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Show all the monochlorination products of the following reaction: (CH_3)_2CH_2CH_2CH_3 + Cl_2 rightarrow
Consider this reaction: (CH_3)3CBr + H_2O rightarrow (CH_3)_3COH +HBr what effect does doubling the concentration of...
Consider this reaction: (CH_3)3CBr + H_2O rightarrow (CH_3)_3COH +HBr what effect does doubling the concentration of (CH_3)_3CBr have on the rate? a) doubles the rate b) halves the rate c) quadruples the rate d) has no effect on the rate Consider this reaction CH_3CH_2CH_2CI rightarrow NaOH CH_3CH_2CH_2OH what effect does doubling the concentration of NaOH have on the rate? a) doubles the rate b) halves the rate c) quadruples the rate d) has no effect on the rate Consider this...
Consider the mechanism for hydrogen and chlorine: Cl_2 + M rightarrow Cl + Cl + M...
Consider the mechanism for hydrogen and chlorine: Cl_2 + M rightarrow Cl + Cl + M Cl + H_2 rightarrow HCl + H, H + Cl_2 rightarrow HCl + Cl, Cl + Cl + M rightarrow Cl_2 + M. With appropriate steady-state assumptions, we know: d[HCl]/dt = 2 k_2 Squareroot k_1/k_4 [Cl_2]^0.5 [H_2] If NCl_3 is added to the mixture as an inhibitor, the following reaction needs to be considered: NCl_3 + Cl rightarrow NCl_2 + Cl_2 What is the...
Complete the following: (CH_3)_2 C = CH CH_3 + Br_2 rightarrow H_2o
Complete the following: (CH_3)_2 C = CH CH_3 + Br_2 rightarrow H_2o
For the reaction 2 HBr(g) + Cl_2(g) rightarrow 2 HCl(g) + Br_2(g) a. Write the equilibrium...
For the reaction 2 HBr(g) + Cl_2(g) rightarrow 2 HCl(g) + Br_2(g) a. Write the equilibrium constant expression for the reaction. b. Using the following G degree values, calculate Delta G degree for the reaction. HBr(g) = -53.22 kJ/mol HCl(g) = -95.27 kJ/mol Cl_2(g) = 0 kJ/mol Br_2(g) = 3.14 kJ/mol c. Calculate the equilibrium constant K_eq be at 298 K. d. Does this equilibrium lie more with reactants or products?
Which of the following reagent(s) eves the reaction below (A) CH_2Cl (B) Cl_2/Fe (C) Cl_2/AlCl_3 (D)...
Which of the following reagent(s) eves the reaction below (A) CH_2Cl (B) Cl_2/Fe (C) Cl_2/AlCl_3 (D) Cl_2/FeCl_3 (E) Cl_2/HCL Which of the following reagent(s) gives the reaction below (A) NaOH (B) KMnO_4/H_2O (C) Sn/HCL, then NaOH (D) CO_2/H^+ (E) O_2/HCl Which of the following reagent(s) gives the following transformation (A) CH_3COCI/AICI_3, then NaOH (B) CH_3COCl/AlCl_3, (C) CH__3CH_2Cl/AlCl_3, then NaBH_4 (D) CH_3CH_2Cl/AICI_2 then PCC (E) CH_3COCI/AICI_3 then NBS Which of the following reagents (a, b) gives the reactions below (A) a...
For the following reaction: CH_3 OH(aq) + H^+ (aq) + Cl^- (aq) rightarrow CH_3Cl(aq) + H_2O(l)...
For the following reaction: CH_3 OH(aq) + H^+ (aq) + Cl^- (aq) rightarrow CH_3Cl(aq) + H_2O(l) the value of [H^+] was measured over a period of time. Given the data, find the average rate of disappearance of H^+(aq) for the time interval between each measurement. What is the average rate of appearance of CH_3 CI(aq) for the same time intervals?
What is Delta G in kJ for the reaction: Cl_2(g)+ 2 Br^- rightarrow Br_2(l) + 2...
What is Delta G in kJ for the reaction: Cl_2(g)+ 2 Br^- rightarrow Br_2(l) + 2 Cl^- if [Br^-] = 0.100, [Cl^-] = 0.50, and p(Cl_2) = 1.00 atm? The temperature 25 degree C.
Write products for the following acid-base reaction () CH_3 OH + H_2 SO_4 rightarrowoverleftarrow CH_3 OH...
Write products for the following acid-base reaction () CH_3 OH + H_2 SO_4 rightarrowoverleftarrow CH_3 OH + NA^+ NH^-_2 rightarrowoverleftarrow CH_3 NH^+_3 CL^- + Na^+ OH^- rightarrowoverleftarrow + rightarrowoverleftarrow
Use Hess's Law to determine Delta H for the reaction 2 Al(s) + 3 Cl_2(g) rightarrow...
