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12. Michael Reactions - Place an A (for Acceptor) or a D (for Donor) in the...
12. Michael Reactions - Place an A (for Acceptor) or a D (for Donor) in the...
12. Michael Reactions - Place an A (for Acceptor) or a D (for Donor) in the box indicating the correct Michael moiety. OMe OET CEN NOZ Eto 0 13. What is the product of the following reactions? 1. (CH2CH),Culi O 1. KOH OEt 2.H30* H 3.H20- 14. The Stork reaction uses which functional group intermediate? 15. Use Stork reactions to filling in the missing information: 1. (CH3)2NH, [HⓇ], heat glo 2. 2 H 0 3. 3. H2O+ 16. Propose a...
12. Michael Reactions - Place an A (for Acceptor) or a D (for Donor) in the...
12. Michael Reactions - Place an A (for Acceptor) or a D (for Donor) in the box indicating the correct Michael moiety. OME OE! EN: NO2 Eto 13. What is the product of the following reactions? 1. (CH,CH, Cumi O 1. KOH OEt 2. H,00 2. H 3. H0 14. The Stork reaction uses which functional group intermediate? 15. Use Stork reactions to filling in the missing information: 1. (CH3)NH, [H*), heat 1. go 2. 2. H 3. 3. H,07...
Show Timer Question Completion Status: Name each of the reactions below by placing the number of...
Show Timer Question Completion Status: Name each of the reactions below by placing the number of the reaction name on the line with the corresponding letter: 1. malonic acid synthesis 2. Acetoacetic acid synthesis 3. Aldol synthesis 4. Claisen Condensation 5. Dieckman Condensation 6. Michael Reaction 0 Oet EtOC(CH)=COET- ndani 1. ya and B 0 OH H3C-C- H H -C-CH2CHCH3 CH3COCH CH3 CH3CCH,COEt R-X- RCH,COH R-X → RCH,COCH; AO EDOC(CH2);COE- OET BO OH H-C-CH2CHCH3 HzC—C—H со Combocco, c CH3COCH-CH3 CH3CCH...
Hi I need help predicting the products for these reactions OEt NaOCH.CH CH,CH OH b. H,...
Hi I need help predicting the products for these
reactions
OEt NaOCH.CH CH,CH OH b. H, O/H,0 a. NaOCH.CH CH,CH,OH b. Br c. NaOHH O, beat d. H2O*/H2O 1. NaCN, DMSO 2. CH,MgBr, Eto 3. H.O/H,O EN 2. NaH, CH,Br chemoselective 1. a. NaOet, EtOH Br b. 2. a. NaOH/H,O, heat b. H30+/H20 CY.NECEN cy OH b. then add HC-NH2 a. NaCN, DMSO b. HO*/H,0
12. What would be the major product of the following reaction? i. Brz, NaOH ii. H20"...
12. What would be the major product of the following reaction? i. Brz, NaOH ii. H20" ? mo Br НО. O II III Br Br ho IV A. I B. II C. III D. IV E. V 13. What would be the major product of the following reaction sequence? A. I B. II C. III D. IV E. V 2 i. LDA ii. CHEI De ci II I III IV V 14. Which of the following could be used to...
RAH CC + (CH) Cả b. Be o RC + 2 CH3NH, CH.CH OH OCHO +...
RAH CC + (CH) Cả b. Be o RC + 2 CH3NH, CH.CH OH OCHO + CHCH,OH Habys o doronde TNHH R OH + CH3CHÚNH OH – Donc logo 1. CH3MgBr CH CH CH.CH2. Hy0 3-pentanone + (CH.CH) Culi- R acyl chloride h ITSE HCI R + R(H) CON excess 1. (CHCHCH2), AIH-78 °C 2. H20 CH,CH,CHOCH, 1. NaBHA RCEN 2. H2O NaBHA RC=CR Section 4. Total points 26 1. Give one example of each of the following name reactions....
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the...
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the reagent list handout Step 1 Step 2 Step 3 OH Alkyl Halides (X = CI, Br or 1) and Acyl chlorides: Assume Allig 15 present, if needed CIP CU CH3X X CI E A B EE Ketones. Aldehydes and Epoxides: Assume "then H20" is included if a protonation step is needed F A A K 0 MN Р Grignard, Wittig and Organocuprate Reagents: Assume...
4. [12 pts] Propose mechanisms for the formation of all 3 products shown in the reaction...
4. [12 pts] Propose mechanisms for the formation of all 3 products shown in the reaction below: (draw curved arrows, intermediates, and resonance structures if necessary. NO NEED FOR TRANSITION STATES! CH CH CH CH Br Heat CH,CH,OH OCH.CH Mechanism.14 points) Mechanism 2 points) Mechanism.3 14 points) 5. [14 pts] Provide the major products of reacting the alkene shown in the middle of the scheme below with all the reagents independently. Draw the products' structures in the corresponding table below...
question 7 8 9 10 11 12 (7) Use HSAB theory to predict the following reactions...
question 7 8 9 10 11 12
(7) Use HSAB theory to predict the following reactions will go or not go (a) CH3-CH3 + H2O → CH,OH+CH (AH = 12 kcal/mol) (b) CH3COCH3 + H2O → CH3COOH + CH, (AH--13 kcal/mol ) (6%) (8) Predict the order of solubility: (9%) (a) MgSO4, CaSO4, SISOs, and Baso. (c) AgF, AgCl, AgBr, and Ag! (b) PbCI, PbBry, and Pbi! (9) List the following acids in order of acid strength in aqueous solution:...
What results when a secondary alcohol is oxidized? a. a ketone d. an acid b. an...
