. Using the following compound answer the following questions. (30 points) a. Draw Newman projections for...
1. (a) Different conformations are found in pentane. (i) Using Newman Projection, draw all the possible staggered and eclipsed conformations of pentane by referring to the bond rotation at C2-C3. (ii) Compare their stability and explain your answer. (b) Draw the most stable form of the chair conformers for trans- and cis-1,4-dimethyl cyclohexane. Comment on their stability. thanks
1. Draw the Neman Projection of the following Promane descriptions Newman projection for most stable Newman projection for least stable conformation conformation 2. Draw the Newman projections for butane looking down the C2-C3 bond through a full 360 degree rotation. Start with the anti-staggered Newman projection then draw and label each Newman projection (staggered, eclipsed, gauche, anti-staggered, fully-eclipsed) for every 60 degrees of rotation Newman projection for most stable Newman projection for second-most stable conformation Conformation Newman projection for least...
2. Conformational Isomerism (15 points). Draw the following molecules in Newman projections with respect to the bond indicated. Indicate whether they are staggered or eclipsed forms. A. The most stable conformational isomer of the hydrocarbon below around the two starred carbon atoms.
6. Conformational Analysis: Newman Projections (25 points) Consider the rotation around the C3-C4 bond of (3R 4R)-3,4-dibromohexane. C3-C4 bond. B Draw all three eclipsed Newman projections. In no particular order. Calculate the total strain associated with each conformation using the table below, enter on the provided line, and identify the least stable conformation (Circle it) Briefly explain your assignment of the least stable conformation - including which specific types of steric strain are involved. Short phrases are great complete sentences...
n. Draw three eclipsed Newman projections along the indicated bond. Use the attached template and finish the drawing by attaching the lines and substituents. least stable eclipsed most stable eclipsed Br Below, draw three staggered Newman projections of the same molecule along the same bond. Use the attached template and finish the drawing by attaching the lines and substituents. least stable staggered most stable staggered 4 5 6 Name the molecule: B. Draw the most stable conformer of meso-2,3-dichlorobutane
Understanding Conformation Analysis Draw two Newman Projections for a n-pentane that depict and anti and gauche conformation looking down the c2-c3 bond. Which conformation is the most stable and why?
Draw Newman projections of 2, 3-dimethylbutane, looking down the C2 to C3 bond, in the most and least stable conformations. Label any important interactions.
Using Newman projection draw an eclipsed, gauche, and anti conformation for the compound brlow and indicate which is the most stable. 2-Iodobutane (C2-C3 bond)
Considering rotation around the indicated bond in the following compound, label the following Newman projections for the most stable and least stable conformations. Enter each substituent in the corresponding labeled box that matches the correct position in the Newman projection.
For the following pairs of isomers draw both the chair conformations. Based on your chair conformations state which isomer will be more stable: Draw the most stable conformation looking down the C3-C4 bond of 4-bromo-3,6-dimethylhept-1- -3-ol in the Newman projection where C3 is the front carbon and C4 is the back carbon: Starting with the conformation you have drawing show the 5 other conformations representing 60 degree rotations of the BACK carbon in an anti-clockwise direction. For the six conformations...