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1. Predict the product of each of the following reactions and explain why you obtain different...
Question 1: draw a mechanism for each of the reactions.
Explain why the different amines create different products.
Question 2: Explain the product distribution. primary vs.
secondary or tertiary amines and their corresponding
products.
1. Draw a mechanism for each of the transformations (primary and secondary amines). Explain why the two different amines lead to different molecules. NaOH RNH2 + CHCI 1° amine R-NEC RNH + CHCI- 2º amine HNR2 2. What are some likely reasons that contribute to this...
Predict the product in each of the following Diels-Alder reactions.
Predict the product in each of the following Diels-Alder reactions. Cyclopentadience reacts as a diene in the Diels-Alder reaction a great deal faster than does 1,3-butadience. Explain. Predict the diene and dienophile that would lead to each of the following products.
Question 1 Predict the major product(s) for each of the following reactions. Show both enantiomers if a racemic mixture is formed: 1) MCPBA 2) H3O 1) BH3 THF 2) H202 NaOH HBr Br, H2 Pt
Draw the major products for the following reactions. If more
than one product is formed equally draw both,
HgSO4 HBr HOOH Brz 1) NaNH, 2) CH,CH,CH,Br
3 Predict the products for the following reactions ( 3 pts each): NO Ci a. AlCh но..//> HNOg MgBr ether C. H3O+ Br 1 H2N NH2 DMF d) 2. NaOH, H20 4. If you were to nitrate chlorobenzene what would be the product or products that would be formed. Is nitration of chlorobenzene regioselective why or why not. Please explain your answer showing resonance structures. (5 pts)
7. For the following substitution reactions predict the product(s) showing stereochemistry only if is of revelance. Also comment on what type reaction: S1 or SN2. Finally is the starting material and product optically active or inactive? Explain! CH, OH HBr CN CH3CH2CH3 HO HBr CN 1 CI CH3CH2CH3 НО HBr CH Br H3C
Predict the major organic product for each reaction below. Predict the structure of the alkene you would use to prepare each alkyl halide below (only product The reaction of isobutene with HBr in ether gives one of the two products below as the major product. Answer the following question(s) about this reaction. HBr Br + ether Product A Product B 32. Which product would be the major product? 33. Which product would be formed via a primary carbocation?
5. Predict the major product for each of the following reactions HCl а. b. HI HBr с. 5. Predict the major product for each of the following reactions HCl а. b. HI HBr с.
Predict the product for the following reactions:
question A)
question B)
(2 of 10) What is the major product for the following reaction? Return to Site HBr 0°C Br a) b) c) d) Br Br Br
Which product(s) would you expect to obtain from each of the following reactions? In each part give the mechanism (Sw1, SN2, E1 or E2) by which each product is formed. Explain your reasoning. (20 pts) 6. a. NaSH OTs DMSO b. CI NaOCH3 C. OMs NaOCH2CH3 d. ON HCECNa e. KOC(CH3).3 CI Br NaOCH2CH3 CH3CH2OHH