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Diels-Alder Reaction: Provide the requirements for a diene and a dienophile for an optimal Diels-Alder reaction....

Diels-Alder Reaction:

Provide the requirements for a diene and a dienophile for an optimal Diels-Alder reaction. Can naphthalene be used as a diene for a Diels-Alder reaction? Explain your answer.

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Answer #1

when diene having electron donating group and dienophile having electron withdrawing group give good yield in diels alder reaction. due to presence of substituents above mentioned the gap between HOMO - LUMO will decrease.

napthlene cannot in act as diene.

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