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1) For the following reactions, draw the product(s). Remember to keep in mind carbocation rearrangements, stereoselectivity...
Problem 10.57 ropose a plausible synthesis for the following transformations. Choose from reagents (A-H): B. 1)...
Problem 10.57 ropose a plausible synthesis for the following transformations. Choose from reagents (A-H): B. 1) NaNH2 2) Mel 3) 9-BBN 4) H202, NaOH 1) Br2 2) Excess NaNH2 3) H20 1) Br2 2) Excess NaNH2 3) H20 4) H2S04. H20, HgSO 1) NaNHz 2) EtI 3) Na, NHa () 1) Excess NaNH2 2) H20 3) NaNH2 4) Mel 5) Na, NH3 C) 1) NaNH2 2) 3) H2, Pt 1) 9-BBN 2) H202, NaOH 1) Excess NaNH2 2) H20 3)...
Q 2 - Fill in the boxes with the product(s) for the following reactions. Draw only...
Q 2 - Fill in the boxes with the product(s) for the following reactions. Draw only the predominate regioisomer and indicate the stereochemistry where appropriate. If a racemic mixture is formed, you may indicate this using a wavy line www or mark the chiral center with an asterisk (*), and write racemic in the box. You may also draw both enantiomers and write RACEMIC in the box. 1.BH3 2, H2O2, NaOH 1. Hg(OAc), H20 2. NaBH4 H3C CH3 1.BH 2....
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H ) 1) CH3Li CrO2, H2S04 1) H 2) H30+ H2O (xs) CI mCPBA (CH3)3COK J) (CH3)3COH CH2Cl2 K) H2SO4, 1800C OH NaH,...
Help sos 1. Show the expected product(s) of the following reactions. For products containin or cis/trar...
Help sos
1. Show the expected product(s) of the following reactions. For products containin or cis/trar asymmetric carbon atoms, indicate relative stereochemistry (syn/anti relationships) and/or whether a racemic mixture is produced. (8 pts each) 1. HNO3, H2so4 NO 2. Fe, HCI OCH3 3. NaNO2 aq. HCI 4, CuCN, Δ сно но 1. Br2 H20 2. Fe SO)S b. HO- -H OH s CH2OH 1. SOCI2 2. NH3 H3C 3. Br2 NaOH, H2O 1. KOH 2. PhCH2CH Br 3. NH2NH2 d....
Draw the structure of the final product(s) of this series of reactions 1pt ernces 1 pt...
Draw the structure of the final product(s) of this series of reactions 1pt ernces 1 pt 1. Br 1 pt 2.3 equivalents of NaNH 3. mild acid 1 pt 4. BH 5. H202/ NaOH 1 pt 1 pt 1 pt Use the wedge/hash bond tools to indicate stereochemistry where it exists Include H atoms at chiral centers only If a group is achiral, do not use wedged or hashed bonds on it Draw organic species only. Do not include lone...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state 'No Reaction'. HI H) 1) CH3Li CrO3, H2SO4 1) H 2) H30+ H20 (xs) CI mCPBA (CH3)3COK J) (CH3)3COH CHCI2 K) H2SO4, 1800C OH Nah, DMSO...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H) 1) CHELI 2) H30 CrOg, H2SO4 H20 (xs) 1) mCPBA J) (CH3),COK (CH3)3COH CH,CI2 K) H2SO4 180°C OH L NaH, DMSO Br...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H) 1) CHELI 2) H30 CrOg, H2SO4 H20 (xs) 1) mCPBA J) (CH3),COK (CH3)3COH CH,CI2 K) H2SO4 180°C OH L NaH, DMSO Br...
7.2 b) c) Draw the major organic product(s) of the following reaction. CH3 H3C-C-CEC-H | NaNH, / NH (1) more pollastre...
7.2
b)
c)
Draw the major organic product(s) of the following reaction. CH3 H3C-C-CEC-H | NaNH, / NH (1) more pollastre CH3CH2–1 CH3 • You do not have to consider stereochemistry. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. Draw the organic product(s) of the following reaction. NaOC2H5...
Draw the product(s) of the following reactions. 1. BH3 / THE CH3CH2CH2-CEC-H 2. H2O2/ aqueous NaOH...
