Cl Cl 1. PhMgBr (2 mols) Cl 2. H30. ?? 2. H,O HO-1
Mg, ether 1-bromobutane. (D) KOH, H2O (A) Na (B) CH CH Br (C) (i) CH30CH2 3 (E) (2) H30 H2SO4, heat (F)
O ? 1) PhMgBr 2) H,о" Incorrect. N. [H2SO4] ? - H20 Edit Incorrect. ? H RCO3H (b) X Н,С- "он Edit CH3 Predict the major product of each reaction below: ? 1) EtMgBr 2) H2O Edit SHOW HINT ? H 1) PhMgBr 2) H20 I
17. Predict the product Br yo + Mg Dry Ether 1. MgBr 2. H+ 1. MgBr Н. 2. H2O/ HT
For each reacuon ere s only as an aid for you. 1) KOH, H-O, heat Diethyl malonate B 1) Ph3P, ether 2) nBuLi, ether CIH1204 2) H, H2O, heat C1SH2406 CHH1202 NaOEt, EtOH Br OCH2CH3 3) PHCHO NH/heat Note: The C-13 NMRS for Structures C, D, and E each show 7 resonances LIAIH D E C1HNO ether C1H1SN Br 1) SOCI2, pyridine F 2) CH3OH 1) CH2COCI,AICI3 1) Mg(s), Et20 H 2) diisopropyl amine, pH 4.5, NaBH3CN 2) CO2 (s)...
MgBr 1. V 'H , ether 2. H2O, H+ H,Cro CH2CH2NH2 H-A
CH3 H/H2O b. +H3CMgBr H/H2O +Li(CH3)2Cu C. mild acid CH3NH2 d. Cl Pd-C H2 (1 equiv) e. H20 H30* +KMnO4 Ht H20 h. + H3C-CEC-Li
Show the product when this substrate is mixed with the reagent shown. a. NH3 b. LiAlH4 and H2O c. 2 PhMgBr, ether and H2O, HCl (a) NH3 – 1. LiAIH 2. H2O 1. 2 PhMgBr, ether 2. H,O, HCI
A. 1. CCN 2.Ht, H2O, a B. 1. NaNO2, HCl 2. Cu CN c. 1. Mg D. INGH 2. CO2 3. H3O+ 2. ^ Br E. 1. mg 2. To 3. H+, H2O F. PCC G. KMn DA H2O, HO- Jo ling H. 1. mg 2.co 3. Haot 4. PCC 3. Ht, H2O + PCC He Ko Al Cly carry *Determine the reagents necessary to out each of the following transformation. -NH2 .CN -OH OH -OH 16 ibis
Complete the reaction (fill in question marks) d. Br BrMg O Mg H30 Ether Ether Cl