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A non-branching ether has a molecular ion peak at m/z=102 and another significant peak at m/z=57. Draw the structure of the molecule. You do not need to show the hydrogen atoms, but you may want to place the carbon atoms in a zigzag pattern to make it easier to count how many you've drawn.
a) Describe the difference between the base peak and the parent ion (or molecular ion) peak. b) Identify the base peak and the parent ion (or molecular ion) peak (if any) according to the mass spectrum. c) Identify the mass fragments which correspond to m/z = 77, 105, 111, and 139. d) Identify and give explanations for the magnitude (or intensity) of the peaks at m/z = 113, 141, and 218. Mass Spectrum ofp-C hlorobenzophenone 105 100 80 139 CI...
Circle the molecular ion peak for the following MS spectrum and the m/z value for the molecular ion is _____________ 4. Circle the molecular ion peak for the following MS spectrum and the m/z value for the molecular ion is 42 pt) 100 80- 60- ? 40- 20- 10 20 30 40 50 m z
The boiling points of t-butyl methyl ether (2-methoxy-2-methylpropane) and n-butyl methyl ether (1-methoxybutane) differ by 16 degrees (71 and 55 °C), even though they have the same molecular weight. Draw the two structures below: The boiling points of t-butyl methyl ether (2-methoxy-2-methylpropane) and n-butyl methyl ether (1- methoxybutane) differ by 16 degrees (71 and 55 °C), even though they have the same molecular weight. Draw the two structures below: Which compound has the higher boiling point and why? 1-methoxybutane has...
label each major peak with a molecular formula (including charge) label the molecular ion peak as "M+" (if present) label major peaks other than the molecular ion with three things: 1) the mass to charge ratio 2) the structure or formula for that charged fragment 3) another formula to show which fragment was lost by the molecular ion to form that ion Mass spec NEUTRAL COMPOUND 100- 80 2-6utanene 60 40 20- 75 60 65 70 35 40 45 10...
Some tert-butyl ether is formed in the solvolysis of tert-butyl chloride. Where does this product come from (i.e. what is the substrate and what is the nucleophile?) Do you think this will affect the kinetics of the reaction? Think about the rate-limiting step in the reaction.
In the Williamson ether synthesis, an alkoxide ion reacts with an alkyl give an to halide ether R-O- + R-x rightarrow R-O-R + X^- To prepare sec-butyl propyl ether by this synthesis, is it better to use sec-butoxide ion and propyl chloride or propoxide ion and sec-butyl chloride? Explain your answer.
In this mass spectrum, which peak most likely represents the molecular ion? In this mass spectrum, which peak most likely represents the molecular ion?
Give 3 possible molecular formulas for a compound with a molecular ion peak of 148 and calculate the degrees of unsaturation for each compound. Please show work
Description: Shown below is an EI-MS spectrum for t-butyl chloride. 1) Clearly label the base peak in the spectrum. Draw the structure of the fragment the base peak corresponds to. 2) Is there a molecular ion present in the spectrum? If so, label the peak that corresponds to the molecular ion. 3) Is there any evidence that the following EI-MS spectrum represents a chlorine containing compound? If so, label the necessary peaks and explain briefly why there is sufficient evidence...