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А Treatment of (S)-(+)-5-methyl-2-cyclohexenone with lithium dimethylcuprate gives, after protonolysis, a good yield of a mixture...
Trearment of (S)-(+)-5methylcyclohex-2-enone with lithium dimethlycuprate gives, after protonolysis, a good yield of a mixture containing mostly dextrorotary Ketone A and a trace of optically inactive isomer B. Treatment of A with zinc amalgam and HCl affords opticlly active hydrocarbon C (C8H16). Compound B, which exhibits only 5 unique signals in its 13C NMR spectrum, undergoes an aldol condensation with NaOEt and benzaldehyde to produce optically active compound D. Identify componds A-Dincluding stereochemical configurations. Treatment of (S)- (+-5-methylcyclohex-2-enone with lithium...