Draw the product(s) of the following reactions. 1. BH3 / THE CH3CH2CH2-CEC-H 2. H2O2/ aqueous NaOH • You do not have to consider stereochemistry, • Separate multiple products using the + sign from the drop-down menu. • You do not have to explicitly draw H atoms. • If no reaction occurs, draw the organic starting material. C - - OOO - [F ChemDoodle remove Draw the product(s) of the following reactions. H2 H9C -CC-CH3 Pd/C • Consider E/Z stereochemistry of...
Problem 10.57 ropose a plausible synthesis for the following transformations. Choose from reagents (A-H): B. 1) NaNH2 2) Mel 3) 9-BBN 4) H202, NaOH 1) Br2 2) Excess NaNH2 3) H20 1) Br2 2) Excess NaNH2 3) H20 4) H2S04. H20, HgSO 1) NaNHz 2) EtI 3) Na, NHa () 1) Excess NaNH2 2) H20 3) NaNH2 4) Mel 5) Na, NH3 C) 1) NaNH2 2) 3) H2, Pt 1) 9-BBN 2) H202, NaOH 1) Excess NaNH2 2) H20 3)...
Q 2 - Fill in the boxes with the product(s) for the following reactions. Draw only the predominate regioisomer and indicate the stereochemistry where appropriate. If a racemic mixture is formed, you may indicate this using a wavy line www or mark the chiral center with an asterisk (*), and write racemic in the box. You may also draw both enantiomers and write RACEMIC in the box. 1.BH3 2, H2O2, NaOH 1. Hg(OAc), H20 2. NaBH4 H3C CH3 1.BH 2....
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H ) 1) CH3Li CrO2, H2S04 1) H 2) H30+ H2O (xs) CI mCPBA (CH3)3COK J) (CH3)3COH CH2Cl2 K) H2SO4, 1800C OH NaH,...
Help sos
1. Show the expected product(s) of the following reactions. For products containin or cis/trar asymmetric carbon atoms, indicate relative stereochemistry (syn/anti relationships) and/or whether a racemic mixture is produced. (8 pts each) 1. HNO3, H2so4 NO 2. Fe, HCI OCH3 3. NaNO2 aq. HCI 4, CuCN, Δ сно но 1. Br2 H20 2. Fe SO)S b. HO- -H OH s CH2OH 1. SOCI2 2. NH3 H3C 3. Br2 NaOH, H2O 1. KOH 2. PhCH2CH Br 3. NH2NH2 d....
Draw the structure of the final product(s) of this series of reactions 1pt ernces 1 pt 1. Br 1 pt 2.3 equivalents of NaNH 3. mild acid 1 pt 4. BH 5. H202/ NaOH 1 pt 1 pt 1 pt Use the wedge/hash bond tools to indicate stereochemistry where it exists Include H atoms at chiral centers only If a group is achiral, do not use wedged or hashed bonds on it Draw organic species only. Do not include lone...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state 'No Reaction'. HI H) 1) CH3Li CrO3, H2SO4 1) H 2) H30+ H20 (xs) CI mCPBA (CH3)3COK J) (CH3)3COH CHCI2 K) H2SO4, 1800C OH Nah, DMSO...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H) 1) CHELI 2) H30 CrOg, H2SO4 H20 (xs) 1) mCPBA J) (CH3),COK (CH3)3COH CH,CI2 K) H2SO4 180°C OH L NaH, DMSO Br...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H) 1) CHELI 2) H30 CrOg, H2SO4 H20 (xs) 1) mCPBA J) (CH3),COK (CH3)3COH CH,CI2 K) H2SO4 180°C OH L NaH, DMSO Br...
7.2
b)
c)
Draw the major organic product(s) of the following reaction. CH3 H3C-C-CEC-H | NaNH, / NH (1) more pollastre CH3CH2–1 CH3 • You do not have to consider stereochemistry. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. Draw the organic product(s) of the following reaction. NaOC2H5...
Draw the product(s) of the following reactions. 1. BH3 / THE CH3CH2CH2-CEC-H 2. H2O2/ aqueous NaOH • You do not have to consider stereochemistry, • Separate multiple products using the + sign from the drop-down menu. • You do not have to explicitly draw H atoms. • If no reaction occurs, draw the organic starting material. C - - OOO - [F ChemDoodle remove Draw the product(s) of the following reactions. H2 H9C -CC-CH3 Pd/C • Consider E/Z stereochemistry of...
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