1) (5 points each) Give tho major product from the following reaecions HCI Br2 H2SO4 H2O...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
1) Determine the major product(s) of the following reactions. Show all appropriate stereochemistry. HCI Br2 1) BH3 w o dd 2) H202, NaOH (aq) Br2, H20
Predict the major organic product
or products of each of the following reactions:
Identify the mechanism
taking place in each of the reactions and please provide
explanation.
H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
Provide the major product for each reaction below
ajor product for each reaction below. 48 points 12 Br2/H20 C12/CH3OH 10 2. OH, H202, H20 Pd/C CH,OH, H2SO4 CH CO3H
I need helo on W and GG.
2 eq, HCI H2SO4, HgSO4, H2O 1 eg, Br2 2 eg, Cl2 1. NaNH2 2. CH2CH2CH2Br 1. Sia BH/THF 2. H2O/OH KMnO4, H2O bb. KMnO4, NaOH H/Pd/BaSO4, quinoline H2, Pt Na/NH3 2 eq, HCI H2SO4 HgSO4, H2O 1 eq, Br2 2 eq. Br2 + 1. Sia BH/THF 2. H2O/OH KMnO4, H2O KMnO4, NaOH gg.
2. Provide the major products from the following reactions. Starting Material Reagent(s) Product? Br2 Place appropriate groups H, Br CH, on scaffold) HCI Place appropriate groups (H, Br, CH, on scaffold) CH Brz/H20 Place appropriate groups H, Br CHs on scaffold] 1) O3 2) Zn/HOÁC LICH H2, Pd/C CH₂ 1. BH3 2. H2O2, NaOH(aq) CH2 hot KMnO4 in H2O - CH₂ CH3CO3H Product from above H30+, H2O
1. Give the major product of the following reactions, write NR. if no reaction happens. Indicate the stereochemistry if necessary CHCI KOC(CH3). (CH),COH 1. conc. HBr, heat 2. KOBU, HOBU 1. NaOM, MOH CI 2. BICN 1. 1 eq. BH3. THE 2. H2O2, NaOH, H2O 3. Hg(OAC), MeOH 4. NaBH4, NaOH, H2O 1. conc. HCI 2. LDA, THF 3. O. CH,OH 4.(CH), 1. Hg(OAC), THE 2. NaBH, NaOH, H2O > OH (Hint: product has a bicyclic ring)
Draw the structure of the one major product expected for each
of the following reactions. Indicate stereochemistry where
applicable
Chemistry 2310 Ch 8 and 10 Test-Addition Reactions of Alkenes and Intro to Radicals 1.) BH3 Br. k) PhCO3H 1.) O 2.) DMS Ni H3C n) HO 1.) H2SO4 heat 2.) Br2 1.) Br2, light 2.) NaOEt 3.) Ch. H2O o) 1.) Cl2, light 2.) NaOEt 3.) Os followed by DMS p) 1.) BH3 THF followed by H202/HO 2.) TsCl, pyridine...
Complete the following reaction with the major
product
Reactions: complete the following reaction with the major product HBr он 1- OH POCl3 pyridine 2- H2SO4 OH 3- Hl 4- H20 H3PO4 5- Cl2 H20 7- 1) BH2-THF 2) H202, KOH 8- 2) 9- 1) BH3-THF 10- DLL 10- Date: G# : 12, and 13- Br H20 но 2) NaH 14, and 15- ) NaOH i NaOH 2 dil H.0 3) PBr 3)HBr F6 FZ F8
Provide the major product for the following reaction? (2)Zn, H* ano Provide the major product for the following reaction? Br2 CH Cl2 H- S Provide the major product for the following reaction? heat H- -H Provide the major product for the following reaction? 1) Hg(OAc)2, H20/TH 2) NABH4 н- H Provide the major product for the following reaction? (1) BH3, ether HO-0H (2) Provide the major product for the following reaction? (1) BH3, ether (2) H202 OH