Please explain why is it Cis or trans. How can we differentiate the isomers? Why one shift futhur downfield than the other?
Homework Answers
The spectrum here for compound clearly indicates it is of trans 1,2-dichloroethene.
The free rotation of atoms in the alkenes are restricted so in H-NMR of the trans-1,2-dichloroethene the hydrogens in different chemical environment and there are two hydrogen atoms so they couple with each other and each peak splits in to two. While for cis-isomer we will get a single peak at around 6.3 ppm.
In C13 NMR of the trans-1,2-dichloroethene there are two peaks in the spectrum indicating two carbons in different chemical environment. But in case of cis-isomer it will have only one peak showing both the carbons are in similar environment and we will have peak at arround 120 ppm.
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Please explain why is it Cis or trans. How can we differentiate
the isomers? Why one...
please answer completely and correctly 8) The 'H and "C NMR spectra of a compound with...
please answer completely and correctly
8) The 'H and "C NMR spectra of a compound with the formula CHoBr are shown below. Pr a structure for this molecule and assign the peaks in the spectra. TMS 10 9 0 ppm Chemical shift (5) TMS 200 180 16010 120 10806040 20 ppm Chemical shift (8) 9) The mass spectrum and 13C NMR spectrum of a hydrocarbon are shown below. Propose a structure for this hydrocarbon and explain your answer based on...
HI. Can someone please differentiate the two NMR of cis and trans Nepetalactone? Like where are t...
HI. Can someone please differentiate the two NMR of cis and
trans Nepetalactone? Like where are the sp2 hybridized C-Hs and all
other aspects of NMR. I labeled all the C's and H's from the
structure but can't differentiate between cis and trans
Nepetalactone. It includes both 1H and 13C NMR. Thanks in
advance.
Cis-Nepetalactone O He 7 10 4 8 9 462626* “64626. 48 44 44 42 40.- 4双3.o 2* 24 24 22 20 ,8 16 '4 1.2 Trans-Nepetalactone...
Please help me annotate the following spectra. "roblem 4 3396 3334 IR Spectrum 1662 4000 3000...
Please help me annotate the
following spectra.
"roblem 4 3396 3334 IR Spectrum 1662 4000 3000 1200 800 2000 v (cm 1600 ) 120 Mass Spectrum Provide the structure for the problem in the space provided % of base peak M+ 135 Cg H, NO 40 80 120 160 m/e 200 240 280 Students are to ignore marked solvents and water in NMR spectra. 13C NMR Spectrum (100 Mz, DMSO-d6 solution) DEPT CHA CHA CHA solvent proton decoupled 200 160...
for the following 2 compounds, please calculate, and show the calculations for, the degree of unsaturation, assign the IR spectrum peaks, assign the 13C NMR peaks, assign the 1H NMR peaks, and draw th...
for the following 2 compounds, please calculate, and
show the calculations for, the degree of unsaturation, assign the
IR spectrum peaks, assign the 13C NMR peaks, assign the 1H NMR
peaks, and draw the structure for the unknown compound.
CHIM 245 Spectroscopy Problem Set #2 In this problem set there are two unknown compounds. You are provided with the formula, IR spectrum, "C NMR spectrum, and 'H NMR spectrum for each compound. Each unknown is worth 10 points, with an...
NEED HELP WITH B) C) D) E) F) and G) that apply to the spectra below....
NEED HELP WITH B) C) D) E) F) and G) that apply to the
spectra below.
OTHER ANSWERS ARE THERE TO SUPPLEMENT
Thank you!
5. Using the GC mentioned in question 4 and the values listed on
the chromatogram for the height and width (at half height) of each
peak, calculate the percent composition for each product (A, B and
C). Be sure to show your work.
Area of peak A = 125 x 8 =
1000mm2
Area of peak...
NMR IR CAN YOU PLEASE ANSWER AS SOON AS POSSIBLE THANK YOU PLEASE EXPLAIN IT IN DETAIL THANK YOU Experimental Data Only report the IR absorptions that provide diagnosis...
NMR
IR
CAN YOU PLEASE ANSWER AS SOON AS POSSIBLE THANK
YOU
PLEASE EXPLAIN IT IN DETAIL THANK YOU
Experimental Data Only report the IR absorptions that provide diagnosis for the major functional groups. Copies of your spectra will be included in your lab report with this information written on the spectra. However, the information should also be included in the body of the report in a text format similar to the example given below IR cm1: 1735 (C-o); MS:...
c) Using your answers to question 5 and 6a, what percent of the mixture obtained in...
c) Using your answers to question 5 and 6a, what percent of the
mixture obtained in reaction 1 is the ortho isomer?
d) What percent of the mixture obtained in reaction 1 is the
meta isomer?
e) What percent of the mixture obtained in reaction 1 is the
para isomer?
f) Could we have used Mass Spectrometry after the GC analysis
(GC-MS) to identify which peak on the GC was which isomer? Why or
why not?
g) Could we have...
