Draw each product out based on given:
Draw each product out based on given: 1.03 2.DMS 3. Na2Cr2O /HsSO /H20 PB13 2-methyl-1-propanol Mg/ether...
1. Cl, H20 2. NaOH 3. CH3CH2MgBr 4. H30* 1. Mg 2h) 2. H₃C.. 3. H30+ 1. SOCI OH 2. DIBAL"H 3. H30* OH 1. NaOH 2j) 2. CH3CH2CI 3. O o 2k) [ N-H H20. STAB OH 2)) 1. NaOH 2. CH3CH,CI 3. O o IN-H 2k) H30*. STAB 21) 1. 2 KCN, HCN 2. LiAlH4 3. H30+ 4. H2, Pt
1) R'-MgBr in THF 2)H,o NaH Ho or OH PAA X2. H20 1) Hg(OAc)2, R'OH 2) NaBH4, NaOH, H20 Os0 NaHSO, H2O I) 2)CH, SCH HyIO HBr ROOR 1)BH3. THF 2)H202, NaOH, H2O Mg, THF PBr3 NaOH )OTHF 2) H30 CrOj. H,SO, 1) NaH 2)RXDMF "О-R DMF PCC DCM ) THF 2) H3O+ SOCI pyridine Li Hexanes
2) Provide a product for each of the following reactions. Ensure correct chemoselectivity, stereoselectivity and regioselectivity in product determination. OH SOCI (2eq) b) 1.0 2) H2O, NaOH - KMnO., NaOH, H2O H3C 1) Mg 2) CO. 3) H30 ОН Na Cr.O H2SO4, H,0 (excess) NaBH EtOH Hint: esterification H+ DLDA 2) PhCH,Br /4 736
Problem #1 Predict the major product(s) from the following reactions: 1.03 2. DMS CHE H3C 1. CH2CO3H 2. H30* CHE CH3 cat. OsO4 t-BuOOH CH KMnO4 CH3 cold CH3 CH₃ H₃C H₂ ? -CH₃ CH3 НАС 1. BH3-THF 2. H2O2, NaOH ? CH3 Brz CH3 CH2OH
Complete the following problems on your own paper. Rewrite the problem. 1. Draw the answer to the following reactions. ao NOGO NaCrO Br 1. NaCN 2. H,O* 1. LiAlH 2. H30* 1. Mg 2. CO2 3. HO* 4. CH CH2CH2CH,OH, H2SO4(catalytic amount) 1. Na2Cr2O7. H SOHO 2. SOCI 3. (CHUCH CH2)2Culi OI 1. SOCI 2. CH CH OH Ο ΟΗ
draw out structures or reagents Draw out either the structures or the reagents A-Q needed to complete the reaction roadmap below 1) CuLi(CH-CH(), 0 2) H.O 1) Mg 2) formaldehyde Br 3) H30 G H2C1 CH3 HyC N B 1)Bry(excess), NaOH 2)HCI PCC F PBr3 E NaOH A Р I 1) Dibal 2) H,O, CH Nz, ether HCI 1) TOSCI, pyridine 2) NaH SOCI J 1) NaBr 2) H30 H M 1) 2CH,MgBr 2) H,O, HCI HECHC=CH2 Acetic Acid NaOCH...
For each reacuon ere s only as an aid for you. 1) KOH, H-O, heat Diethyl malonate B 1) Ph3P, ether 2) nBuLi, ether CIH1204 2) H, H2O, heat C1SH2406 CHH1202 NaOEt, EtOH Br OCH2CH3 3) PHCHO NH/heat Note: The C-13 NMRS for Structures C, D, and E each show 7 resonances LIAIH D E C1HNO ether C1H1SN Br 1) SOCI2, pyridine F 2) CH3OH 1) CH2COCI,AICI3 1) Mg(s), Et20 H 2) diisopropyl amine, pH 4.5, NaBH3CN 2) CO2 (s)...
Hc VCH Draw the organic product formed when CH3CH2CH2OH is treated with each reagent. a H2S04 (180°C) d SOC12, pyridine Ig 1) NaH; 2) CH3CH2Br b NaH e PBr3 h 1) TSCI, pyridine; 2) NaSH c HBr f TsCl, pyridine 3. Draw the organic product formed when l-methylcyclohexanol is treaded with each reagent. In some cases, no reaction occurs. a KH c HBr Te NaHCO3 b Nacid HCI f 1) KH; 2) CH3CH2Br Draw two different routes to each of...
4. Synthesis Reactions. Draw the feature product of the following reactions. (8 x 3 pts) 1. Mg Ph Br 2. CO2 3. H a "NH2 Ph 1. NaOH, CI 2. LAIH b. CHỊCH NHA NaBHgCN, H+ Ph C. Br (excess) NH d NaOH H HO OH H CH e. 1. NaOH H2O NH 2. H+ o= 1. NaOH H2O 2. SOCI N(CH3)2 3 HO
4. Synthesis Reactions. Draw the feature product of the following reactions. (8 x 3 pts) 1. Mg Ph Br 2. CO2 3. H+ 1. NaOH, ANH, 1. NaOH, CANADA ? 2. Lialla NH2 2. LiAIH4 CH3CH2NH2, NaBH3CN, H+ c. PhD Br (excess) CNH LB (excess) NaOH H+ YO- OH . H' CH3 1. NaOH, H2O NH - 2. H+ 1. NaOH, H2O 2. SOCI . N(CH3)2 HO فه H2NCH3 OCH3