Draw the structure with the mass spectrum and NMR. 151) (Mass of molecular ion: 100e-1N-7213 80...
A variety of spectra for an organic compound with molecular formula C10H16O are presented below. The experimental accurate mass using (+) APCI source is 153.1280 u. The 1H, 13C, COSY, HSQC and HMBC NMR spectra are given in the following slides. Propose a structure for this unknown and answer or address the following questions or requirements: d. If there are still any questionable assignments, propose additional NMR experiments which would solve those questions and briefly explain specifically what correlations you...
A variety of spectra for an organic compound with molecular formula C10H16O are presented below. The experimental accurate mass using (+) APCI source is 153.1280 u. The 1H, 13C, COSY, HSQC and HMBC NMR spectra are given in the following slides. Propose a structure for this unknown and answer or address the following questions or requirements: a. Using the most abundant isotopes of C, H and O, what are the errors in ppm and milli-Daltons for the experimental accurate mass?...
label the spectrum OTBS Meo Yome Me H NMR spectrum (CDC13, 400 MHz) 8.5 8.0 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 f1 (ppm) 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0.0 -0.5 18C NMR spectrum (CDCI, 100 MHz) 210 200 190 180 170 160 150 140 130 120 110 100 fi (ppm) 90 80 70 60 50 40 30 20 10 -10
draw structure of C8H10 and C8H8O2 based on the 1HNMR AND 13C-NMR shown in the pictures provided. any tips of steps will help! thank you! please scroll for all lictures! C-NMR data given. D ons: Solve the structures for C8H10 and C8H8O2 using only the molecular formula and 'H- and R data given. DO NOT WORK IN GROUPS. You may ask your TA for minor assistance. You may use your tab manual (pages 31-39). Please write your final structures in...
CHEM210 Name 3. Based on the molecular formula and spectrum below, propose a structure to analyze each peak using the information on chemical shift, integration, and multiplicity lean role. The insets are expanded views of each peak so that the muplicity is clear. propose a structure for the molecule. Show your work it, integration, and multiplicity learned in the tutorial. Molecular Formula: CH..0: Predicted 1H NMR Spectrum 34 4.15 4.10 ppm 4.05 1.30 1.25 1.20 ppm 1.15 1.00 OH 2.50...
analyze this NMR & IR S23 CDC13 QE-300 240 UN (43 MIL.) 10.02s, 1H), 7.716.J-2 Hz. ) 2.0 11.5 11.0 10.5 10.0 9.5 9.0 8.5 8.0 7.5 7.0 6.5 6.0 4.0 3.5 3.0 2.5 20 15 100.5 0.0 -0.5 -1.0 -1.5 -2. 5.5 5.0 4.5 fl (ppm)
Assign the NMR peaks below DIRECTLY onto the paper, please!!!! The impurities are water at 2.19 ppm and acetone at 1.6 ppm. So just ignore those peaks. The peaks for the aromatic Hydrogens can be grouped up to one (I believe they are the left most peaks at around 7 to 7.5 ppm. Given that please assign the rest of the hydrogens. We were unable to transcribe this imager2 30 25 20 15 10 9.0 8.5 8.0 7.5 7.0 6.5...
Please give the structure based on the NMR spectra depicted. Compound G: Molecular formula = C9H12. Key Infrared signal: 3082, 749, 699 cm 5H, m 3H, t 2H, sextet 2H, t 10 Heoe-ese Pprn Draw your final in this box. Compound H: Molecular formula C$H10O. Infrared signal: 2874, 2719, 1726 cm 3H, t 9-10 2H, 2H, t udd sextet 1H, singlet 2H, pentet 1.5 2.0 1.0 PPM 3.0 t0 5 10.0 9 9.0 8.5 8.0 7.5 7.0 6.5 PPM Draw...
V. Draw the structures of Compound 23A (6 pts). Compound 23B (6 pts) and clearly indicate your assignments of all proton resonances using the lower case letter associated with the signal (6 pts). Calculate the Unsaturation Index of each compound (2 pts) (20 points total) 1.24 126 25 e = 1.25 ppm 20 doublet, 6H a = 10.0 ppm 1.5 singlet, 1H 10 00 10 0.5 Compound 23a: CH,20 Unsat. Index = (2C+2-H-X+N¥2 = 70 7.09 X=number of halogens b=7.84...
Analyze the peaks in this NMR spectrum of p-nitrophenol assigning the peaks, discuss multiplicity, splitting, shielding/deshielding effects, and integration. I have assigned the peaks but i am not sure if i have done it correctly. Is there expected to a peak for the -OH? or is there not a peak because the proton is exchangeable? is there complex or normal splitting observed? 901 C 18 1.00 19 -429 -7.5 7030 P-nitrophenol OH H NMR, nitrophenol in CDCl un A 7...