Question

1. Calculate the emf of a Copper-Zinc battery with few drops of salt dipped in water....

1. Calculate the emf of a Copper-Zinc battery with few drops of salt dipped in water.
2. Do we get a higher voltage if salt is dipped into our Copper-Zinc battery's electrolyte? If yes, why? If not, why not?

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Answer #1

1. Assuming salt solution contains sodium chloride

Then at the zinc terminal

On the copper terminal water will be electrolysed

or using autoprotolysis

This will happen since sodium has a much lower electron affinity than water/hydronium..

2. If salt is dipped into our copper zinc battery's electolyte, we get a higher voltage.

A electrochemical simple cell can be made by dipping two different pieces of metal (copper and zinc) of different reactivity into a salt solution which will act as electrolyte.

Due to the series connection, the voltage is increased and you might light a bulb! having made a crude battery!

salt soluhion contains Sodiun sSum chlorfde ther at the 궈nc -terminal On -te Copper -ler minal uoaler uwill be -the per ial uoałer uw electioyed or using atoprotoly sis Thts coill happen since sodiun hj Ower electron a-iru uch louser electionfhan olerydium E- Ov Tota emf -2.1-o.83+0 E°- - 3.54 V

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