Question

A student gets a 3 mL sample of saturated KHP at 28.0°C. It takes 27.6 mL of 0.107 M NaOH to titrate to the endpoint. How many moles of NaOH is this? How many moles of KHP were present in the sample? what is the molarity of the saturated KHP solution? What is the value of Ksp for this solution? (Assume syringe volume is good to 2 dp. Assume buret volume is good to 2 dp. Assume molarity of NaOH is good to 4 dp.) moles moles

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Answer #1

1)

moles of NaOH = 27.6 x 0.107 / 1000

moles of NaOH = 2.95 x 10^-3 mol

2)

moles of KHP = 2.95 x 10^-3 mol

3)

moles of KHP = moles of NaOH

3 x 10^-3 x M = 2.95 x 10^-3

M = 0.984

Molarity of KHP = 0.984 M

4)

Ksp of = 0.0965 x 0.0965

Ksp of the solution = 9.31 x 10^-3

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