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12. Among the following set of carbonyl compounds, identify the appropriate starting material (s) for the...
Give a reasonable synthesis for each of the following compounds from the indicated starting materials. You...
Give a reasonable synthesis for
each of the following compounds from the indicated starting
materials. You may use any other organic or inorganic reagents you
wish unless otherwise indicated. The desired product for each
reaction you propose must be the one of the predominant products.
Give the reactants, conditions (where appropriate) and products of
each synthetic step. If equal mixtures are anticipated (i.e. ortho
/ para products) then indicate where separations are needed. NO
MECHANISMS! [6 points
2. Give a...
S RROwn as nucleophilic addition. The C-O bond is highly polarized, making carbonyl compounds ele...
S RROwn as nucleophilic addition. The C-O bond is highly polarized, making carbonyl compounds electrophilic at carbon. If the Grignard reagent reacts with an aldehyde, ketone or ester, the ultimate product is an alcohol. Overall Reaction 0 Br Me PartA Part B Pre-lab questions (15 points) Show the mechanism of the reaction of bromobenzene with magnesium metal in anhydrous diethyl ether There are many inert solvents that could be used but diethyl ether was chosen because it can assist the...
II. Reactions: Predict the major organic product(s) or write the appropriate reagents/starting materials for the following...
II. Reactions: Predict the major organic product(s) or write the appropriate reagents/starting materials for the following reactions. Indicate stereochemistry and regiochemistry when appropriate. Indicate reactions that are expected to result in a racemic mixture of products DBr 1. Н.О, CHCI он HSO, heat кон 1) вн, THF 3. 2) H202. HO 1) Hg(OAc)2, CH,OH 2) NaBH, OH 5. Br2 SH 6. HIO4 OH THF, H2O "он III. Synthesis: Starting from the alkenyl bromide below, devise a synthesis that produces the...
QUESTION 1 For the following reaction, identify the 1,2-addition product. A) B) Br Br- Br +...
QUESTION 1 For the following reaction, identify the 1,2-addition product. A) B) Br Br- Br + HBr C) D) Br ОООО С D 1 points QUESTION 2 Identify the product of the following reaction. + H,CO,C -CO,CH -CO,CH -CO_CH -CO,CH A CO,CH D) c) A) B) COACH CO,CH COCH, CO.CH B ОООО С D QUESTION 3 For (3E,5E)-octa-1,3,5,7-tetraene, shown below, how many of the a-molecular orbitals are bonding orbitals? 3 ОООО 6 PUS QUESTION 4 ОН ОН Which one of...
Identify the following ir spectrum 3 6 1 2 ✓ ເຂົ້າມາມຮນສາມ M ong 12 15 B...
Identify the following ir spectrum 3 6 1 2 ✓ ເຂົ້າມາມຮນສາມ M ong 12 15 B 1000 18 2-butanone 21 2-methyl-2-propen-1-ol 24 ethyl vinyl ether 2-methylpropanal a Question 20 (2.5 points) ✓ Saved Give the major product of the following sequence of reactions 9 1) HNOJH SO acetophenone 12 2) HyPa Op-aminoethylbenzene 15 ✓ m-aminoethylbenzene 18 m-aminoacetophenone 21 m-nitroacetophenone Question 12 (2.5 points) What is the major product of the following reaction? 1 2 3 4 2-butanone 5 6 (PL);P-CHCH...
Grignard reagent THE GRIGNARD REAGENT-PREPARATION AND REACTION In this experiment, you will prepa...
i need help with the postlab questions please
Grignard reagent THE GRIGNARD REAGENT-PREPARATION AND REACTION In this experiment, you will prepare a Grignard reagent, phenyl magnesium bromide, from bromobenzene and magnesium metal. The Grignard reagent will then react with methyl benzoate to form triphenylmethanol. Introduction Grignard reagents, such as organomagnesium halides, were discovered in 1910 by French chemist Victor Grignard. The Grignard reaction is one of the most general methods for carbon- carbon bond formation in all of organic chemistry....
please identify the unknown and write a derivative Unknown compound 3 Clear liquid Physcial Properties Solubility...
please identify the unknown and write a derivative
Unknown compound 3 Clear liquid Physcial Properties Solubility Dissolve in ethyl ether Not dissolved in water Boiling point 77 IR spectrum Transmitance 3000 1000 2000 Wavenumber cm-1) Classification Positive test in Alkaline Iron (III) Hydroxamate test test CLASSIFICATION TESTS These tests must be done together with known AND FOLLOW PROCEDURE IN YOUR TEXT CARBOXYLIC ACIDS are detected by teating aqueous solutions with limus or pH paper. Also, disolve In NaHCO with bubbles...
