6 | 0.027778 | 2434.776 |
ɣ | 144.8833333 | 144.8833333 | 144.9166667 | 144.8944 | 14.89444 | 0.25703909 | 435.3643 | 4353.643 | 4340.643 | 5 | 0.04 | 2296.927 |
β | 146.6666667 | 144.75 | 144.7166667 | 145.3778 | 15.37778 | 0.26518217 | 449.1568 | 4491.568 | 4861.52 | 4 | 0.0625 | 2226.394 |
α | 152.9166667 | 153 | 153 | 152.9722 | 22.97222 | 0.39028481 | 661.0515 | 6610.515 | 6563.052 | 3 | 0.111111 | 1512.741 |
Plotting 1/λ(cm) vs 1/n2:
Slope= - 10958 cm-1
Rydberg's constant, R= - Slope=10958 cm-1
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