Homework Answers
Markovnikav addition: The negative part of the reagent is added
to the double bonded carbon atom which is attached to less number
of hydrogen atoms.
Example: Addition of HX, H2O, oxymercuration-demercuration
Anti-Markovnikov addition: the negative part of the reagent is
added to the double bonded carbon atom which is attached more
number of hydrogen atoms.
Example of addition of HX in the presence of light or Peroxide,
Hydroboration-oxidation.
Here reactions a,b, and d are Markovnikav addition
Reactions c,e and f are Antimarkovnikov addition.
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Name: CHEM 330 Homework #9 Due: 11/06/19 1. Provide the major product for each of the...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr Br2 CH2Cl2 HBr...
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
1. Predict the major organic product for each of the following reactions. Be sure to clearly...
1. Predict the major organic product for each of the following reactions. Be sure to clearly indicate the proper stereochemical relationships between groups (if appropriate), and write the word "racemic” under any compound that is formed as a racemic mixture. B12 Ph Ph H20 H2 Pd/C OSO4 CH3 NMO H3C 1) Hg(OAC)2, H20 2) NaBH4, aq. NaOH CH3 812 CCl4 now any resposta Hac 1) BH3, THE 2) H2O2, aq. NaOH
Q 2 - Fill in the boxes with the product(s) for the following reactions. Draw only...
Q 2 - Fill in the boxes with the product(s) for the following reactions. Draw only the predominate regioisomer and indicate the stereochemistry where appropriate. If a racemic mixture is formed, you may indicate this using a wavy line www or mark the chiral center with an asterisk (*), and write racemic in the box. You may also draw both enantiomers and write RACEMIC in the box. 1.BH3 2, H2O2, NaOH 1. Hg(OAc), H20 2. NaBH4 H3C CH3 1.BH 2....
Name Organic Chemistry I Worksheet Due 11/13/19 State the reagents required to perform the following reactions. 1....
Name Organic Chemistry I Worksheet Due 11/13/19 State the reagents required to perform the following reactions. 1. Matching Cl2 HBr. Peroxides (ROOR) Bry, H,0 1) BH, THE 2) H30, OH 1) Hg(OAc), H0 2) NaBH, OH H:0, H SO. HCI
1. Give the major product of the following reactions, write NR. if no reaction happens. Indicate the stereochemistr...
1. Give the major product of the following reactions, write NR. if no reaction happens. Indicate the stereochemistry if necessary CHCI KOC(CH3). (CH),COH 1. conc. HBr, heat 2. KOBU, HOBU 1. NaOM, MOH CI 2. BICN 1. 1 eq. BH3. THE 2. H2O2, NaOH, H2O 3. Hg(OAC), MeOH 4. NaBH4, NaOH, H2O 1. conc. HCI 2. LDA, THF 3. O. CH,OH 4.(CH), 1. Hg(OAC), THE 2. NaBH, NaOH, H2O > OH (Hint: product has a bicyclic ring)
3. Complete the following reactions of the compound shown by drawing the correct products with CORRECT...
3. Complete the following reactions of the compound shown by drawing the correct products with CORRECT stereochemistry if important (10 pts). Br Br2 in H2O 1. O3 2. MegS HO H2/Pd OP A01018 1. Hg(OAc)2 in THF/Water 2. NaBH NaOH 1. BH3-THF 2. H2O2, NaOH estolqind, ( ym peroxyacid he anolbe o s HBr HBr/peroxide 1. OsO4 2. NAHSO3
CHEM 330 Homework # 9 Name: Due: 11/06/19 Identify which of the following two reactions you would expect to occur more...
CHEM 330 Homework # 9 Name: Due: 11/06/19 Identify which of the following two reactions you would expect to occur more rapidly and then explain your choice. (2 pts) 4. НЕг HЕг 5. Suggest an efficient target synthesis for the following transformation. (3 pts) OH 2 steps Br Provide the complete mechanism for the following reaction. (6 pts) 6 но HаРОд Н-о
please explain fully with details. thanks 6. Predict the major product(s) for each of the following...
please explain fully with details. thanks
6. Predict the major product(s) for each of the following reactions. Include Swi regiochemistry/stereochemistry where appropriate. HCI b) ? Brą, H20 1) Hg(OAC)2, H20 2) NaBH4 1) BH3, THE 2) H2O2, NaOH e) ? 1) MCPBA 3) 2 , Hyor 1) O3 2) Zn, H30*
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (10 points total) Br...
