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6. Determine a synthesis for the following reactions: (4 pts, 12 pts total) NH NH Show...
Please, do not use C/Bz, H2Pd/C for third one 6. Determine a synthesis for the following reactions: (4 pts, 12 pts total) NH NH
4. Synthesis Reactions. Draw the feature product of the following reactions. (8 x 3 pts) 1. Mg Ph Br 2. CO2 3. H a "NH2 Ph 1. NaOH, CI 2. LAIH b. CHỊCH NHA NaBHgCN, H+ Ph C. Br (excess) NH d NaOH H HO OH H CH e. 1. NaOH H2O NH 2. H+ o= 1. NaOH H2O 2. SOCI N(CH3)2 3 HO
19) Predict the reagents for the following synthesis? 6 Pts OH он H A B A B- D- 20) Rank the following Carboxyllic Acid derivatives in decreasing order (Most to Least) of reactivity towards Nucleophillic Substitution reactions? 3 Pts NH II III IV More Reactive: Least Reactive 21) Match the following? 2 Pts 1) Alkynes 2) Aromatic Compounds 3) Aldehydes/Ketones 4) Carboxyllic acid derivatives A) Nucleophillic Addition Reactions B) Nucleophillie Substitution Reactions C) Electrophillie Additon Reactions D) Electrophillic Substitution Reactions
4. Synthesis Reactions. Draw the feature product of the following reactions. (8 x 3 pts) 1. Mg Ph Br 2. CO2 3. H+ 1. NaOH, ANH, 1. NaOH, CANADA ? 2. Lialla NH2 2. LiAIH4 CH3CH2NH2, NaBH3CN, H+ c. PhD Br (excess) CNH LB (excess) NaOH H+ YO- OH . H' CH3 1. NaOH, H2O NH - 2. H+ 1. NaOH, H2O 2. SOCI . N(CH3)2 HO فه H2NCH3 OCH3
4. Show reagents for the reactions below: (2 pts each, 6 pts total) LEO OH CO H
V) Determine whether ca neither(1.5 x 4-6 pts) whether each of the following reactions is an oxidation.c oxidation reduction or om Br A Br + HR OH NH OH VI) Give the IUPAC Names of the following organic compounds. Include E/Z for alkenes, cis-trans for cycloalkanes (if needed) and R.S configuration if a compound has chiral center(s) (2x5-10 pts) ICH, c) Br CH CH CH G-CH, BV CH3 - Сң сH = CH = CH -CH3 CH,CH3
4. (3 pts) Using retrosynthetic analysis, provide a synthesis for the following molecule. Place the required reagents next to the arrows and the necessary intermediate in the box provided. Me NH но HK он 1 4 5. 6. 3. 2. NH2 O) 08 4. (3 pts) Using retrosynthetic analysis, provide a synthesis for the following molecule. Place the required reagents next to the arrows and the necessary intermediate in the box provided. Me NH но HK он 1 4 5....
5. Show the expected products for the following reactions: (2 pts each, 16 pts total) 0 O NH 1) Conc, KMnO4, NaOH 2) H20+ 3) xs PhMgCI 4) H20" 1) KCN, HCl 2) PCC, CHCI 3) PhyP 1) dilute H2SO4 2) PCC, CH.CL 3) NH w 1) SOCI 2) EtMgBr 3) H.O ОН 1) KCN, HCl 2) H0 3) SOCI, 4) i 1) HCI | 2) HENNH. [H] 3) KOH,H,O, heat 1) RCO,H 2) LAIH 3) H.O 4) H NET,...
4) Predict the products formed in the following reactions (3 per part, 18 Pts total) Cat. H20 IZ, Draw Major Product КОН NH2 NH₂ Heat Draw Major Product OH Cat. H20 N u HH H Draw Major Product PhP4
show all work please thank you!! 6. (4 pts total; 2 pts, each) For each of the following questions, circle the BEST answer a. Strongest Bronsted-Lowry acid HF HCI HBr b. Has the lowest pka CHA NH Hao HAS 7. (4 pts total, 2 pts each) For each of the following molecular structures, circle the MOST acidic hydrogen. Note that lone pairs have been omitted for clarity. HH нннн HANC COH HHH HH