11. (4) Reactions A. Draw all the products of the following reaction: EtOH Ag(NO3) Cl B....
Propose a mechanism for the following reaction: 11. Propose mechanisms for the following reactions. Draw all arrows, lone pairs, formal charges, counter ions, and label all reaction steps (e.g. proton transfer, loss of leaving group, etc.). A. (13 pts) CH:NH 2 N N - CH3 Cl
4. The following reaction has a small, positive AG and takes place slowly at room temper H3C-Cl + H-OH - H3C-OH + H-CI (a) The mechanism for the reaction is shown below. Which bond is being broken in the sky step? Which bond is being made? slow Step 1 H3C-Cl + H-OH- - H3C-CH3 + CI endothermic fast Step 2 H3C-OH3 + 1 - H2C-Cl + H-CI exothermic (b) Based on this multi-step mechanism, draw a free energy reaction coordinate...
10) Write the mechanism for the following EAS reaction? 4P CL), AICI, 11) Predict the all possible products for the following reactions and circle the major product among them? 8 Pt A) -CH2 HNO3, H,SO CI, AICI, B) C) CH,CI, AICI: сна HNO.H.SO. D) OH
for the reaction: acetaminophen + (NaOH/EtOH note: etoh is ethanol) and butyl iodide ---------------> 4-butoxyacetanilide a) The first step in this reaction is to reflux acetaminophen in a NaOH/EtOH solution, followed by the addition of butyl iodide. What is the purpose of using the NaOH/EtOH solution? Would the SN2 reaction still occur if the first step was not completed? Why or why not? b) Upon completion of the reaction (before filtration), an additional 4.0 mL of 1.0 M NaOH/EtOH was...
1. Predict the major organic products of the following reactions. Draw all stereoisomers that are formed. НО, OH 1 eq ,H2SO4 (assume H2O workup of reaction to neutralize product) 1. LDA 2. (assume H,O workup of reaction to neutralize product) 3. Hg(OAC)2 4. NaBH, EtOH 1eq HBr EtOH ambiente 1. Brz. CCL 2. NaOET, ETOH OH
11. Draw the complete mechanism for the following reaction. Assume that this reaction takes place via El mechanism. (Hint: a series of carbocation rearrangements will occur) 1. Weak Base EtOH HO но"
1. Draw all products for the following reactions. For the reaction b indicate the stereochemistry of the product. 1. Oz 2. Mes a CH3 CH3 CH3 1. O3, CH2Cl2, -78°C 2. Mezs 1. Oz/ CH2Cl2 / -78°C 2. Mezs
1. Draw all products for the following reactions. For the reaction b indicate the stereochemistry of the product. HCM 1.03 2. Mes a. CH3 CH3 CH3 Hac 1. Oz / CH2Cl2/-78°C 1. O3, CH2Cl2, -78°C 2. Mezs c. V 2. Mens
Complete the products of the following sequence of reactions OH OH EtOH / acetona H2SO4 cat. 1. Meso Cl, piridina 2. KCN en DMSO 1. LIAIH4, THE 2. H307 HO c OH A B
4. Draw a mechanism for the following reactions: Be sure to include all products and stereochemistry when applicable. (8 pts each) H2SO4 HgSO4 to HC