IA] 1)-LAHTHE 2)-Hjo. IBI 1Bl Raney Ni /H Solvent) ICl NaBH, 0 Ethanol Solvent) 2-H0 NPh...
Predict the products of the following. Thank you!!! NaBH H,so, e) CH OH Raney Ni PBr3 о- Li 0: HCI g) 2. H30* 1. Give the products of the following reactions by first, writing the products without stereochemistry and labeling the stereocenters. Then write out all stereoisomers. Hint: the correct number of isomers is given in ). Label the relationships between the products CO2CH3 2) CO2CHs heat
H,SO HO 1. BHTHF 2. HẠO, NaOH ou H,SO H0 1. Hg(OAc),,H,O 2. NaBH H.PO H.0 Draw the mechanisms of each of the reactions including all electrons and arrow pushing
2Li 1. РСС Et2O CH2CI2 2. Hо" C) Н2 NaH H Raney Ni D)
Draw the structure Ç(CH3)3 0 1) PhČCI, AICI: 2) Et2NH, H2, Raney-Ni, heat CO2Me 1) EtMgBr (2 equiv.) 2) H20, H30+
н'-н,о) HS Raney Ni HS H'-но) + Н Но CH2OH NH2 CI 1) LAH ОН 2) H,О ZI Question 1 (6 points). Provide IUPAC names for the following structures. Question 2 (14 points). Convert the following IUPAC names into structures. 2,4-dimethylcyclopent-2-enone 5-hydroxy-2-phenyl-3-hexanone (S)-2-bromo-2-methylcyclobutanone 3-methyl-5-(4-chlorophenyl) hexanal 3-isobutylbenzoic acid Acetic butanoic anhydride N-phenyl-N-propyl-2,3-dimethylbutanamide Page 2 o
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...
о, DMS RCO H Он но н'но) Он SOCI РСС ОН н'-но) SH Raney Ni HS н'*но) н' Но CH, Oн NH2 1) LAH ОН 2) H,O Shem 415 Question 1 (6 points). Provide IUPAC names for the following structures. Question 2 (14 points), Convert the following IUPAC names into structures. 2,4-dimethylcyclopent-2-enone 5-hydroxy-2-phenyl-3-hexanone (S)-2-bromo-2-methylcyclobutanone 3-methyl-5-(4-chlorophenyl) hexanal 3-isobutylbenzoic acid Acetic butanoic anhydride N-phenyl-N-propyl-2,3-dimethylbutanamide Page 2 o
draw the major product 11. Ç(CH3) 30 1) CH3CCI, AICI 2) (CH3)2NH H2, Raney-Ni, heat 12. ÇO Me 1) PhMgBr (2 equiv.) 2) H20, H,00 13. CNH2 1) Brz, NaOH, H20 O 11 2) CH3CCI, pyridine
give major product O 11. Ç(CH3)3 1) CH3CCI, AICI: 2) (CH3)2NH H2, Raney-Ni, heat 12. ÇO Me 1) PhMgBr (2 equiv.) 2) H20, H30 13. CNH2 1) Brz, NaOH, H20 2) CH,CCI, pyridine 14. HNO3 CHO но +н н+он н+он нон CH OH оо 15. H2NCO, 1) (CH3),COCOCOC(CH3)3 Ph -N: C: NH- PhNHNH | 16. CHO HOTH HOH (3 equiv.) H-OH HO+H CH2OH ai
What reagent(s) will complete the following reaction? HO. 1. Hg(OAc)2, H2O/THF 1. B, H, THE H0/H0 HO/HO 2. NaBH, 2. NaOH, HẠO II III IV ΟΙ O II III O IV Both I and III will work.