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Rank these reaction conditions for the rate of formation of elimination products from 2-Chloro-3- 5. methylbutane....
che 1. Rank from fastest (1) to slowest (5) the rates of the SN2 reaction of...
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1. Rank from fastest (1) to slowest (5) the rates of the SN2 reaction of the compounds shown. Br Br CH3-C-CH3 CH3 CHaCHs CH2 CH-CH21 CH-CH,он CH3CH2Br 2. Rank from fastest (1) to slowest (5) the rates of the solvolysis reaction in HOAC/HOH of the compounds shown. Br Br CH3-с-CHз CH3CH2OH CH2-CH-CH21 CH3-C-CH3 CH3 CH3CH2Br B. Circle the number corresponding to the correct answer. Answer 5. a) What is the principal determinant of reaction order? i. structure of substrate...
b) When the following deuterated compound reacts under the same conditions, the rate of formation of...
b) When the following deuterated compound reacts under the same conditions, the rate of formation of the substitution product is unchanged, but the elimination rate is slowed by a factor of 7. Why is the elimination slowed, but substitution unchanged? D3C-CH-CD3 + KOH - D2C=CH-CD3 + D3C-CH-CD3 Br alcohol OH (20) 7. Which reaction of the following pairs will take place more rapidly? a) CH, CH, CH, Br + CH, OH — CH, CH, CH, Br + CH30 — b)...
Which statement or set of conditions listed below is not consistent with an Syl reaction pathway?...
Which statement or set of conditions listed below is not consistent with an Syl reaction pathway? O a. Neutral nucleophile work just fine. b. The leaving group is typically the conjugate base of a strong acid. O c. The rate is not dependent upon the concentration of the nucleophile. d. The temperature is relatively "cooler" to reduce competing elimination products. e. The solvent is polar and aprotic. Of. The substrate has a leaving group that is typically on a 30,...
need help with part c and d L euly butane 2-chloro-2-methylbutane 2-chloro-3-methylbutane 2-chlorobutane c) Draw a...
need help with part c and d
L euly butane 2-chloro-2-methylbutane 2-chloro-3-methylbutane 2-chlorobutane c) Draw a curved-arrow mechanism for the following reaction: - H2O Hạº, d) Label the following reactions as S1, S2, E1, E2, addition, or acid/base (2 pts, cach). i. Bromoethane becomes ethanol upon treatment with hydroxide ion. ii. 1-Methyl-1-cyclohexanol reacts with acid in water to form l-methylcyclohexene. iii. Propyne becomes propane in the presence of hydrogen and metal catalyst. iv. I-iodopropane reacts with potassium tert-butoxide. SN e)...
30) Give the major elimination product for the reaction. (3 points) 2"он CHs CH3 Br CHs 31) Give the major product for the E2 reaction. (3 points) CH3 0 CH3 CH3 CHs CHCH2 C 32) What is the major...
30) Give the major elimination product for the reaction. (3 points) 2"он CHs CH3 Br CHs 31) Give the major product for the E2 reaction. (3 points) CH3 0 CH3 CH3 CHs CHCH2 C 32) What is the major product of the following reactions?(6 points) CH он HCI, Δ
30) Give the major elimination product for the reaction. (3 points) 2"он CHs CH3 Br CHs 31) Give the major product for the E2 reaction. (3 points) CH3 0 CH3 CH3...
aromatic reaction worksheet 2. b IV. fastest > slowest 3. Under each reaction, circle the correct...
aromatic reaction worksheet
2. b IV. fastest > slowest 3. Under each reaction, circle the correct operating mechanism 1) NaNH, NH. --Br 2) 1,0 EAS, SNAr, or Elimination-Addition b) FeBry HC- Br? EAS, SyAr, or Elimination-Addition 1) NaOH, 70°C ON- -Br 2)H,0 EAS, SyAr, or Elimination-Addition Topose a synthesis of each of the following compounds, from the given starting material and any other needed reagents. -OH from -CH2-CH3 c= CH2 from -CH2-CH2-CH, from
1. 3-methyl-1-butene on reaction with H-Cl forms two products, namely 2-chloro-3- methylbutane (minor) and 2-chloro-2-methylbutane (major)....
