Using Newman projections, draw all the staggered and eclipsed conformations that result from rotationaround the indicated bond in 2-methylbutane(shown below) and place these on a graph of energy versus dihedralangle for a 360° rotation about this bond. To orient your graph, one structure has been filled in for you. Please start your conformational analysis and energy curve from this structure.
Using Newman projections, draw all the staggered and eclipsed conformations that result from rotationaround the indicated...
5. Construct a model of 1,2-difluoroethane. Draw the Newman projections for the staggered and eclipsed conformations of 1,2-difluoroethane. Are these molecules isomers or conformers? If they are isomers to what specific category do they belong? 6. The structure of cyclohexane (C6H12) is based on a six membered ring of carbon atoms. Construct a model of cyclohexane. Cyclohexane can exist in two conformations; the boat or chair conformation (shown below). What are the C-C-C, C-C-H, and H-C-H bond angles at each...
In-Class Worksheet In the box below each molecule, draw Newman projections for the structures A, B, and C shown from the perspective indicated. For each Newman projection that you've drawn, indicate if there are any eclipsed bonds or 1. gauche butane interactions. H H CH3 H3C CH3 CH3 H. H3C CH3 H CH3 H H Structure C Structure B Structure A Structure A can exist in a lower energy conformation by undergoing a bond rotation; draw the Newman projection of...
n. Draw three eclipsed Newman projections along the indicated bond. Use the attached template and finish the drawing by attaching the lines and substituents. least stable eclipsed most stable eclipsed Br Below, draw three staggered Newman projections of the same molecule along the same bond. Use the attached template and finish the drawing by attaching the lines and substituents. least stable staggered most stable staggered 4 5 6 Name the molecule: B. Draw the most stable conformer of meso-2,3-dichlorobutane
Draw the staggered and eclipsed Newman projections for chloroethane and indicate which one is lower in energy (2 points). 9.
5. Draw the Newman projections for the anti conformation and two types of eclipsed conformations of 1,2-diiodoethane. Of the two eclipsed conformations, which is of higher energy, and why?
Draw the Newman projections for the anti conformation and two types of eclipsed conformations of 1,2-diiodoethane. Of the two eclipsed conformations, which is of higher energy, and why?
Problem 4 Give the IUPAC name for each Newman projection. the folle eniwoll ot orl broo 6lumol be F ormula CH (H3C)2HC CHз CH(CH9CHIC CH CH HаС CH(CH2CH2CH3)CH3 CH3 Problem 3 Sroldo For the following molecule answer the following questions. (a) Using Newman projections, draw all staggered and eclipsed conformations (6 in total) that result from rotation around the bet014 indicated bond in each molecule; (b) Draw a graph of energy versus rotation around this bond. CI H
using the c3-c4 axis, draw newman projections for an eclipsed and a staggered conformation of 2.5 dimethylhexane. Draw the most stable conformation for the molecule as well.
2.16. Using a Newman projection, draw a staggered and eclipsed 2.17. For alkanes containing four or more carbons, use the Newman projection to draw 2.18. Describe what contributes to the changes in the potential energy of an alkane as you on of an alkane. (Section 4.7) the gauche and anti conformations. (Section 4.8) rotate around a carbon-carbon bond. (Section 4.7 & 4.8) energy conformations. (Section 4.7 &4.8) carbon bond. (Section 4.7 & 4.8) 2.19. Use a sawhorse projection or Newman...
2. Conformational Isomerism (15 points). Draw the following molecules in Newman projections with respect to the bond indicated. Indicate whether they are staggered or eclipsed forms. A. The most stable conformational isomer of the hydrocarbon below around the two starred carbon atoms.