![4 of 15 Determine the overall reaction order for the reaction, A C+D using the table of data below: Experiment Initial [A]/M](http://img.homeworklib.com/questions/d82d8800-7034-11ea-bb59-e91e71131376.png?x-oss-process=image/resize,w_560)
Homework Answers
Solution:
4) Order will be zero (0),
From the given table, we can seen that increasing the concentration of A does not affect the rate of reaction. Hence, order will be zero.
5) Changing the temperature
According to Arhenius,
K = A e -Ea/RT
Thus, rate constant of reaction increases with increasing temperature.
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4 of 15 Determine the overall reaction order for the reaction, A C+D using the table...
Part A From the data, determine the rate law for the reaction. You may want to...
Part A From the data, determine the rate law for the reaction. You may want to reference (Pages 629 - 634) Section 14.3 while completing this problem. Consider the following reaction: CHCl(9) + Cl2(g) → CCL (9) + HC1() The Initial rate of the reaction is measured at several different concentrations of the reactants with the following results: [CHCI](M) [CI] (M) initial Rate (M/s) 0.010 0.010 0.0034 0.020 0.010 0.0068 rate=K[CHC13]/2Cl2}\/2 O rate-k[CHCI)(CI)" Oratenk(CHCI)(C1) O rate=k[CHC13) C1,]1/2 0.020 0.040 0.020...
14 of 15 The rate law for the reaction, A+B-C, that is zero order for both...
14 of 15 The rate law for the reaction, A+B-C, that is zero order for both reactants is O rate=k O rate=k[A] O rate=k[A][B] O rate=k[C] 15 of 15 For a reaction that is second order in A, calculate the value of the rate law constant using the table below: Experiment Initial [A]/M Initial rate/M s 0.010 0.020 .040 0 win 0.012 .050 0.19 3 0 118 M-18-1 O 126 M-15-1 O 0.40 M-15-1 O 121 M-15-1
2. (13 pts) Determine the rate constant and reaction orders for the following reaction using the...
2. (13 pts) Determine the rate constant and reaction orders for the following reaction using the data provided: 2 NO (g) + 02 (g) > 2 NO2 (g) Rate (M/s 0.028 0.057 0.114 0.227 Experiment NO 0.020 0.020 0.020 0.040 0.010 0.010 0.020 0.040 0.020 0.020 3 4 a.) For the rate law, determine all reaction orders Rate -k [NO]m[O2]' Reaction order m (CIRCLE ONE) 1½ Reaction order n (CIRCLE ONE) 1½
12 of 15 Use the table below to calculate the initial reaction rate of the following...
12 of 15 Use the table below to calculate the initial reaction rate of the following reaction: 2AB+C [A]/M t/s 0.100 0.045 O 0.006 M/S -0.006 M/S -0.012 M/s 0.012 M/s 13 of 15 Use the table below to determine the rate law for the reaction A-2B: Initial rate/Ms Experiment Initial [A]/M 1 0.010 0.020 0.040 0.0010 0.0040 0.0160 2 3 1 rate=k O rate=k[A] O rate=k[A]2 O rate=k[A][B]2
QUESTION 6 From the following data, the reaction order for Ais___and the reaction order for Bis...
QUESTION 6 From the following data, the reaction order for Ais___and the reaction order for Bis A Second order for A: first order for B B. zero order for Azero order for B C. zero order for Afirst order for B D. first order for As first order for B E. None of the answers are correct. QUESTION 7 You are trying to determine the reaction rate for a reaction with several intermediate steps. The rate for the overall reaction...
From the data, determine the rate constant (k) for the reaction. Express your answer using two...
From the data, determine the
rate constant (k) for the reaction. Express your answer using two
significant figures.
<Chapter 14 Homework For Practice 14.2 - Enhanced - with Feedback 10 of 48 Review I Constants Periodic Table Consider the following reaction: CHCl (g)Cl(g) -CCl (g) +HCl(g) Submit Previous Answers The initial rate of the reaction is measured at several different concentrations of the reactants with the Correct following results Fractional-order reactions are not comman but are occasionally observed. The first...
3. A second order reaction of the type A + B → P was carried out...
3. A second order reaction of the type A + B → P was carried out in a solution with initial concentrations of 0.075 and 0.050 moVL for A and B, respectively. After one hour, the concentration of B decreased to 0.020 mol/L. The reaction rate is expressed as v = k[A][B] 3.1 Calculate the rate constant of this reaction. 3.2 What is the half-life time of the reactants?
Question 15 4 pts Consider the following generic reaction and the corresponding rate law: X+Y+zStuff Rate...
Question 15 4 pts Consider the following generic reaction and the corresponding rate law: X+Y+zStuff Rate = k[Y][Z]2 Which of the following changes will NOT increase the rate of this reaction? Increasing the concentration of reactant X Increasing the concentration of reactant z Adding a catalyst Increasing the temperature O Increasing the average number of collisions per second of the reactants
2. When using the method of initial rates to determine the reaction order of each individual...
2. When using the method of initial rates to determine the reaction order of each individual reactant, why must data only be used in which one reactant is changing concentration but not the other reactants? 3. Briefly explain why the number of total drops being mixed in each experiment is kept constant throughout all five experiments. 4. Sketch a molecular‐level picture that illustrates why reaction rate increases when the concentration of a reactant is increased. Note – this might be...
