2) Provide a product for each of the following reactions. Ensure correct chemoselectivity, stereoselectivity and regioselectivity...
он e) Na Cr 0. H2SO4, H,0 (excess) NaBH EtOH он Hint: esterification H+ 1 LDA 2) PhCH Br 14 /36
1. Provide the major organic product(s) for each of the following reactions: 1) HNOZ/H, SO 2) Sn/HCl(aq) 3) HO 1) (CH3)2CHCI/AICI: 2) NBS/hv 1) Cly/FeCl3 2) HNO,/H2SO4 1) CH3CH,COCI/AICI 2) H20 оооооооо 3) Zn(Hg)/HCl(aq) 1) SOZ/H,SO 2) Bry/FeBrz 1) (CH3)3CCI/AICI: 2) KMnO/HOIA 2) H30* 1) CH,COCIAICI: 2) H, 3) Bry/FeBry COH 1) SOCI_/pyridine 2) PhCH/AICI 3) H20 1. Br JFeBry 2. Mg/Eto 3. oxirane 4, HO* 1) Bry/FeBry 2) s09/H230 1) NBS/hv 2) PhoNa (1 CH3COCI / AIC وا (2...
VI. Reactions (21 pts) Provide the major product in the following reaction. It as the product Show your work for each stepll Pay attentio Stereochemistry! Product in the following reaction. If no reaction occurs, write" NR stepll pay attention to Regiochemistry and TSCI ElyN 1. CHy-Br (xs) 2 A0,0,H,O, A H-CI E-G NaBH,CN a. NaNs, EtOH b. H20, он 1. SOCI, pyridine 2. NaN, DMF 3. LIAIH, EL 0
2020 - Word Search ences Mailings Review View Help to E ES AL AaBbCcDa AaBb C AaBbCcDd AaBbceDi AaBbccd F Emphasis Heading 1 1 Normal Strong Subtitle Paragraph Styles 1. Reaction Sequences: Draw the structure for the major organic product(s) for six of the following reaction sequences. Each reaction sequence is worth 6 points. Circle your choices. A Na2Cr207 SOCI NH3 H2SO4, H20,4 HNO H,SO 1) Sn, H,O 2) NaOH CI 1) CH,CI, AICI 2) HO, OH В. C. SOCI2...
Name: CHEM 330 Homework #9 Due: 11/06/19 1. Provide the major product for each of the following reactions. If a racemic mixture is produced, you must show them both. (Remember to consider regio- and stereoselectivity) (18 pts) HCI 1) Hg(OAC)2, ETOH 2) NaBH 1) BH; 2) H2O2, NaOH H30* 1) BH3 2) H2O2, NaOH HBr H₂O₂ H2, Pd
1. Predict the product(s) for each of the following reactions: H2SO4 NH2 a. 0 1. H2N-NH2, H2S04, -H20 H 2. KOH/H2O b. MeOH, TsOH он H2O C. H2SO4, -H20 HO d. H2O, H30+ e. H20,H30+ 2. Predict the product and draw the full pushing arrow mechanism for the following reaction NH2 H20,H30+ a. b. 3. Devise an efficient synthesis for the following transformation. HO Br Br
5. Identify the major product expected to form at the completion of the following synthetic sequence. O OH SO3, H2SO4 Br2 H2O H3O*-H2O но ОН Br ОН Он Он Br о Он Br но но Но НО но Br SO3H Br Br (A) (B) (C) (D) (E) 6.Which of the following synthetic sequences is expected to yield 2-chloro-4-nitrobenzoic acid in highest yleld? 1. KMnO OH Cla- FeCl HNO3- H2SO heat (A) 2. H30 1. KMnO4 , OH HNO- H2SO Clo-...
3. (5pts each) For the following reactions, in each box please provide the missing reage or predict the reactants or major products. 1) LDA 2) a. Br Br b. ОН ix x PPh3 c. H d. NaOH, H2O, heat 2eq GE2 e. キミのIII f. -GEN 1) Me-MgBr 2) H,0
1) For the following reactions, draw the product(s). Remember to keep in mind carbocation rearrangements, stereoselectivity (syn/anti addition) and racemic mixture of enantiomers due to formation of new chiral centers. h) Lindlar's catalyst excess CH3CH2C CH HCI H2O, H2S04 HgSo k) 1.9-BBN 2. H202. NaOH CH3CH2CH2-CEc-CH3 excess Ce CH3CH2CH2-CEC-CH3 CCI4 1 eq Br2 CCl 1. Оз 2. H20 n) o) H 1) NaNH2 H3C 2) CH3CH2CH2Br
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O