1. The body can break down alcohol through the following reaction: ethanol + NAD + acetadehyde...
The body can break down alcohol through the following reaction: ethanol + NAD +→ acetadehyde + NADH + H+ Calculate Delta G* for this reaction at 25C. The standard reduction potentials are: ethanol →acetaldehyde + 2H+ + 2e- E = -0.197V NAD+ + H+ + 2e- → NADH E= -0.320V 1. The body can break down alcohol through the following reaction: ethanol + NAD* acetadehyde + NADH+H* Calculate AGº for this reaction at 25°C. The standard reduction potentials are: ethanol...
Question 2a (1 pt): Alcohol dehydrogenase catalyzes the reversible reaction shown. In the space below, write the two half-reactions for the redox reaction. Then, determine the cell potential (AE) and standard Gibbs free energy change (AG) for the reaction. (Hint: Use Tables 13.7a/b in "Metabolism Overview") Acetaldehyde + NADH+H→ Ethanol + NAD Question 2b (1 pt): Under physiological conditions, the reaction actually proceeds in the direction that has a positive AG. What would be the minimum value of the reaction...
For the reaction: L-Malate + NAD⁺ ← → Oxaloacetate + NADH ΔE' = -0.154 n=2 T=298 K using the equation ln (Keq) = (nFΔE'৹)/(RT) Find Keq? I know this sounds just plug and chug but am confused about the signs of the numbers when plugged in. Please only answer if you're of what you're doing! Standard Reduction Potential of Some Biologically Important Half-Reactions, at pH 7.0 and 25°C (298 K) Half-reaction E' (V) 2H+ + 2e — H, (at standard...
A) In this reaction, Acetaldehyde + NADH + H+ --> ethanol + NAD+ 1. Acetaldehyde is the reducing agent 2. Acetaldehyde is the oxidizing agent 3. NAD+ is oxidized 4. NADH is the oxidizing agent B) In ATP synthase complex, the F0 portion: 1. serves as proton channel 2. goes through conformational change to release ATP 3. oversees transport of ATP from mitochondria of eukaryotic cells 4. pumps proton against concentration gradient
If anyone can provide help that would be great! Thanks! Calculate the actual AG for the reaction in which molecular oxygen is reduced by the electron carrier NADH. 1202 + NADH+H→ H2O + NAD The concentrations of O2 and NADH are 1.00M and H20 and NAD are 0.100M. The relevant half reactions and their E values are: (1) % O2 + 2H+ +2e → H20 (2) NAD + H+ +2e → NADH E' = 0.816 V E' = -0.320 V
the reaction, acetaldehyde + NADH + H+ --> ethanol + NAD+, occurs during? 1. aerobic catabolism of glucose 2.preparation phase of glycolysis 3. anaerobic catabolism of glucose in muscle cells 4. anaerobic catabolism of glucose in yeast
Name Standard Reduction Potentials of Some Biologically Important Half-Reactions TABLE 13-7 Amino acids pki k2 pkR Half-reaction 2.34 9.60 2.34 9.69 1.99 10.96 2.32 9.62 2.36 9.60 2.36 9.68 Ubiquinone + 2H+ + 2e-→ ubiquinol + H: 0.045 Fumarate:-+ 2H. + 2e-→ succinate"- 2H+ + 2e-→ H2 (at standard conditions, pH 0) 0.000 Crotonyl-CoA+2H +2butyryl-CoA0.015 Oxaloacetate:-+ 2H+ + 2e-→ malate"--0.166 Pyruvate +2H2elactate Acetaldehyde + 2H+ + 2e-→ ethanol FAD +2HFADH2 Glutathione + 2H+ + 2e- Alanine Proline 0.031 228 921...
Q7) Using Table 9.1 (page 294) in your textbook and/or in the slides of chapter 9 (online material), determine the standard free energy (AG) for the following reaction in kJ/mol. [Faraday constant = 96.5 kJ/V] [10 points) FADH2 + 1/202 - FAD + 2H+ + H:0 Show detailed calculation. Final answer without clear work will not be considered. TABLE 9.1 Standard Reduction Potentials Redox Half-Reaction 2H+ + 2e" - H a-Ketoglutarate + CO, + 2H+ 2e isocitrate NADP+ + H+...
In one step of glycolysis, glyceraldehyde 3-phosphate is oxidized by NAD+ to yield 3-phosphoglycerate and NADH. 1) Consider that reaction, in the direction written. Which chemicals) is(are) losing electrons, and which chemical(s) is(are) gaining electrons? It's best to answer this in a clear complete sentence. 2 2 2 Table 10-2 Standard Reduction Potentials for Redox Pairs of Biological Relevance* Redox Pair Number of (oxidized form → reduced form) Electrons E.(V) acetate pyruvate 2 -0.70 succinate → a-ketoglutarate 2 -0.67 acetate...
TABLE 13-7 Standard Reduction Potentials of Some Biologically Important Half Half-reaction Ero (V) 0.816 0.421 NO 2H + 2e >NO H20 Cytochrome f(Fcytochromef Fe) 0.365 Fe(CN) (ferricyanide) +eFe(CN)6 0.36 Cytochrome a3 (Fecytochrome az (Fe*>) 035 0.295 Cytochrome a (Fe3 +cytochrome a (F 0.29 Cytochrome c Fcytochrome c (Fe) 0254 Cytochrome cl (Fe3-ㄧ˙-cytochrome cl (Fe2+) 0.22 Cytochrome (Fecytochrome (Fe 0.077 Ubiquinone 2H 2eubiquinol Fumarate+2H+2esuccinate2 2Ht+2e-H2 (at standard conditions, pH0)0.000 Crotonyl-CoA 2H 2e butyryl-CoA Oxaloacetate+2Ht+2e- malate Pyruvate+ 2H 2elactate Acetaldehyde 2H+2e-ethanol FAD...