1. A solution is prepared by dissolving 20.2 mL CH,OH in 100.0 mL HO at 25...
1. A solution is prepared by dissolving 20.2 mL CH,OH in 100.0 mL HO at 25 degrees Celsius. The final volume of the solution is 118.0 mL. The densities of CHOH and H,O are 0.782 g/mL and 1.00 g/mL, respectively. For this solution, calculate molality, molarity, mole fraction of each component and % by mass of each component. 2. A solution contains a mixture of pentane and hexane at room temperature. The solution has a vapor pressure of 258 torr....
Part A From the data, determine the rate law for the reaction. You may want to reference (Pages 629 - 634) Section 14.3 while completing this problem. Consider the following reaction: CHCl(9) + Cl2(g) → CCL (9) + HC1() The Initial rate of the reaction is measured at several different concentrations of the reactants with the following results: [CHCI](M) [CI] (M) initial Rate (M/s) 0.010 0.010 0.0034 0.020 0.010 0.0068 rate=K[CHC13]/2Cl2}\/2 O rate-k[CHCI)(CI)" Oratenk(CHCI)(C1) O rate=k[CHC13) C1,]1/2 0.020 0.040 0.020...
14 of 15 The rate law for the reaction, A+B-C, that is zero order for both reactants is O rate=k O rate=k[A] O rate=k[A][B] O rate=k[C] 15 of 15 For a reaction that is second order in A, calculate the value of the rate law constant using the table below: Experiment Initial [A]/M Initial rate/M s 0.010 0.020 .040 0 win 0.012 .050 0.19 3 0 118 M-18-1 O 126 M-15-1 O 0.40 M-15-1 O 121 M-15-1
2. (13 pts) Determine the rate constant and reaction orders for the following reaction using the data provided: 2 NO (g) + 02 (g) > 2 NO2 (g) Rate (M/s 0.028 0.057 0.114 0.227 Experiment NO 0.020 0.020 0.020 0.040 0.010 0.010 0.020 0.040 0.020 0.020 3 4 a.) For the rate law, determine all reaction orders Rate -k [NO]m[O2]' Reaction order m (CIRCLE ONE) 1½ Reaction order n (CIRCLE ONE) 1½
12 of 15 Use the table below to calculate the initial reaction rate of the following reaction: 2AB+C [A]/M t/s 0.100 0.045 O 0.006 M/S -0.006 M/S -0.012 M/s 0.012 M/s 13 of 15 Use the table below to determine the rate law for the reaction A-2B: Initial rate/Ms Experiment Initial [A]/M 1 0.010 0.020 0.040 0.0010 0.0040 0.0160 2 3 1 rate=k O rate=k[A] O rate=k[A]2 O rate=k[A][B]2
QUESTION 6 From the following data, the reaction order for Ais___and the reaction order for Bis A Second order for A: first order for B B. zero order for Azero order for B C. zero order for Afirst order for B D. first order for As first order for B E. None of the answers are correct. QUESTION 7 You are trying to determine the reaction rate for a reaction with several intermediate steps. The rate for the overall reaction...
From the data, determine the
rate constant (k) for the reaction. Express your answer using two
significant figures.
<Chapter 14 Homework For Practice 14.2 - Enhanced - with Feedback 10 of 48 Review I Constants Periodic Table Consider the following reaction: CHCl (g)Cl(g) -CCl (g) +HCl(g) Submit Previous Answers The initial rate of the reaction is measured at several different concentrations of the reactants with the Correct following results Fractional-order reactions are not comman but are occasionally observed. The first...
3. A second order reaction of the type A + B → P was carried out in a solution with initial concentrations of 0.075 and 0.050 moVL for A and B, respectively. After one hour, the concentration of B decreased to 0.020 mol/L. The reaction rate is expressed as v = k[A][B] 3.1 Calculate the rate constant of this reaction. 3.2 What is the half-life time of the reactants?
Question 15 4 pts Consider the following generic reaction and the corresponding rate law: X+Y+zStuff Rate = k[Y][Z]2 Which of the following changes will NOT increase the rate of this reaction? Increasing the concentration of reactant X Increasing the concentration of reactant z Adding a catalyst Increasing the temperature O Increasing the average number of collisions per second of the reactants
1. A solution is prepared by dissolving 20.2 mL CH,OH in 100.0 mL HO at 25 degrees Celsius. The final volume of the solution is 118.0 mL. The densities of CHOH and H,O are 0.782 g/mL and 1.00 g/mL, respectively. For this solution, calculate molality, molarity, mole fraction of each component and % by mass of each component. 2. A solution contains a mixture of pentane and hexane at room temperature. The solution has a vapor pressure of 258 torr....
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