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Calculate ‹x›, ‹x2› ‹p›, ‹p2›, σx, and σp, for the nth stationary state of the infinite square well. Check that the uncertainty principle is satisfied. Which state comes closest to the uncertainty limit?

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Answer #1

The expression for wave function of an infinite square well.

Here, is the wave function of an infinite square well, a is the width of an infinite square well, n is the principle quantum number, x is the position of the particle.

The expression for the expectation value or average value of position is,

Substitute for in.

Assume that .

On differentiation, .

The limits are as follows:

When then , and when then .

The average value of position is,

Therefore, the average value of position is .

The expression for the expectation value or average value of is,

Therefore, the expectation value or average value of is .

The expectation value or average value of momentum is,

Therefore, the expectation value or average value of momentum is .

According to the time independent Schrodinger wave equation,

The expectation value or average value of is,

Substitute for in above equation as follows:

Substitute 1 for .

Substitute for in above equation as follows:

Therefore, the average value of is.

The value of is,

Substitute for , and for in.

Therefore, the value of is .

The value of is,

Substitute 0 for , and for in .

Therefore, the value of is.

The product of is,

The product is smallest for the state .

Substitute 1 for n in .

Therefore, the product is satisfied the uncertainty principle. It comes closest to uncertainty limit at the state .

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