n. Draw three eclipsed Newman projections along the indicated bond. Use the attached template and finish...
using the c3-c4 axis, draw newman projections for an eclipsed and a staggered conformation of 2.5 dimethylhexane. Draw the most stable conformation for the molecule as well.
3. 1) Draw the Newman projection of the following compound, looking down the indicated bond. (2) Label this Newman projections as a staggered or eclijpsed conformation. (3) Rotate this Newman projection to draw the Newman projection of the most stable conformation of this compound. (3) Label this Newman projections as a staggered or eclipsed conformation. (4) Re-draw this most stable conformation in a wedge-dash form as the original compound below is shown). a. он в н b. Cl 3. 1)...
. Using the following compound answer the following questions. (30 points) a. Draw Newman projections for all the possible conformational isomers for 2,3-dibromo-pentane rotation along the axes of C2-C3. b. Label the different Newman projections. (hint: anti, eclipsed, or stagger, etc). c. Rank the conformations in order from most stable (1) to least stable. d. Base on your answer on part c take the most stable isomer and one least stable isomer and Explain in details why the difference in...
1. Draw the Neman Projection of the following Promane descriptions Newman projection for most stable Newman projection for least stable conformation conformation 2. Draw the Newman projections for butane looking down the C2-C3 bond through a full 360 degree rotation. Start with the anti-staggered Newman projection then draw and label each Newman projection (staggered, eclipsed, gauche, anti-staggered, fully-eclipsed) for every 60 degrees of rotation Newman projection for most stable Newman projection for second-most stable conformation Conformation Newman projection for least...
(Cp 4) For the structure shown below, use one of the templates to show the Newman projection which corresponds to the view down the bold bond. In the Newman projection you need only show the atoms attached directly to the carbons connected by the bold bond (and not the remainder of the ring). If there is a more stable conformation for the molecule, draw it in the box to the right (do not give a Newman projection for the more...
3. Consider 2,2,4-trimethylpentane Draw this compound. a. b. Now, provide Newman projections for the three staggered conformations for this compound looking down the C3 - C4 bond. c. Label the orientation of substituents (i.e. gauche or anti) in each structure and circle the most stable conformation(S)
Using Newman projections, draw all the staggered and eclipsed conformations that result from rotationaround the indicated bond in 2-methylbutane(shown below) and place these on a graph of energy versus dihedralangle for a 360° rotation about this bond. To orient your graph, one structure has been filled in for you. Please start your conformational analysis and energy curve from this structure.
2. Conformational Isomerism (15 points). Draw the following molecules in Newman projections with respect to the bond indicated. Indicate whether they are staggered or eclipsed forms. A. The most stable conformational isomer of the hydrocarbon below around the two starred carbon atoms.
14) For rotation about the C2-C3 bond of 2,3-Dibromobutane: A) Draw the Newman projector of the most stable conformer B) Draw the Newman projector of the least stable conformer
In-Class Worksheet In the box below each molecule, draw Newman projections for the structures A, B, and C shown from the perspective indicated. For each Newman projection that you've drawn, indicate if there are any eclipsed bonds or 1. gauche butane interactions. H H CH3 H3C CH3 CH3 H. H3C CH3 H CH3 H H Structure C Structure B Structure A Structure A can exist in a lower energy conformation by undergoing a bond rotation; draw the Newman projection of...