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12. Michael Reactions - Place an A (for Acceptor) or a D (for Donor) in the...
12. Michael Reactions - Place an A (for Acceptor) or a D (for Donor) in the box indicating the correct Michael moiety. OMe OEt NO, Eto 0 0 13. What is the product of the following reactions? 0 OEt 1. (CH,CH) CuLi 01. KOH 2. Hj0+ 2. H 3. H,0* 14. The Stork reaction uses which functional group intermediate? 15. Use Stork reactions to filling in the missing information: 1. (CH2)2NH, [H+], heat 1, . 2. 2. 0 3. 3....
12. Michael Reactions - Place an A (for Acceptor) or a D (for Donor) in the box indicating the correct Michael moiety. OMe OET CEN NOZ Eto 0 13. What is the product of the following reactions? 1. (CH2CH),Culi O 1. KOH OEt 2.H30* H 3.H20- 14. The Stork reaction uses which functional group intermediate? 15. Use Stork reactions to filling in the missing information: 1. (CH3)2NH, [HⓇ], heat glo 2. 2 H 0 3. 3. H2O+ 16. Propose a...
The Stork reaction is a condensation reaction between an enamine donor and an a,B-unsaturated carbonyl acceptor. The overall reaction consists of a three-step sequence of 1. formation of an enamine from a ketone, 2. Michael addition to an a,B-unsaturated carbonyl compound, and 3. hydrolysis of the enamine in dilute acid to regenerate the ketone. Consider the Stork reaction between acetophenone and 3-buten-2-one. 1 Draw the structure of the product of the enamine formed between acetophenone and dimethylamine. N - O...
Classify the following substituents a acceptor d = donor n = no effect CO: 1. Inductive effect . Resonance effect CH-C 00% 2. Inductive effect Resonance effect . 3. Inductive effect Resonance effect CO. benzenesulfonyl
complete the following reactions: fill in the blanks (A, B, and C) with the appropriate number. thanks COMPLETE LITE THE FOLLOWING RxNs Eto 0 Na OEL C B Z 1. CH₃ Bc 2.) CH₃ CH₂ B Eto 6.) Eto 3) CH3 CH₂ CH₂ Br O Eto 1) H0* 8. Her 9 H₂O +, Hear
2. Give the products for four of the five reactions below, If you do all five, I will grade the first four in order. (12 points) heodsoM-0arE nteimsd 3 H,0 /H20/ A NMe To oe EOH/Pyridine +3 OH 43 MeOH/H/ A OH wa 2 eq. EtLi OMe then H,O 3. Give the product for the following acetoacetic acid ester synthesis. Draw the transition state for the decarboxylation. (5 points) O 1. EtONa /PhCH Br Na OEt 2. HO/A 2. Give...
Hi I need help predicting the products for these reactions OEt NaOCH.CH CH,CH OH b. H, O/H,0 a. NaOCH.CH CH,CH,OH b. Br c. NaOHH O, beat d. H2O*/H2O 1. NaCN, DMSO 2. CH,MgBr, Eto 3. H.O/H,O EN 2. NaH, CH,Br chemoselective 1. a. NaOet, EtOH Br b. 2. a. NaOH/H,O, heat b. H30+/H20 CY.NECEN cy OH b. then add HC-NH2 a. NaCN, DMSO b. HO*/H,0
28. A Lewis Acid is an electron A) donor B) acceptor C) eliminator D) coupler 29. A process has a AH of 8.5 kJ/mol and a AS of 35.2 J/mol-K. What is AG at 300 K for this process? A) -23.0 kJ/mol B) -2.06 kJ/mol C) +33.4 kJ/mol D) +1.24 kJ/mol 30. A spontaneous voltaic cell is based on the following two standard half-reactions: ()+ 2e → CdEred (Ca/Cd)--0.40 V + 2e → Sn Ered (Sn™/Sn) - -0.14 V What...
46) What is the major product formed in the 4-step reaction sequence? Io non o od NH C AICI NO2 2) H0 3) HNO3, H2SO4 4) H2NNH, KOH 47) What is the final product formed in the following sequence of reactions? NHCOCH3OH 1) H,SO./H201) NaNO,, HCI ? heat Conc. H,SO 2 ) H3PO, SOGH 2) dilute NaOH NH21 oor hoe oud SO,H 48) Which of the following reactions would occur as written? Select all that apply. O CHOCI Snc 1)...
Show Timer Question Completion Status: Name each of the reactions below by placing the number of the reaction name on the line with the corresponding letter: 1. malonic acid synthesis 2. Acetoacetic acid synthesis 3. Aldol synthesis 4. Claisen Condensation 5. Dieckman Condensation 6. Michael Reaction 0 Oet EtOC(CH)=COET- ndani 1. ya and B 0 OH H3C-C- H H -C-CH2CHCH3 CH3COCH CH3 CH3CCH,COEt R-X- RCH,COH R-X → RCH,COCH; AO EDOC(CH2);COE- OET BO OH H-C-CH2CHCH3 HzC—C—H со Combocco, c CH3COCH-CH3 CH3CCH...