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1. Complete the following reactions by drawing the skeletal structures of the major products in the...
Complete all of the following reactions by drawing structures of the major products for each. Where appropriate, clearly indicate stereochemistry of the product. Н, РО, 2 Br 3. (1)OsO (2)NaHSO) Cl2/H2O 5. ()Bн, (2)H,O2OH(a 6- (1O (2)Zn, H 1. CHClyNaOH 8. (1)Hg 2+ (2)NaBH 9. KMnO. HO 10. 41
Complete the following reaction sequences by drawing the major
products or the reagents necessary to make them. Be sure to include
stereochemistry when appropriate.
1. (48 pts) Complete the following reaction sequences by drawing the major products or the reagents necessary to make them. Be sure to include stereochemistry when appropriate. HBr Benzene FeBr3 HO NaH DMF hv NaNH2 2 BnBr CH2Cl2 Benzene Br2 cat. H+ H2o Ph NaOH NBS H Br H20 hv
(30 pts) (a) Complete the following reactions by drawing the major products or the reagents to make them. (b) Label each reaction as Sy1.S2, El, E2, or addition. Be sure to 1. KOMe b. HOMe H20 d. MeOH cat. H Cl EtoH Cl
7. Complete the following transformations by drawing the structures of the organic products PhLi H,o heat H2-Pd/C HNo, H2O, acetic H2SO4 acid heat Br2, FeBr3 NaNO2 NH, H 2 heat HBF NaNO heat N NH, HCI H2o KNH2 N heat
7. Complete the following transformations by drawing the structures of the organic products PhLi H,o heat H2-Pd/C HNo, H2O, acetic H2SO4 acid heat Br2, FeBr3 NaNO2 NH, H 2 heat HBF NaNO heat N NH, HCI H2o KNH2 N heat
3. Complete the following reactions of the compound shown by drawing the correct products with CORRECT stereochemistry if important (10 pts). + Br2 Brain H20 1. 03 2. Mezs Hipo H/Pd 1. Hg(OAC) in THF/water 2. NaBH4, NaOH 1. BH3-THF 2. H2O2, NaOH peroxyacid HBO HBr/peroxide 1. Os04 2. NaHSO3
Unambiguously identify the structures of the major products, reactants, or reagents for the following reactions, including stereochemistry when appropriate. Indicate if the reactions undergo E1, E2, SN1, or SN2 mechanism. 1. ?? H2SO4, H20o NaOCH3 CH3OH 2. CI ?? H2SO4, H20 3. t-BuOK t-BuOH 4 CI CN 5. CI XcCH.OH 6. CI
pls help
Clearly indicate stereoisomers, unless otherwise indicated. 1. Predict the products of the following reactions. a. H O DCC HCI I HOPh H2O c. ☺ NaOH 1) SOCl2, A 2) AICI: VHO 2. Suggest starting materials for the following reactions. b. acetone i) LiAIH4 Meo ii) H20 workup
3. Complete the following reactions of the compound shown by drawing the correct products with CORRECT stereochemistry if important (10 pts). Br Br2 in H2O 1. O3 2. MegS HO H2/Pd OP A01018 1. Hg(OAc)2 in THF/Water 2. NaBH NaOH 1. BH3-THF 2. H2O2, NaOH estolqind, ( ym peroxyacid he anolbe o s HBr HBr/peroxide 1. OsO4 2. NAHSO3
39. actions and give the structures of any intermediates. 1. Complete the major products of the following reactions and give Include stereochemistry, when appropriate. 1) BH, THE 2)H,0OH Bra но KMnO, OH theat) Oso4 H202 110, 2) (CH3) 21 HGCOAC), H0 1) Hg(OAc) H2O c) H20 H2SO4 2) NaBHA H2 1)03 2) (CH3)2s Pd-C CH3OH
Complete the following reaction
sequences by drawing the major products or reagents needed to make
them.
2. (2 4 pts) Complete the following reaction sequences by drawing the major products or the reagents necessary to make them. Be sure to include stereochemistry when appropiate Br2 H20 Br HBr NaNH2 b. H202 m-CPBA c.