What results when a secondary alcohol is oxidized? a. a ketone d. an acid b. an amine e. no reaction c. an aldehyde Which of the following combinations will react spontaneously? A. 12 + Cu2+ B. Pb2+ + Ag C. Zn2+ + Mg D. Sn2+ + Ni2+ The general formula for a cycloalkane can be represented by which of the following? a. C,H, C. CH b. C.H2n+2 d. C.H21-2 In a certain reaction AH =-136 kJ and E, = 96...
12. Michael Reactions - Place an A (for Acceptor) or a D (for Donor) in the box indicating the correct Michael moiety. OMe OET CEN NOZ Eto 0 13. What is the product of the following reactions? 1. (CH2CH),Culi O 1. KOH OEt 2.H30* H 3.H20- 14. The Stork reaction uses which functional group intermediate? 15. Use Stork reactions to filling in the missing information: 1. (CH3)2NH, [HⓇ], heat glo 2. 2 H 0 3. 3. H2O+ 16. Propose a...
12. Michael Reactions - Place an A (for Acceptor) or a D (for Donor) in the box indicating the correct Michael moiety. OME OE! EN: NO2 Eto 13. What is the product of the following reactions? 1. (CH,CH, Cumi O 1. KOH OEt 2. H,00 2. H 3. H0 14. The Stork reaction uses which functional group intermediate? 15. Use Stork reactions to filling in the missing information: 1. (CH3)NH, [H*), heat 1. go 2. 2. H 3. 3. H,07...
Show Timer Question Completion Status: Name each of the reactions below by placing the number of the reaction name on the line with the corresponding letter: 1. malonic acid synthesis 2. Acetoacetic acid synthesis 3. Aldol synthesis 4. Claisen Condensation 5. Dieckman Condensation 6. Michael Reaction 0 Oet EtOC(CH)=COET- ndani 1. ya and B 0 OH H3C-C- H H -C-CH2CHCH3 CH3COCH CH3 CH3CCH,COEt R-X- RCH,COH R-X → RCH,COCH; AO EDOC(CH2);COE- OET BO OH H-C-CH2CHCH3 HzC—C—H со Combocco, c CH3COCH-CH3 CH3CCH...
Hi I need help predicting the products for these
reactions
OEt NaOCH.CH CH,CH OH b. H, O/H,0 a. NaOCH.CH CH,CH,OH b. Br c. NaOHH O, beat d. H2O*/H2O 1. NaCN, DMSO 2. CH,MgBr, Eto 3. H.O/H,O EN 2. NaH, CH,Br chemoselective 1. a. NaOet, EtOH Br b. 2. a. NaOH/H,O, heat b. H30+/H20 CY.NECEN cy OH b. then add HC-NH2 a. NaCN, DMSO b. HO*/H,0
12. What would be the major product of the following reaction? i. Brz, NaOH ii. H20" ? mo Br НО. O II III Br Br ho IV A. I B. II C. III D. IV E. V 13. What would be the major product of the following reaction sequence? A. I B. II C. III D. IV E. V 2 i. LDA ii. CHEI De ci II I III IV V 14. Which of the following could be used to...
RAH CC + (CH) Cả b. Be o RC + 2 CH3NH, CH.CH OH OCHO + CHCH,OH Habys o doronde TNHH R OH + CH3CHÚNH OH – Donc logo 1. CH3MgBr CH CH CH.CH2. Hy0 3-pentanone + (CH.CH) Culi- R acyl chloride h ITSE HCI R + R(H) CON excess 1. (CHCHCH2), AIH-78 °C 2. H20 CH,CH,CHOCH, 1. NaBHA RCEN 2. H2O NaBHA RC=CR Section 4. Total points 26 1. Give one example of each of the following name reactions....
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the reagent list handout Step 1 Step 2 Step 3 OH Alkyl Halides (X = CI, Br or 1) and Acyl chlorides: Assume Allig 15 present, if needed CIP CU CH3X X CI E A B EE Ketones. Aldehydes and Epoxides: Assume "then H20" is included if a protonation step is needed F A A K 0 MN Р Grignard, Wittig and Organocuprate Reagents: Assume...
4. [12 pts] Propose mechanisms for the formation of all 3 products shown in the reaction below: (draw curved arrows, intermediates, and resonance structures if necessary. NO NEED FOR TRANSITION STATES! CH CH CH CH Br Heat CH,CH,OH OCH.CH Mechanism.14 points) Mechanism 2 points) Mechanism.3 14 points) 5. [14 pts] Provide the major products of reacting the alkene shown in the middle of the scheme below with all the reagents independently. Draw the products' structures in the corresponding table below...
question 7 8 9 10 11 12
(7) Use HSAB theory to predict the following reactions will go or not go (a) CH3-CH3 + H2O → CH,OH+CH (AH = 12 kcal/mol) (b) CH3COCH3 + H2O → CH3COOH + CH, (AH--13 kcal/mol ) (6%) (8) Predict the order of solubility: (9%) (a) MgSO4, CaSO4, SISOs, and Baso. (c) AgF, AgCl, AgBr, and Ag! (b) PbCI, PbBry, and Pbi! (9) List the following acids in order of acid strength in aqueous solution:...
What results when a secondary alcohol is oxidized? a. a ketone d. an acid b. an amine e. no reaction c. an aldehyde Which of the following combinations will react spontaneously? A. 12 + Cu2+ B. Pb2+ + Ag C. Zn2+ + Mg D. Sn2+ + Ni2+ The general formula for a cycloalkane can be represented by which of the following? a. C,H, C. CH b. C.H2n+2 d. C.H21-2 In a certain reaction AH =-136 kJ and E, = 96...
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