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4) Which of the following is the strongest acid? CO.H CO2H CO H CO2H Br OMe CN
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Answer #1

4-Cyanobenzoic acid has deactivating group at para position which shows -R and -I effect which enhance the acidic strength of carboxylic acid. So option D is correct that is 4-Cyanobenzoic acid is strongest acid among them. Among all, 4-Cyanobenzoic acid has pka value =3.55, 4-bromobenzoic acid has pKa=3.96,Benzoic acidpKa=4.2 and 4-Methoxybenzoic acid has pKa= 4.50. So correct order is D>A>C>B.

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