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1. Show the expected product(s) of the following reactions. For products containin or cis/trar...
1) For the following reactions, draw the product(s). Remember to keep in mind carbocation rearrangements, stereoselectivity...
1) For the following reactions, draw the product(s). Remember to keep in mind carbocation rearrangements, stereoselectivity (syn/anti addition) and racemic mixture of enantiomers due to formation of new chiral centers. h) Lindlar's catalyst excess CH3CH2C CH HCI H2O, H2S04 HgSo k) 1.9-BBN 2. H202. NaOH CH3CH2CH2-CEc-CH3 excess Ce CH3CH2CH2-CEC-CH3 CCI4 1 eq Br2 CCl 1. Оз 2. H20 n) o) H 1) NaNH2 H3C 2) CH3CH2CH2Br
Draw the major product(s) or reagents for the following reactions. Pay attention to stereochemistry where appropriate....
Draw the major product(s) or reagents for the following
reactions. Pay attention to stereochemistry where appropriate. Put
a box or circle around your final answer.
1. NaN Br g. 2. H2 (xs), Pod 1. xs LAH 2. H20 h. NH2 3. ethyl iodide (xs) 1. NaNO2, HC 2. CuCN NH2 3. PhMgBr (xs) 4. Hyo xs LiAI(OR) H 0 1. Br2. FeBr 2. SOCI2. Py NH2 k.
2. Reactions: (27 pts) Draw the structure of the expected organic product(s) formed in the following...
2. Reactions: (27 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state 'No Reaction'. H2, Pd/C Cla, hv A) Br CH2OH B) C) CH2CH2CH2OH H2SO4 NaBH4 SOCI2 D) H CH3CH2OH TEA OTS CH3 SNa E) DMSO OH PCC...
9-17. Syntheses: draw / provide the likely organic product(s) generated in each of the reactions (or...
9-17. Syntheses: draw / provide the likely organic product(s) generated in each of the reactions (or reaction sequences) below. As appropriate, pay attention to regiospecificity (new bond formation and location in the product formed) and stereochemistry (direction in space of new bond[s] formed). Indicate ALL likely products; where one product does not predominate, label / indicate the MAJOR product(s). Where a product mix results, indicate the MINOR or TRACE product(s). (12 pts) 9. First, exhaustively alkylate, then add Ag20 and...
Problem #1 Predict the major product(s) from the following reactions: 1.03 2. DMS CHE H3C 1....
Problem #1 Predict the major product(s) from the following reactions: 1.03 2. DMS CHE H3C 1. CH2CO3H 2. H30* CHE CH3 cat. OsO4 t-BuOOH CH KMnO4 CH3 cold CH3 CH₃ H₃C H₂ ? -CH₃ CH3 НАС 1. BH3-THF 2. H2O2, NaOH ? CH3 Brz CH3 CH2OH
0/1 pts ncorrect Question 1 Select from the list of numbered reagents/conditions the correct order that...
0/1 pts ncorrect Question 1 Select from the list of numbered reagents/conditions the correct order that would yield the desired synthesis indicated below. Enter as your answer the sequence of numbers separated by commas. This synthesis is not intended to be an efficient or elegant approach; rather, it is intended to get you to "revisit" several reactions so that you can become more facile using your mental synthesis toolbox. CH4 9. CH3Br, FeBr3 10. xs NH3 11. SOC2. pyridine 12....
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO...
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO ROOR Question 2: Draw a mechanism for the following transformations: a) H₃C CH3 HCI H₂C T CH3 HAC CH3 нс с Question 3: Draw the mechanism for the following transformations: нс сH3 CH3 о (H,SO4), он H₂C7 Question 4 HĄCE 1) Hg(OAC), H, 2) NaBH, HEC CH, Question : Predict the product(s) of the following reaction: 1) BHZ. THE Н4С SCH, 2) H2O, NaOH...
1) Determine the major product(s) of the following reactions. Show all appropriate stereochemistry. HCI Br2 1)...
1) Determine the major product(s) of the following reactions. Show all appropriate stereochemistry. HCI Br2 1) BH3 w o dd 2) H202, NaOH (aq) Br2, H20
1. (24) Write structural formulas for the major organic product(s) for the following reactions. Be sure...
1. (24) Write structural formulas for the major organic product(s) for the following reactions. Be sure to indicate the stereochemistry when relevant. HC CH=CH2 H CH,OH CH2OH 1. Na, liq. NH (b) CH,CH.C=CCH CH3 HẠCH, B, P NH, 2.D2, Pt Cl2 HC CCH2CH=CH CH,CH HCC CH,Cl2 1. BH/THF (d) CH,CH,C=CH2 2. H,02, HO", H0 CH -0.47- CH; Br2 excess NaCl 1. 03,-78°C 2. (CH3)2S woboto (h) + Br₂ -
1. For each of the following reactions, provide the structure of the major organic product(s). Show...
1. For each of the following reactions, provide the structure of the major organic product(s). Show all the relevent stereochemistry clearly. who CH2OH reflux CH2CH3 Na SET Br DMSO, 20 °C I- A to CH2CH3 CH3 H- EtOH OTS 20 °C Me NaNH2 NH2 DMSO dilute solution of substrate 2. Complete each of the following reaction by providing reagents and conditions (solvent. temperature, concentration, etc.) so that the product shown will be the major one. Note: for c), two steps...
