C1H1204 2) nBuLi, ether 2) H*, H2O, heat C1H1202 NaOEt, EtOH C18H2406 Br OCH CH 3) PHCHO NH3/heat Note: The C-13 NMRS for Structures C. D. and E each show 7 reson ances D LIAIH4 C1HINO2 CIH15N ether Br 1) CH2COCI,AICI 1) SOCI2, pyridine 1) Mg(s), Et2O H 2) diisopropyl amine, pH 4.5, 2) CH3OH 2) CO2 (s) 3) H*, H20 C16H25NO2
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For each reacuon ere s only as an aid for you. 1) KOH, H-O, heat Diethyl malonate B 1) Ph3P, ether 2) nBuLi, ether CIH1...
Draw each product out based on given: 1.03 2.DMS 3. Na2Cr2O /HsSO /H20 PB13 2-methyl-1-propanol Mg/ether...
Draw each product out based on given:
1.03 2.DMS 3. Na2Cr2O /HsSO /H20 PB13 2-methyl-1-propanol Mg/ether 1. CO2 2. H,09 1. KMnO,/NaOH/H,0 2. H30 SOCI pyridine (CHz) CHCH OH pyridine V Mg/ether 1.CO2 2. H₂O* 1. LiAlH. 2. H2O
2. Predict the product. CH,CHINH Or . 1. excess CH 1 2. Ag,0,H,O heat 5. Match...
2. Predict the product. CH,CHINH Or . 1. excess CH 1 2. Ag,0,H,O heat 5. Match the reagents to the corresponding reaction. G. H20 H. xs CH3CH2NH2 A. SOCI2, pyridine B. Ethanol, pyridine C. 1) xs LAH 2) H20 D. 1) xs CH,CHMgBr 2) H30 E. 1) NaOH 2) H30* F. 1) DIBAH 2) H20 1. 1) LiAl(OR)2) H20 J. (CH2CH2) Culi K. xs NH3 L. 1) NaOH 2) CHÚCHỊCHÚCOCI M. Butanol, H
21. Please give the structures of the product for each step. (20 pts) 1. LIAIH(O-t-Bu)s -78...
21. Please give the structures of the product for each step. (20 pts) 1. LIAIH(O-t-Bu)s -78 °C COOH CH,NH2 72- sOCl н" а). 2. H2O Br PhP CH 1. CHyCN Mg b) Wittig reaction 2. H,O Ether 1) 2 eq. CH,MgBr Он CH,CH2OH c) 2) H,0 н" N н SOCI2 он d)
Fill in the reaction's reagents/ products 1) KOH H, H2O سینه Heat 2) Ph-CH2-Br 1) 2x...
Fill in the reaction's reagents/ products
1) KOH H, H2O سینه Heat 2) Ph-CH2-Br 1) 2x MgBr اللہ H 2) H20 PhCuli H Heat
draw the missing structures for the letters Scheme 1 Br S NaOH CI + A B...
draw the missing structures for the
letters
Scheme 1 Br S NaOH CI + A B + С H2N NH2 Scheme 2 1. MCPBA Na2Cr2O7 D E 2. H20, H30+ H30+ Scheme 3 1. LIAIH4 PBr3 F G Н 2. H30+ ether Scheme 4 1. H20, Hg(OAc)2 DMP H I 2. NaBH4 CH2Cl2 Scheme 5 OH tosyl chloride Na J K pyridine ОН
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the...
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the reagent list handout Step 1 Step 2 Step 3 OH Alkyl Halides (X = CI, Br or 1) and Acyl chlorides: Assume Allig 15 present, if needed CIP CU CH3X X CI E A B EE Ketones. Aldehydes and Epoxides: Assume "then H20" is included if a protonation step is needed F A A K 0 MN Р Grignard, Wittig and Organocuprate Reagents: Assume...
Propose an efficient synthesis for the transformation below, using two sequential reductive aminations. Enter the appropriate number...
Propose an efficient synthesis for the transformation below,
using two sequential reductive aminations. Enter
the appropriate number or letter from the reagent list handout.
Propose an efficient synthesis for the transformation below, using two sequential reductive aminations. Enter the appropriate number or letter from the reagent list handout. Step 1 + NaBH3CN, H+, Step 2 - NaBH3CN, H+ Reagent List (Updated 4/30/2020) Enter # or letter in the appropriate boxes. Note: Exam responses are case insensitive Alkyl Halides (X = Cl,...
1. CO2 2. H20 Br Mg, ether SOCI2 compound a compound b compound c LI Cul...
1. CO2 2. H20 Br Mg, ether SOCI2 compound a compound b compound c LI Cul compound compound d compounde compoundf Work out the complete synthesis on a separate sheet of paper, and then draw the structure of compound 6. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. . Do not include lone pairs in your answer. They will not be considered in the grading. • Draw organometallic compounds as...
Fill the missing reagents/products in each box 1) KOH H, H20 vilion Heat 2) Ph-CH2-Br 1)...
