1. A second-order reaction of the type A + A → P was carried out in a solution with the initial concentration [A]0 = 0.58 mol L-1. After 20.5 s the concentration of A had fallen to [A]t = 0.12 mol L-1. What is the rate constant k for this reaction in units of liter per mol per second (L mol-1 s-1) ? 2. A compound with vaporization enthalpy of ΔHvap = 68.0 kJ for every 2 molesof liquid...
4 of 15 Determine the overall reaction order for the reaction, A C+D using the table of data below: Experiment Initial [A]/M Initial [B]/M Initial rate/M s. 1 1 2 0.010 0.020 0.040 0.075 0.050 0.025 0.0017 0.0015 0.0016 O O WN - o O O 5 of 15 Which of the following would have the greatest effect on the value of the rate law constant in the rate law equation, rate=k[A]? O increasing the concentration of the reactant O...
For a type 2 second order reaction, the reaction is 60% complete in [A] in 60 seconds when [A]0 = 0.1 M and [B]0 = 0.5 M. What is the rate constant for this reaction? Calculate the time for the reaction to reach 60% completion change if the initial reactant concentrations are decreased by a factor of 2. (Are the two times the same regardless of initial reactant concentrations?)
The second order gas phase irreversible reaction: 2.4-B is carried out in an isothermal batch reactor containing 40 kg of catalyst and with an initial volume of 60-liter. The reactor is initially filled with equal molar quantities of A and inert I at 300 K and 2.5 atm. Calculate the time needed for the concentration of product (B) to be 0.02 mole/liter if: a) the reaction takes in a constant pressure batch reactor (3 points) b) the reaction takes place...
An acid-catalyzed irreversible liquid-phase reaction A B is carried out adiabatically in a CSTR. The reaction is second order in A. The feed is equimolar A and solvent (S, which contains catalyst), and enters the reactor at a total volumetric flow rate of 10 dm3/min at a concentration of A of 4 mol/L. The feed enters at 300 K. The product and reactant heat capacities are 15 cal/(mol°C), the solvent is 18 cal/(mol°C). The reaction rate constant at 300 K...
10 and 11 10. Nitrosyl chloride, NOCI, decomposes slowly to NO and Cl2, the reaction follows second order kinetics with a rate constant of 0.020 L mol-' s at a certain temperature. 2 NOCI (g) → 2 NO(g) + Cl2(g) If the initial concentration of NOCI in a closed reaction vessel is 0.050 M, what will be the concentration be after 30 minutes? 11. The reaction 2 NO2 (g) → 2 NO(g) + O2(g), is second order with respect to...
Reaction is A-->B is carried out adiabatically in a CSTR. The reaction is second order in A. The feed, which is equal molar in water (which contains the catalyst) and A, enters the reactor at a temperature of 52 C and a total volumetric flow rate of 10 dm3/min. The concentration of A entering the reactor is 4 molar. a) What is the reactor volume to achieve 80% conversion b) What conversion can be achieved in a 1000 dm3 CSTR?...
+ Half-life for First and Second Order Reactions 11 of 11 The half-life of a reaction, t1/2, is the time it takes for the reactant concentration A to decrease by half. For example, after one half-Me the concentration falls from the initial concentration (Alo to A\o/2, after a second half-life to Alo/4 after a third half-life to A./8, and so on. on Review Constants Periodic Table 11/25 For a second-order reaction, the half-life depends on the rate constant and the...
3. The endothemic irreversible 2nd order reaction A +B C is carried out in a pressurised adiabatic batch reactor. The initial temperature is 120°C and the initial concentrations of both A and B are 2.0 kmol m2 Kinetic studies showed that the reaction rate constant is given by: 6000 k 2 x 105 exp(- m3kmol 1s1 T (8) (a) Derive the mass and energy balances for the reactor. Calculate the conversion achieved and the reactor temperature (b) (12) after 30...
For a first-order reaction, the half-life is constant. It depends only on the rate constant k k and not on the reactant concentration. It is expressed as t1/2=0.693k t 1 / 2 = 0.693 k For a second-order reaction, the half-life depends on the rate constant and the concentration of the reactant and so is expressed as t1/2=1k[A]0. A certain first-order reaction (A→products A → p r o d u c t s ) has a rate constant of 9.30×10−3...