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6) Draw the starting materials required to make the following product. 5pts A fi 7) Provide...
Post- Laboratory Questions: 1. Draw the product of the following Diels-Alder reactions 2. What starting materials would be used to prepare the following compound by the Diels- Alder reaction? 3. Cyclopentadiene dimerizes easily. Before using cyclopentadiene in a reaction, it is necessary to crack the diene. Draw the Diels-Alder reaction for the dimerization of cyclopentadiene. 4. What are the products of the following Diels-Alder reactions? Show the stereochemistry where applicable
9) Draw the product(s) for the following reaction. 3pts 1 eq. HNO3 H2S04 10) Select the product for the following reaction. 2pts Excess HNO3 ? H2SO4 1hr NO2 NO2 NO2 -NO2 B с D NO2 NO2 11) Provide the full mechanism for the following reaction (use as much space as you need). 5pts HNO3 NO2 H2SO4
2) Predict the starting materials for the following Diels-Alder product: ० H क 3) Some highly fused ring systems can be made through an intramolecular Diels-Alder reaction. Suggest a mechanism for the following reaction:
1. The following reactions begin with starting materials of differing stereochemistry yet each provide the same stereoisomer of the product. Explain this observation using an arrow-pushing mechanism. Tsoo- сн,со, CH3CO2H CH,CO, CH3CO2H
1. The following reactions begin with starting materials of differing stereochemistry yet each provide the same stereoisomer of the product. Explain this observation using an arrow-pushing mechanism Tso сH,со; CH-со,н TsO CH,со, CH3CO2H
Organic chemistry 1 questions Please answer #6, 7, and 9 Provide the structures a the two major organic products generated upon completion of the following reaction scheme. 7 . Predict the product and provide a curved arrow mechanism for the formation of the product. 9.(5pts) For the following reaction draw the two major organic products produced.
In the reactions below you are given a product and enough the starting materials information about the formation of the product to provide 1. Th followling as munde usiig a Dicls-Alder reuction Provide the rouctants and reaction conditiows The foliowing product was made starting with benzene -provide all steps of the reaction and reaction conditions 2. 3. The following was made in an enamine synthesis-provide the starting materials and reaction condit Aromaticity-3 points each Please classify the following compounds us...
ASAP 6.(8) a. The 1,2 addition product of the reaction is shown. Draw the 1,4 addition product. HBr 1,2 1,4 b. Which is more stable? Circle one: the 1,2 product, the 1.4 product. c. Which product is favored at low temperatures? Circle one: the 1.2 product, the 14 product d. "The proximity effect is used to account for the formation of which product? Circle one: the 1,2 product, the 1.4 product. 7. (5) The pesticide chlordane, sold starting in 1948,...
For the following reactions fill in the box with the missing major organic product. Make sure to include stereochemistry when appropriate. If a reaction affords a mixture of enantiomers draw only one enantiomer. In the space below the reaction draw a detailed arrow pushing mechanism for that reaction.
6. Draw the arrow-pushing mechanism for this transformation 2 NaOH(aq) 7. Propose routes to make the products shown from the reactants. Give all reagents required and draw all stable, neutral intermediate compounds. You will need more than one step in each case. OH CH CH3 CH3 HyC H3C н,с Br он Br CH3 Brunker CHEM332