5. Using the GC mentioned in question 4 and the values listed on the chromatogram for...
5. Using the GC mentioned in question 4 and the values listed on the chromatogram for the height and width (at half height) of each peak, calculate the percent composition for each product (A, B and C). Be sure to show your work. (8 points) 6. The products corresponding to each peak on the GC are the ortho, meta, and para isomers of the nitrated product shown in the scheme for reaction 1. These isomers were isolated, and a proton...
Explain # 7 compound name P-Chlorophenol elaborate on What 7. NMR-both C13 and HI -Please include...
Explain # 7 compound name P-Chlorophenol
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NMR Exercise Lab Determine the structure of the following unknown organic compounds from the 'H and...
NMR Exercise Lab Determine the structure of the following unknown organic compounds from the 'H and C NM below. When supplying spectroscopic information for parts b-c below, be sure to give units appropriately when identifying specific peaks in a spectrum that are associated with specific portions of the structural formula that you give in part a. (a) Provide a structural formula which is consistent with all of the given information; give the degrees of unsaturation (DoU). (b) For the 15'C...
please answer completely and correctly
8) The 'H and "C NMR spectra of a compound with the formula CHoBr are shown below. Pr a structure for this molecule and assign the peaks in the spectra. TMS 10 9 0 ppm Chemical shift (5) TMS 200 180 16010 120 10806040 20 ppm Chemical shift (8) 9) The mass spectrum and 13C NMR spectrum of a hydrocarbon are shown below. Propose a structure for this hydrocarbon and explain your answer based on...
HI. Can someone please differentiate the two NMR of cis and
trans Nepetalactone? Like where are the sp2 hybridized C-Hs and all
other aspects of NMR. I labeled all the C's and H's from the
structure but can't differentiate between cis and trans
Nepetalactone. It includes both 1H and 13C NMR. Thanks in
advance.
Cis-Nepetalactone O He 7 10 4 8 9 462626* “64626. 48 44 44 42 40.- 4双3.o 2* 24 24 22 20 ,8 16 '4 1.2 Trans-Nepetalactone...
Please help me annotate the
following spectra.
"roblem 4 3396 3334 IR Spectrum 1662 4000 3000 1200 800 2000 v (cm 1600 ) 120 Mass Spectrum Provide the structure for the problem in the space provided % of base peak M+ 135 Cg H, NO 40 80 120 160 m/e 200 240 280 Students are to ignore marked solvents and water in NMR spectra. 13C NMR Spectrum (100 Mz, DMSO-d6 solution) DEPT CHA CHA CHA solvent proton decoupled 200 160...
for the following 2 compounds, please calculate, and
show the calculations for, the degree of unsaturation, assign the
IR spectrum peaks, assign the 13C NMR peaks, assign the 1H NMR
peaks, and draw the structure for the unknown compound.
CHIM 245 Spectroscopy Problem Set #2 In this problem set there are two unknown compounds. You are provided with the formula, IR spectrum, "C NMR spectrum, and 'H NMR spectrum for each compound. Each unknown is worth 10 points, with an...
NEED HELP WITH B) C) D) E) F) and G) that apply to the
spectra below.
OTHER ANSWERS ARE THERE TO SUPPLEMENT
Thank you!
5. Using the GC mentioned in question 4 and the values listed on
the chromatogram for the height and width (at half height) of each
peak, calculate the percent composition for each product (A, B and
C). Be sure to show your work.
Area of peak A = 125 x 8 =
1000mm2
Area of peak...
NMR
IR
CAN YOU PLEASE ANSWER AS SOON AS POSSIBLE THANK
YOU
PLEASE EXPLAIN IT IN DETAIL THANK YOU
Experimental Data Only report the IR absorptions that provide diagnosis for the major functional groups. Copies of your spectra will be included in your lab report with this information written on the spectra. However, the information should also be included in the body of the report in a text format similar to the example given below IR cm1: 1735 (C-o); MS:...
c) Using your answers to question 5 and 6a, what percent of the
mixture obtained in reaction 1 is the ortho isomer?
d) What percent of the mixture obtained in reaction 1 is the
meta isomer?
e) What percent of the mixture obtained in reaction 1 is the
para isomer?
f) Could we have used Mass Spectrometry after the GC analysis
(GC-MS) to identify which peak on the GC was which isomer? Why or
why not?
g) Could we have...
5. Using the GC mentioned in question 4 and the values listed on the chromatogram for the height and width (at half height) of each peak, calculate the percent composition for each product (A, B and C). Be sure to show your work. (8 points) 6. The products corresponding to each peak on the GC are the ortho, meta, and para isomers of the nitrated product shown in the scheme for reaction 1. These isomers were isolated, and a proton...
Explain # 7 compound name P-Chlorophenol
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NMR Exercise Lab Determine the structure of the following unknown organic compounds from the 'H and C NM below. When supplying spectroscopic information for parts b-c below, be sure to give units appropriately when identifying specific peaks in a spectrum that are associated with specific portions of the structural formula that you give in part a. (a) Provide a structural formula which is consistent with all of the given information; give the degrees of unsaturation (DoU). (b) For the 15'C...
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