1. 3-methyl-1-butene on reaction with H-Cl forms two products, namely 2-chloro-3- methylbutane (minor) and 2-chloro-2-methylbutane (major). Illustrate the mechanism for the formation of these two products. Use curved arrows to illustrate electron movement and all intermediates must be shown. 2. 3,3-dimethyl-1-butene on reaction with HBr forms two products, namely 3-bromo-2,2- dimethylbutane (minor) and 2-bromo-2,3-dimethylbutane (major). Illustrate the mechanism for the formation of these two products. Use curved arrows to illustrate electron movement and all intermediates must be shown. 3. Calculate...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions is: HZC Br CH3 A. 1 B. | F—CH,BH C. CH3-C-CH-CH, CHz CH3 D. CH3 CH3-C-CH2CH2-Br CH3 E. A Br 2. Your task is to convert 2-chloropentane into 1-pentene. Which reagents would you choose? a) NaOH/H20 b) KOH/CH3OH c) CH3ONa/CH3OH d) CH3CH2ONa/CH3CH2OH e) (CH3)3COK/(CH3)3COH 3. Circle the reaction below which is faster in polar protic solvents. OH,H,O A. CH,CH,CH,Br- CH,CH,CH,OH + Br or SH.RSH...
3) Complete the reactions to show the multi-step syntheses of each product from (R)-2 bromo-3-methylbutane. Reaction...
3) Complete the reactions to show the multi-step syntheses of each product from (R)-2 bromo-3-methylbutane. Reaction conditions go in boxes above arrows (1 reaction/box) Complete the template molecules provided to show each step of the synthesis. [20] Hint- This question involves addition, elimination, substitution and alcohol chemistry Br (R)-2-bromo-3-methylbutane 3-methylbutan-1-ol (R)-2-bromo-3-methylbutane (R)-3-bromo-2 methylbutan-2-ol (R)-2-bromo-3-methylbutane (1-chloro-2-methylbutane (R)-2-bromo-3-methylbutane CN ()-1-cyano-3-methylbutan-1-ol
3) Identify the tertiary alcohols). Draw the products of the elimination upon reaction with 3) H2804...
3) Identify the tertiary alcohols). Draw the products of the elimination upon reaction with 3) H2804 for the chosen compound. Assign the most stable alkene product according to the Zaitsev rule. OH ol OEI s) only lI C only III Dy both I and III A) only I ) Which of the following alkenes exhibit cis-trans isomerism? Il. (CHab-CHCHa A) II and IV B) 1 and II O I and III Dy I, II, and I s5) Which of the...
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1. Rank from fastest (1) to slowest (5) the rates of the SN2 reaction of the compounds shown. Br Br CH3-C-CH3 CH3 CHaCHs CH2 CH-CH21 CH-CH,он CH3CH2Br 2. Rank from fastest (1) to slowest (5) the rates of the solvolysis reaction in HOAC/HOH of the compounds shown. Br Br CH3-с-CHз CH3CH2OH CH2-CH-CH21 CH3-C-CH3 CH3 CH3CH2Br B. Circle the number corresponding to the correct answer. Answer 5. a) What is the principal determinant of reaction order? i. structure of substrate...
b) When the following deuterated compound reacts under the same conditions, the rate of formation of the substitution product is unchanged, but the elimination rate is slowed by a factor of 7. Why is the elimination slowed, but substitution unchanged? D3C-CH-CD3 + KOH - D2C=CH-CD3 + D3C-CH-CD3 Br alcohol OH (20) 7. Which reaction of the following pairs will take place more rapidly? a) CH, CH, CH, Br + CH, OH — CH, CH, CH, Br + CH30 — b)...