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (10 points total) Br HBr CH2CI Br2 HBr Но ROOR CH,OH Н,о н* Н,о° 1) Hg(O,CCF3)2 CH,OH 1) BН, THF 2) H,О, NaOH, Нао 2) NaBH, NaOH 1) Hg(OAc) Н0, THF/ Hа Pd/C 2) NaBH, NaOH
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
1. Predict the major organic product for each of the following reactions. Be sure to clearly indicate the proper stereochemical relationships between groups (if appropriate), and write the word "racemic” under any compound that is formed as a racemic mixture. B12 Ph Ph H20 H2 Pd/C OSO4 CH3 NMO H3C 1) Hg(OAC)2, H20 2) NaBH4, aq. NaOH CH3 812 CCl4 now any resposta Hac 1) BH3, THE 2) H2O2, aq. NaOH
Q 2 - Fill in the boxes with the product(s) for the following reactions. Draw only the predominate regioisomer and indicate the stereochemistry where appropriate. If a racemic mixture is formed, you may indicate this using a wavy line www or mark the chiral center with an asterisk (*), and write racemic in the box. You may also draw both enantiomers and write RACEMIC in the box. 1.BH3 2, H2O2, NaOH 1. Hg(OAc), H20 2. NaBH4 H3C CH3 1.BH 2....
Name Organic Chemistry I Worksheet Due 11/13/19 State the reagents required to perform the following reactions. 1. Matching Cl2 HBr. Peroxides (ROOR) Bry, H,0 1) BH, THE 2) H30, OH 1) Hg(OAc), H0 2) NaBH, OH H:0, H SO. HCI
1. Give the major product of the following reactions, write NR. if no reaction happens. Indicate the stereochemistry if necessary CHCI KOC(CH3). (CH),COH 1. conc. HBr, heat 2. KOBU, HOBU 1. NaOM, MOH CI 2. BICN 1. 1 eq. BH3. THE 2. H2O2, NaOH, H2O 3. Hg(OAC), MeOH 4. NaBH4, NaOH, H2O 1. conc. HCI 2. LDA, THF 3. O. CH,OH 4.(CH), 1. Hg(OAC), THE 2. NaBH, NaOH, H2O > OH (Hint: product has a bicyclic ring)
3. Complete the following reactions of the compound shown by drawing the correct products with CORRECT stereochemistry if important (10 pts). Br Br2 in H2O 1. O3 2. MegS HO H2/Pd OP A01018 1. Hg(OAc)2 in THF/Water 2. NaBH NaOH 1. BH3-THF 2. H2O2, NaOH estolqind, ( ym peroxyacid he anolbe o s HBr HBr/peroxide 1. OsO4 2. NAHSO3
CHEM 330 Homework # 9 Name: Due: 11/06/19 Identify which of the following two reactions you would expect to occur more rapidly and then explain your choice. (2 pts) 4. НЕг HЕг 5. Suggest an efficient target synthesis for the following transformation. (3 pts) OH 2 steps Br Provide the complete mechanism for the following reaction. (6 pts) 6 но HаРОд Н-о
please explain fully with details. thanks
6. Predict the major product(s) for each of the following reactions. Include Swi regiochemistry/stereochemistry where appropriate. HCI b) ? Brą, H20 1) Hg(OAC)2, H20 2) NaBH4 1) BH3, THE 2) H2O2, NaOH e) ? 1) MCPBA 3) 2 , Hyor 1) O3 2) Zn, H30*
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (10 points total) Br HBr CH2CI Br2 HBr Но ROOR CH,OH Н,о н* Н,о° 1) Hg(O,CCF3)2 CH,OH 1) BН, THF 2) H,О, NaOH, Нао 2) NaBH, NaOH 1) Hg(OAc) Н0, THF/ Hа Pd/C 2) NaBH, NaOH
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