1) For the following reactions, draw the product(s). Remember to keep in mind carbocation rearrangements, stereoselectivity (syn/anti addition) and racemic mixture of enantiomers due to formation of new chiral centers. h) Lindlar's catalyst excess CH3CH2C CH HCI H2O, H2S04 HgSo k) 1.9-BBN 2. H202. NaOH CH3CH2CH2-CEc-CH3 excess Ce CH3CH2CH2-CEC-CH3 CCI4 1 eq Br2 CCl 1. Оз 2. H20 n) o) H 1) NaNH2 H3C 2) CH3CH2CH2Br
Draw the major product(s) or reagents for the following
reactions. Pay attention to stereochemistry where appropriate. Put
a box or circle around your final answer.
1. NaN Br g. 2. H2 (xs), Pod 1. xs LAH 2. H20 h. NH2 3. ethyl iodide (xs) 1. NaNO2, HC 2. CuCN NH2 3. PhMgBr (xs) 4. Hyo xs LiAI(OR) H 0 1. Br2. FeBr 2. SOCI2. Py NH2 k.
2. Reactions: (27 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state 'No Reaction'. H2, Pd/C Cla, hv A) Br CH2OH B) C) CH2CH2CH2OH H2SO4 NaBH4 SOCI2 D) H CH3CH2OH TEA OTS CH3 SNa E) DMSO OH PCC...
9-17. Syntheses: draw / provide the likely organic product(s) generated in each of the reactions (or reaction sequences) below. As appropriate, pay attention to regiospecificity (new bond formation and location in the product formed) and stereochemistry (direction in space of new bond[s] formed). Indicate ALL likely products; where one product does not predominate, label / indicate the MAJOR product(s). Where a product mix results, indicate the MINOR or TRACE product(s). (12 pts) 9. First, exhaustively alkylate, then add Ag20 and...
Problem #1 Predict the major product(s) from the following reactions: 1.03 2. DMS CHE H3C 1. CH2CO3H 2. H30* CHE CH3 cat. OsO4 t-BuOOH CH KMnO4 CH3 cold CH3 CH₃ H₃C H₂ ? -CH₃ CH3 НАС 1. BH3-THF 2. H2O2, NaOH ? CH3 Brz CH3 CH2OH
0/1 pts ncorrect Question 1 Select from the list of numbered reagents/conditions the correct order that would yield the desired synthesis indicated below. Enter as your answer the sequence of numbers separated by commas. This synthesis is not intended to be an efficient or elegant approach; rather, it is intended to get you to "revisit" several reactions so that you can become more facile using your mental synthesis toolbox. CH4 9. CH3Br, FeBr3 10. xs NH3 11. SOC2. pyridine 12....
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO ROOR Question 2: Draw a mechanism for the following transformations: a) H₃C CH3 HCI H₂C T CH3 HAC CH3 нс с Question 3: Draw the mechanism for the following transformations: нс сH3 CH3 о (H,SO4), он H₂C7 Question 4 HĄCE 1) Hg(OAC), H, 2) NaBH, HEC CH, Question : Predict the product(s) of the following reaction: 1) BHZ. THE Н4С SCH, 2) H2O, NaOH...
1) Determine the major product(s) of the following reactions. Show all appropriate stereochemistry. HCI Br2 1) BH3 w o dd 2) H202, NaOH (aq) Br2, H20
1. (24) Write structural formulas for the major organic product(s) for the following reactions. Be sure to indicate the stereochemistry when relevant. HC CH=CH2 H CH,OH CH2OH 1. Na, liq. NH (b) CH,CH.C=CCH CH3 HẠCH, B, P NH, 2.D2, Pt Cl2 HC CCH2CH=CH CH,CH HCC CH,Cl2 1. BH/THF (d) CH,CH,C=CH2 2. H,02, HO", H0 CH -0.47- CH; Br2 excess NaCl 1. 03,-78°C 2. (CH3)2S woboto (h) + Br₂ -
1. For each of the following reactions, provide the structure of the major organic product(s). Show all the relevent stereochemistry clearly. who CH2OH reflux CH2CH3 Na SET Br DMSO, 20 °C I- A to CH2CH3 CH3 H- EtOH OTS 20 °C Me NaNH2 NH2 DMSO dilute solution of substrate 2. Complete each of the following reaction by providing reagents and conditions (solvent. temperature, concentration, etc.) so that the product shown will be the major one. Note: for c), two steps...
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