Use Hess's Law to determine Delta H for the reaction 2 Al(s) + 3 Cl_2(g) rightarrow 2 AlCl_3(s) given: 2 Al(s) + 6 HCl(aq) rightarrow 2 AlCl_3(aq) + 3 H_2(g) Delta H = -1049 kJ HCl(g) rightarrow HCl(aq) Delta H = -74.8 kJ H_2(g) + Cl_2(g) rightarrow 2 HCl(g) Delta H = -185 kJ AlCl_3(s) rightarrow AlCl_3(aq) Delta H = -323 kJ
Consider the reaction Cl_2(g) + 3F_2(g) rightarrow 2CIF _3 (g) Delta [Cl_2]/Delta t = -0.077 M/s...
Consider the reaction Cl_2(g) + 3F_2(g) rightarrow 2CIF _3 (g) Delta [Cl_2]/Delta t = -0.077 M/s Find Delta [F_2]/Delta t Express your answer to two significant figures and include the appropriate units. Find Delta [CIF_3]/Delta t Express your answer to two signific ant figures and include the appropriate units.
Consider this reaction: (CH_3)3CBr + H_2O rightarrow (CH_3)_3COH +HBr what effect does doubling the concentration of (CH_3)_3CBr have on the rate? a) doubles the rate b) halves the rate c) quadruples the rate d) has no effect on the rate Consider this reaction CH_3CH_2CH_2CI rightarrow NaOH CH_3CH_2CH_2OH what effect does doubling the concentration of NaOH have on the rate? a) doubles the rate b) halves the rate c) quadruples the rate d) has no effect on the rate Consider this...
Consider the mechanism for hydrogen and chlorine: Cl_2 + M rightarrow Cl + Cl + M Cl + H_2 rightarrow HCl + H, H + Cl_2 rightarrow HCl + Cl, Cl + Cl + M rightarrow Cl_2 + M. With appropriate steady-state assumptions, we know: d[HCl]/dt = 2 k_2 Squareroot k_1/k_4 [Cl_2]^0.5 [H_2] If NCl_3 is added to the mixture as an inhibitor, the following reaction needs to be considered: NCl_3 + Cl rightarrow NCl_2 + Cl_2 What is the...
Complete the following: (CH_3)_2 C = CH CH_3 + Br_2 rightarrow H_2o
For the reaction 2 HBr(g) + Cl_2(g) rightarrow 2 HCl(g) + Br_2(g) a. Write the equilibrium constant expression for the reaction. b. Using the following G degree values, calculate Delta G degree for the reaction. HBr(g) = -53.22 kJ/mol HCl(g) = -95.27 kJ/mol Cl_2(g) = 0 kJ/mol Br_2(g) = 3.14 kJ/mol c. Calculate the equilibrium constant K_eq be at 298 K. d. Does this equilibrium lie more with reactants or products?
Which of the following reagent(s) eves the reaction below (A) CH_2Cl (B) Cl_2/Fe (C) Cl_2/AlCl_3 (D) Cl_2/FeCl_3 (E) Cl_2/HCL Which of the following reagent(s) gives the reaction below (A) NaOH (B) KMnO_4/H_2O (C) Sn/HCL, then NaOH (D) CO_2/H^+ (E) O_2/HCl Which of the following reagent(s) gives the following transformation (A) CH_3COCI/AICI_3, then NaOH (B) CH_3COCl/AlCl_3, (C) CH__3CH_2Cl/AlCl_3, then NaBH_4 (D) CH_3CH_2Cl/AICI_2 then PCC (E) CH_3COCI/AICI_3 then NBS Which of the following reagents (a, b) gives the reactions below (A) a...
For the following reaction: CH_3 OH(aq) + H^+ (aq) + Cl^- (aq) rightarrow CH_3Cl(aq) + H_2O(l) the value of [H^+] was measured over a period of time. Given the data, find the average rate of disappearance of H^+(aq) for the time interval between each measurement. What is the average rate of appearance of CH_3 CI(aq) for the same time intervals?
What is Delta G in kJ for the reaction: Cl_2(g)+ 2 Br^- rightarrow Br_2(l) + 2 Cl^- if [Br^-] = 0.100, [Cl^-] = 0.50, and p(Cl_2) = 1.00 atm? The temperature 25 degree C.
Write products for the following acid-base reaction () CH_3 OH + H_2 SO_4 rightarrowoverleftarrow CH_3 OH + NA^+ NH^-_2 rightarrowoverleftarrow CH_3 NH^+_3 CL^- + Na^+ OH^- rightarrowoverleftarrow + rightarrowoverleftarrow
Use Hess's Law to determine Delta H for the reaction 2 Al(s) + 3 Cl_2(g) rightarrow 2 AlCl_3(s) given: 2 Al(s) + 6 HCl(aq) rightarrow 2 AlCl_3(aq) + 3 H_2(g) Delta H = -1049 kJ HCl(g) rightarrow HCl(aq) Delta H = -74.8 kJ H_2(g) + Cl_2(g) rightarrow 2 HCl(g) Delta H = -185 kJ AlCl_3(s) rightarrow AlCl_3(aq) Delta H = -323 kJ
Consider the reaction Cl_2(g) + 3F_2(g) rightarrow 2CIF _3 (g) Delta [Cl_2]/Delta t = -0.077 M/s Find Delta [F_2]/Delta t Express your answer to two significant figures and include the appropriate units. Find Delta [CIF_3]/Delta t Express your answer to two signific ant figures and include the appropriate units.
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