Which statement or set of conditions listed below is not consistent with an Syl reaction pathway? O a. Neutral nucleophile work just fine. b. The leaving group is typically the conjugate base of a strong acid. O c. The rate is not dependent upon the concentration of the nucleophile. d. The temperature is relatively "cooler" to reduce competing elimination products. e. The solvent is polar and aprotic. Of. The substrate has a leaving group that is typically on a 30,...
need help with part c and d
L euly butane 2-chloro-2-methylbutane 2-chloro-3-methylbutane 2-chlorobutane c) Draw a curved-arrow mechanism for the following reaction: - H2O Hạº, d) Label the following reactions as S1, S2, E1, E2, addition, or acid/base (2 pts, cach). i. Bromoethane becomes ethanol upon treatment with hydroxide ion. ii. 1-Methyl-1-cyclohexanol reacts with acid in water to form l-methylcyclohexene. iii. Propyne becomes propane in the presence of hydrogen and metal catalyst. iv. I-iodopropane reacts with potassium tert-butoxide. SN e)...
30) Give the major elimination product for the reaction. (3 points) 2"он CHs CH3 Br CHs 31) Give the major product for the E2 reaction. (3 points) CH3 0 CH3 CH3 CHs CHCH2 C 32) What is the major product of the following reactions?(6 points) CH он HCI, Δ
30) Give the major elimination product for the reaction. (3 points) 2"он CHs CH3 Br CHs 31) Give the major product for the E2 reaction. (3 points) CH3 0 CH3 CH3...
aromatic reaction worksheet
2. b IV. fastest > slowest 3. Under each reaction, circle the correct operating mechanism 1) NaNH, NH. --Br 2) 1,0 EAS, SNAr, or Elimination-Addition b) FeBry HC- Br? EAS, SyAr, or Elimination-Addition 1) NaOH, 70°C ON- -Br 2)H,0 EAS, SyAr, or Elimination-Addition Topose a synthesis of each of the following compounds, from the given starting material and any other needed reagents. -OH from -CH2-CH3 c= CH2 from -CH2-CH2-CH, from
1. 3-methyl-1-butene on reaction with H-Cl forms two products, namely 2-chloro-3- methylbutane (minor) and 2-chloro-2-methylbutane (major). Illustrate the mechanism for the formation of these two products. Use curved arrows to illustrate electron movement and all intermediates must be shown. 2. 3,3-dimethyl-1-butene on reaction with HBr forms two products, namely 3-bromo-2,2- dimethylbutane (minor) and 2-bromo-2,3-dimethylbutane (major). Illustrate the mechanism for the formation of these two products. Use curved arrows to illustrate electron movement and all intermediates must be shown. 3. Calculate...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions is: HZC Br CH3 A. 1 B. | F—CH,BH C. CH3-C-CH-CH, CHz CH3 D. CH3 CH3-C-CH2CH2-Br CH3 E. A Br 2. Your task is to convert 2-chloropentane into 1-pentene. Which reagents would you choose? a) NaOH/H20 b) KOH/CH3OH c) CH3ONa/CH3OH d) CH3CH2ONa/CH3CH2OH e) (CH3)3COK/(CH3)3COH 3. Circle the reaction below which is faster in polar protic solvents. OH,H,O A. CH,CH,CH,Br- CH,CH,CH,OH + Br or SH.RSH...
3) Complete the reactions to show the multi-step syntheses of each product from (R)-2 bromo-3-methylbutane. Reaction conditions go in boxes above arrows (1 reaction/box) Complete the template molecules provided to show each step of the synthesis. [20] Hint- This question involves addition, elimination, substitution and alcohol chemistry Br (R)-2-bromo-3-methylbutane 3-methylbutan-1-ol (R)-2-bromo-3-methylbutane (R)-3-bromo-2 methylbutan-2-ol (R)-2-bromo-3-methylbutane (1-chloro-2-methylbutane (R)-2-bromo-3-methylbutane CN ()-1-cyano-3-methylbutan-1-ol
3) Identify the tertiary alcohols). Draw the products of the elimination upon reaction with 3) H2804 for the chosen compound. Assign the most stable alkene product according to the Zaitsev rule. OH ol OEI s) only lI C only III Dy both I and III A) only I ) Which of the following alkenes exhibit cis-trans isomerism? Il. (CHab-CHCHa A) II and IV B) 1 and II O I and III Dy I, II, and I s5) Which of the...
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