Fill the missing reagents/products in each box
1) KOH H, H20 vilion Heat 2) Ph-CH2-Br 1) 2x MgBr rich 2) H20 H* Ph2Culi ou H Heat
please include any enantiomers! a.) H H2Cr04 acetone b.) 1. XS KMnO4/KOH / H2O/A 2. H30*...
please include any enantiomers!
a.) H H2Cr04 acetone b.) 1. XS KMnO4/KOH / H2O/A 2. H30* c.) XS NaBH4, H20 H OH d.) 1. XS LIAIH/THF/-78 °C 2. H20 OH H e.) NaNH / liq NH3 f.) Br 1. Mg/THE 2. CO2 3. H30* Ph Ph cyclopropene HF CHE h.) OH 1. PCC/CH2CH2 2. i-PrLi 3. NH4Cl(aq) i.) CI 1. LITHF 2. CO2 3. NHCl(aq) j.) Ph 1/HNO, Ph k.) NH2 1. HNO,(aq) 2. NaSCH2CH2CH3 1.) AICI: 3-chloro-2-methylpentane
Draw each product out based on given:
1.03 2.DMS 3. Na2Cr2O /HsSO /H20 PB13 2-methyl-1-propanol Mg/ether 1. CO2 2. H,09 1. KMnO,/NaOH/H,0 2. H30 SOCI pyridine (CHz) CHCH OH pyridine V Mg/ether 1.CO2 2. H₂O* 1. LiAlH. 2. H2O
2. Predict the product. CH,CHINH Or . 1. excess CH 1 2. Ag,0,H,O heat 5. Match the reagents to the corresponding reaction. G. H20 H. xs CH3CH2NH2 A. SOCI2, pyridine B. Ethanol, pyridine C. 1) xs LAH 2) H20 D. 1) xs CH,CHMgBr 2) H30 E. 1) NaOH 2) H30* F. 1) DIBAH 2) H20 1. 1) LiAl(OR)2) H20 J. (CH2CH2) Culi K. xs NH3 L. 1) NaOH 2) CHÚCHỊCHÚCOCI M. Butanol, H
21. Please give the structures of the product for each step. (20 pts) 1. LIAIH(O-t-Bu)s -78 °C COOH CH,NH2 72- sOCl н" а). 2. H2O Br PhP CH 1. CHyCN Mg b) Wittig reaction 2. H,O Ether 1) 2 eq. CH,MgBr Он CH,CH2OH c) 2) H,0 н" N н SOCI2 он d)
Fill in the reaction's reagents/ products
1) KOH H, H2O سینه Heat 2) Ph-CH2-Br 1) 2x MgBr اللہ H 2) H20 PhCuli H Heat
draw the missing structures for the
letters
Scheme 1 Br S NaOH CI + A B + С H2N NH2 Scheme 2 1. MCPBA Na2Cr2O7 D E 2. H20, H30+ H30+ Scheme 3 1. LIAIH4 PBr3 F G Н 2. H30+ ether Scheme 4 1. H20, Hg(OAc)2 DMP H I 2. NaBH4 CH2Cl2 Scheme 5 OH tosyl chloride Na J K pyridine ОН
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the reagent list handout Step 1 Step 2 Step 3 OH Alkyl Halides (X = CI, Br or 1) and Acyl chlorides: Assume Allig 15 present, if needed CIP CU CH3X X CI E A B EE Ketones. Aldehydes and Epoxides: Assume "then H20" is included if a protonation step is needed F A A K 0 MN Р Grignard, Wittig and Organocuprate Reagents: Assume...
Propose an efficient synthesis for the transformation below,
using two sequential reductive aminations. Enter
the appropriate number or letter from the reagent list handout.
Propose an efficient synthesis for the transformation below, using two sequential reductive aminations. Enter the appropriate number or letter from the reagent list handout. Step 1 + NaBH3CN, H+, Step 2 - NaBH3CN, H+ Reagent List (Updated 4/30/2020) Enter # or letter in the appropriate boxes. Note: Exam responses are case insensitive Alkyl Halides (X = Cl,...
1. CO2 2. H20 Br Mg, ether SOCI2 compound a compound b compound c LI Cul compound compound d compounde compoundf Work out the complete synthesis on a separate sheet of paper, and then draw the structure of compound 6. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. . Do not include lone pairs in your answer. They will not be considered in the grading. • Draw organometallic compounds as...
Fill the missing reagents/products in each box
1) KOH H, H20 vilion Heat 2) Ph-CH2-Br 1) 2x MgBr rich 2) H20 H* Ph2Culi ou H Heat
please include any enantiomers!
a.) H H2Cr04 acetone b.) 1. XS KMnO4/KOH / H2O/A 2. H30* c.) XS NaBH4, H20 H OH d.) 1. XS LIAIH/THF/-78 °C 2. H20 OH H e.) NaNH / liq NH3 f.) Br 1. Mg/THE 2. CO2 3. H30* Ph Ph cyclopropene HF CHE h.) OH 1. PCC/CH2CH2 2. i-PrLi 3. NH4Cl(aq) i.) CI 1. LITHF 2. CO2 3. NHCl(aq) j.) Ph 1/HNO, Ph k.) NH2 1. HNO,(aq) 2. NaSCH2CH2CH3 1.) AICI: 3-chloro-2-methylpentane
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