10. Write a one-page summary of the attached paper? INTRODUCTION Many problems can develop in activated...
10. Write a one-page summary of the attached paper? INTRODUCTION Many problems can develop in activated sludge operation that adversely affect effluent quality with origins in the engineering, hydraulic and microbiological components of the process. The real "heart" of the activated sludge system is the development and maintenance of a mixed microbial culture (activated sludge) that treats wastewater and which can be managed. One definition of a wastewater treatment plant operator is a "bug farmer", one who controls the aeration...
Give a reasonable synthesis for
each of the following compounds from the indicated starting
materials. You may use any other organic or inorganic reagents you
wish unless otherwise indicated. The desired product for each
reaction you propose must be the one of the predominant products.
Give the reactants, conditions (where appropriate) and products of
each synthetic step. If equal mixtures are anticipated (i.e. ortho
/ para products) then indicate where separations are needed. NO
MECHANISMS! [6 points
2. Give a...
S RROwn as nucleophilic addition. The C-O bond is highly polarized, making carbonyl compounds electrophilic at carbon. If the Grignard reagent reacts with an aldehyde, ketone or ester, the ultimate product is an alcohol. Overall Reaction 0 Br Me PartA Part B Pre-lab questions (15 points) Show the mechanism of the reaction of bromobenzene with magnesium metal in anhydrous diethyl ether There are many inert solvents that could be used but diethyl ether was chosen because it can assist the...
II. Reactions: Predict the major organic product(s) or write the appropriate reagents/starting materials for the following reactions. Indicate stereochemistry and regiochemistry when appropriate. Indicate reactions that are expected to result in a racemic mixture of products DBr 1. Н.О, CHCI он HSO, heat кон 1) вн, THF 3. 2) H202. HO 1) Hg(OAc)2, CH,OH 2) NaBH, OH 5. Br2 SH 6. HIO4 OH THF, H2O "он III. Synthesis: Starting from the alkenyl bromide below, devise a synthesis that produces the...
QUESTION 1 For the following reaction, identify the 1,2-addition product. A) B) Br Br- Br + HBr C) D) Br ОООО С D 1 points QUESTION 2 Identify the product of the following reaction. + H,CO,C -CO,CH -CO,CH -CO_CH -CO,CH A CO,CH D) c) A) B) COACH CO,CH COCH, CO.CH B ОООО С D QUESTION 3 For (3E,5E)-octa-1,3,5,7-tetraene, shown below, how many of the a-molecular orbitals are bonding orbitals? 3 ОООО 6 PUS QUESTION 4 ОН ОН Which one of...
Identify the following ir spectrum 3 6 1 2 ✓ ເຂົ້າມາມຮນສາມ M ong 12 15 B 1000 18 2-butanone 21 2-methyl-2-propen-1-ol 24 ethyl vinyl ether 2-methylpropanal a Question 20 (2.5 points) ✓ Saved Give the major product of the following sequence of reactions 9 1) HNOJH SO acetophenone 12 2) HyPa Op-aminoethylbenzene 15 ✓ m-aminoethylbenzene 18 m-aminoacetophenone 21 m-nitroacetophenone Question 12 (2.5 points) What is the major product of the following reaction? 1 2 3 4 2-butanone 5 6 (PL);P-CHCH...
i need help with the postlab questions please
Grignard reagent THE GRIGNARD REAGENT-PREPARATION AND REACTION In this experiment, you will prepare a Grignard reagent, phenyl magnesium bromide, from bromobenzene and magnesium metal. The Grignard reagent will then react with methyl benzoate to form triphenylmethanol. Introduction Grignard reagents, such as organomagnesium halides, were discovered in 1910 by French chemist Victor Grignard. The Grignard reaction is one of the most general methods for carbon- carbon bond formation in all of organic chemistry....
please identify the unknown and write a derivative
Unknown compound 3 Clear liquid Physcial Properties Solubility Dissolve in ethyl ether Not dissolved in water Boiling point 77 IR spectrum Transmitance 3000 1000 2000 Wavenumber cm-1) Classification Positive test in Alkaline Iron (III) Hydroxamate test test CLASSIFICATION TESTS These tests must be done together with known AND FOLLOW PROCEDURE IN YOUR TEXT CARBOXYLIC ACIDS are detected by teating aqueous solutions with limus or pH paper. Also, disolve In NaHCO with bubbles...
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