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Question 2: Which of the following enolate ions is formed under thermodynamic conditions? Briefly explain your...
4. (2 pts) Consider the enolate forming reaction below. Provide the structure of the enolate anion formed in this reaction (only need to provide one resonance contributor). HiC o: H2C Нас pKa -20 pKa -33 Enolate oti (2 pts) Based on the information provided, do you expect the favored enolate to be the kinetic or thermodynamic enolate? Briefly explain.
Which will likely be more soluble in water, MgO or NaCl? Explain briefly the thermodynamic reason for your answer.
Is the following reaction performed under kinetic or thermodynamic conditions? EtO ! CHÚCH CHO A • Thermodynamic Kinetic Question 7 2 pts Classify the following reaction as a C-C Bond forming reaction or a Functional Group Transformation. HBr G-C Bond Forming Funct. Group Trans. Question 8 2 pts Classify the following reaction as a C-C Bond forming reaction or a Functional Group Transformation но Ph 1. PhLi 2. H0+ C-C Bond Forming Funct. Group Trans. Question 9 2 pts
second part of question is important. Label which is made under thermodynamic and kinetic control 1. (10pts) Provide the missing reagents/conditions and the products for each reaction. Also please label which product is made under thermodynamic and kinetic control. Br Br
question 1 and 3 can you form an enolate ion under acidic conditions? If so, provide the mechanism for its formation. 2. Draw the enol tautomer of the following compounds. arbonyl and base cucido eprotonatohy - a carbon hol-acid molate= bast CHAPTL! 3. Some compounds can form more than one enol tautomer. Draw all the possible enol tautomers for the following compounds. 4. Circle the side of the reaction favored at equilibrium. + OH н + H2O pka = 15.7...
7. Under the following conditions, three products are formed in this reaction. OH H2O a. Draw the mechanism that leads to the product that is the least likely to form in the space below. (7pts) b. In the space below, explain why that product is the most likely to form. You should be able to justify your answer. (4pts)
3.1 Predict the structure of the product formed in the monohalogenation the following compound, briefly explain your answer (do not forget to draw your predicted product (8 marks) NH2 HO NO2 3.2 Refer to question 3.1 above, write a full mechanism for the bromination of the given structure, (show the formation of the electrophile and the formation of the product) (10 marks)
Consider the following reaction under basic conditions: NO−2(aq)+Al(s)⟶NH3(g)+AlO−2(aq) How many hydroxide ions will appear in the balanced equation? Enter your answer as a whole number without any decimal places.
1. For the following Alkyl halide indicate which position will react under SN1 reaction conditions and under SN2 reaction conditions. Explain your answer. BEBE 2. Draw the complete mechanism and the products for of the following SN1 reaction paying close attention to stereochemistry. HyCc CH OH CH CHE
1. Draw a mechanism for the following Aldol condensation reaction under basic conditions, including the formation of the enolate. Please include ALL lone pair electrons, formal charges, and stereo/regiochemistry whenever applicable. 1) LDA, H2O 2) LAH 2. Draw a mechanism for the following Dieckmann reaction under basic conditions, including the formation of the enolate. Please include ALL lone pair electrons, formal charges, and stereo/regiochemistry whenever applicable. 1) NaOEt 2) Hзо* OEt 3. Draw a mechanism for the following alkylation reaction...