Question
Please match the compound to its spectrum and explain why
cpd 22
Spectrum A 100- 60 40 20 100 125 50 75 m/z Spectrum B 100 80- 60 40 20- 10 20 30 40 50 60 70 0 90 100 110 120 m/z
(6 points) Match EOT Spectrum C 100- 80- 60 40 75 100 125 50 m/z Spectrum D 100 80 60- 40 20- 25 50 75 100 125 m/z
Spectrum E 100 80 60 20 10 20 30 40 50 60 70 80 90 100 110 120 m/z Spectrum F 100 80- 2 40 20 1 10 20 30 40 50 60 70 80 0 100
Spectrum G 100 80 60 20 20 30 40 50 60 70 80 90 100 110 120 130 Spectrum H 100 80 60 40 20 10 20 30 40 50 60 70 80 90 100 110
Spectrum I 40 50 60 70 80 90 100 110 120 m/ z Spectrum J 100 80 60 40- 20- 0 50 75 100 125 25 m/ z
Spectrum K 100 60 20- 10 20 30 40 50 6 70 0 90 100 110 120 m/z Spectrum L 100 80 60 2 40 10 ГО 30 40 50 60 70 80 90 100 110 1
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Answer #1

In mass spectrum the peak with highest m/z value is called as molecular ion peak. That mass is called as molecular ion mass.

Molecular formula of the given compound is C7H13NO.

Molar mass of the compound is,

7(C)+13(H)+1(N)+1(O)

= 7(12)+13(1(+1(14)+1(16)

= 84+13+14+16

=127

The 13C atom M+1 peak molar mass is 128

Hence the molecular ion (M) peak m/z is 127.

Eliminate the spectrums which are not having molecular ion peak at 127.

Therefore the correct option is spectrum A.

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