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2. (13 pts) Determine the rate constant and reaction orders for the following reaction using the data provided: 2 NO (g) + 02 (g) > 2 NO2 (g) Rate (M/s 0.028 0.057 0.114 0.227 Experiment NO 0.020 0.020 0.020 0.040 0.010 0.010 0.020 0.040 0.020 0.020 3 4 a.) For the rate law, determine all reaction orders Rate -k [NO]m[O2] Reaction order m (CIRCLE ONE) 1½ Reaction order n (CIRCLE ONE) 1½

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Answer #1

a)
see experiment 2 and 4:
[NO] doubles
[O2] is constant
rate becomes 4 times
so, order of NO is 2
Answer: m = 2

b)
see experiment 1 and 2:
[NO] is constant
[O2] doubles
rate doubles
so, order of O2 is 1
Answer: n = 1

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